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We revisit the classical problem of flow of electrolyte solutions through charged capillary nanopores or nanotubes as described by the capillary pore model (also called "space charge" theory). This theory assumes very long and thin pores…

化学物理 · 物理学 2019-08-16 P. B. Peters , R. van Roij , M. Z. Bazant , P. M. Biesheuvel

We derive a large-scale hydrodynamic equation, including diffusive and dissipative effects, for systems with generic static position-dependent driving forces coupling to local conserved quantities. We show that this equation predicts…

统计力学 · 物理学 2021-12-10 Joseph Durnin , Andrea De Luca , Jacopo De Nardis , Benjamin Doyon

We present a new method for Monte Carlo or Molecular Dynamics numerical simulations of three dimensional polar fluids. The simulation cell is defined to be the surface of the northern hemisphere of a four-dimensional (hyper)sphere. The…

软凝聚态物质 · 物理学 2014-09-29 Jean-Michel Caillol , Martin Trulsson

We develop a Hamiltonian theory of a time dispersive and dissipative inhomogeneous medium, as described by a linear response equation respecting causality and power dissipation. The proposed Hamiltonian couples the given system to auxiliary…

数学物理 · 物理学 2009-04-24 Alex Figotin , Jeffrey H. Schenker

We develop a lattice-based Monte Carlo simulation method for charged mixtures capable of treating dielectric heterogeneities. Using this method, we study oil-water mixtures containing an antagonistic salt, with hydrophilic cations and…

软凝聚态物质 · 物理学 2017-11-29 Nikos Tasios , Sela Samin , René van Roij , Marjolein Dijkstra

Recent microfluidic experiments revealed that large particles advected in a fluidic loop display long-range hydrodynamic interactions. However, the consequences of such couplings on the traffic dynamics in more complex networks remain…

软凝聚态物质 · 物理学 2015-05-30 Raphaël Jeanneret , Julien Piera-Vest , Denis Bartolo

In order to detect the effect of the surface charge discreteness on the properties at the solid-liquid interface, molecular dynamics simulation model taking consideration of the vibration of wall atoms was used to investigate the ion and…

化学物理 · 物理学 2016-12-20 Yinghua Qiu , Yunfei Chen

Liquids in contact with solids are submitted to intermolecular forces making liquids heterogeneous and stress tensors are not any more spherical as in homogeneous bulks. The aim of this article is to show that a square-gradient functional…

经典物理 · 物理学 2017-08-23 Henri Gouin

Water in nanoscale cavities is ubiquitous and of central importance to everyday phenomena in geology and biology. However, the properties of nanoscale water can be remarkably different from bulk, as shown e.g., by the anomalously low…

材料科学 · 物理学 2025-01-08 Venkat Kapil , Christoph Schran , Andrea Zen , Ji Chen , Chris J. Pickard , Angelos Michaelides

To better understand the capture process by a nanopore, we introduce an efficient Kinetic Monte Carlo (KMC) algorithm that can simulate long times and large system sizes by mapping the dynamic of a point-like particle in a 3D spherically…

生物物理 · 物理学 2021-03-22 Le Qiao , Maxime Ignacio , Gary W. Slater

We study effects of electron correlation on the transport through a small interacting system connected to reservoirs using an effective Hamiltonian which describes the free quasi-particles of a Fermi liquid. The effective Hamiltonian is…

介观与纳米尺度物理 · 物理学 2009-11-07 Akira Oguri

We present a lattice-based numerical method to describe the non equilibrium behavior of a simple fluid under non-uniform spatial conditions. The evolution equation for the one-particle phase-space distribution function is derived starting…

统计力学 · 物理学 2009-11-13 S. Melchionna , U. Marini Bettolo Marconi

We show that the dynamics of the surface plasmon in metallic nanoparticles damped by its interaction with particle-hole excitations can be modelled by a single degree of freedom coupled to an environment. In this approach, the fast decrease…

介观与纳米尺度物理 · 物理学 2011-11-09 Cesar Seoanez , Guillaume Weick , Rodolfo A. Jalabert , D. Weinmann

The Hamiltonian dynamics of chains of nonlinearly coupled particles is numerically investigated in two and three dimensions. Simple, off-lattice homopolymer models are used to represent the interparticle potentials. Time averages of…

统计力学 · 物理学 2007-05-23 Alessandro Mossa , Marco Pettini , Cecilia Clementi

The structure of a polystyrene matrix filled with tightly cross-linked polystyrene nanoparticles, forming an athermal nanocomposite system, is investigated by means of a Monte Carlo sampling formalism. The polymer chains are represented as…

软凝聚态物质 · 物理学 2014-01-17 Georgios G. Vogiatzis , Evangelos Voyiatzis , Doros N. Theodorou

Microscopically conserving reduced models of many-body systems have a long, highly successful history. Established theories of this type are the random-phase approximation for Coulomb fluids and the particle-particle ladder model for…

强关联电子 · 物理学 2019-07-19 Frederick Green

Despite a recent flurry of experimental and simulation studies, an accurate estimate of the interaction strength of water molecules with hexagonal boron nitride is lacking. Here we report quantum Monte Carlo results for the adsorption of a…

Water plays a key role in biological membrane transport. In ion channels and water-conducting pores (aquaporins), one dimensional confinement in conjunction with strong surface effects changes the physical behavior of water. In molecular…

生物物理 · 物理学 2019-07-02 Oliver Beckstein , Mark S. P. Sansom

Low temperature structural and superfluid properties of $^4$He confined in cylindrical nanopores are theoretically investigated by means of first principle Quantum Monte Carlo (QMC) simulations. We vary the density of $^4$He inside the…

介观与纳米尺度物理 · 物理学 2022-02-03 Andrea Nava , Domenico Giuliano , Phong H. Nguyen , Massimo Boninsegni

We review quantum Monte Carlo results on energetic and structure properties of quantum fluids adsorbed in a bundle of carbon nanotubes. Using realistic interatomic interactions the different adsorption sites that a bundle offer are…

材料科学 · 物理学 2015-05-13 M. C. Gordillo , J. Boronat