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We show that the symmetry of the spin zigzag chain E phase of the orthorhombic perovskite manganites and nickelates allows for the existence of a finite ferroelectric polarization. The proposed microscopic mechanism is independent of…

强关联电子 · 物理学 2007-05-23 I. A. Sergienko , C. Sen , E. Dagotto

Using first principles calculations, we study the microscopic origin of ferroelectricity (FE) induced by magnetic order in the orthorhombic HoMnO3. We obtain the largest ferroelectric polarization observed in the whole class of improper…

材料科学 · 物理学 2009-11-13 Silvia Picozzi , Kunihiko Yamauchi , Biplab Sanyal , Ivan A. Sergienko , Elbio Dagotto

We have carried out a first-principles theoretical study of the magnetically induced polarization in orthorhombic TbMnO3, a prototypical material in which a cycloidal spin structure generates an electric polarization via the spin-orbit…

材料科学 · 物理学 2009-12-16 Andrei Malashevich , David Vanderbilt

Ferroelectricity is observed in orthorhombic $HoMnO_3$ and $YMnO_3$ at the magnetic lock-in transitions into an E-type structure or an incommensurate phase with a temperature independent wave vector, respectively. In $HoMnO_3$ the…

强关联电子 · 物理学 2011-11-09 B. Lorenz , Y. Q. Wang , C. W. Chu

This work investigates the magnetically driven ferroelectricity in orthorhombic manganites RMnO3 (R=Gd, Dy or Tb) from the point of view of the symmetry. The method adopted generalizes the one used to characterize the polar properties of…

材料科学 · 物理学 2009-11-13 J. L. Ribeiro

Pyroelectric current and magnetoelectric coupling measurements on polycrystalline samples of the quadruple perovskite (LaMn$_{3}$)Mn$_{4}$O$_{12}$ give evidence of ferroelectricity driven by the antiferromagnetic ordering of the $B$-site…

Magnetically-driven ferroelectric atomic displacements of the order of 10$^{-3} Angstrom have been observed in orthorhombic (perovskite like) YMnO$_3$ by a single-crystal synchrotron x-ray diffraction. The refined polar structure shows the…

The ground state structural, electronic and magnetic properties of multiferroic TbMn$_2$O$_5$ are investigated via first-principles calculations. We show that the ferroelectricity in TbMn$_2$O$_5$ is driven by the non-centrosymmetric…

材料科学 · 物理学 2009-11-13 Chenjie Wang , Guang-Can Guo , Lixin He

Multiferroics, where two or more ferroic order parameters coexist, is one of the hottest fields in condensed matter physics and materials science[1-9]. However, the coexistence of magnetism and conventional ferroelectricity is physically…

材料科学 · 物理学 2016-03-11 Xiangang Wan , Hang-Chen Ding , Sergey Y. Savrasov , Chun-Gang Duan

The microscopic origin of the magnetically-driven ferroelectricity in collinear AFM-E orthorhombic manganites is explained by means of first-principles Wannier functions. We show that the polarization is mainly determined by the "asymmetric…

强关联电子 · 物理学 2009-11-13 Kunihiko Yamauchi , Frank Freimuth , Stefan Blügel , Silvia Picozzi

The question of how ferroelectric polarization is coupled to magnetism in magnetoelectric multiferroics, in which both types of order are simultaneously present, is of considerable scientific and practical interest. A recent Letter…

材料科学 · 物理学 2009-07-13 Rogerio de Sousa , Joel E. Moore

In order to clarify the mechanism associated with pressure/magnetic-field-induced giant ferroelectric polarization in TbMnO3, this work investigated changes in magnetic ordering brought about by variations in temperature, magnetic field,…

We demonstrate that small but finite ferroelectric polarization ($\sim$0.01 $\mu$C/cm$^2$) emerges in orthorhombic LuFeO$_3$ ($Pnma$) at $T_N$ ($\sim$600 K) because of commensurate (k = 0) and collinear magnetic structure. The synchrotron…

Orthorhombic HoMnO3 is a multiferroic in which Mn antiferromagnetic order induces ferroelectricity. A second transition occurs within the multiferroic phase, in which a strong enhancement of the ferroelectric polarization occurs…

强关联电子 · 物理学 2021-01-04 Y. W. Windsor , M. Ramakrishnan , L. Rettig , A. Alberca , T. Lippert , C. W. Schneider , U. Staub

In this contribution to the special issue on multiferroics we focus on multiferroicity driven by different forms of charge ordering. We will present the generic mechanisms by which charge ordering can induce ferroelectricity in magnetic…

材料科学 · 物理学 2011-07-22 Jeroen van den Brink , Daniel I. Khomskii

We present a unique example of giant magnetoelectric effect in a conventional multiferroic HoMnO3, where polarization is very large (~56 mC/m2) and the ferroelectric transition temperature is higher than the magnetic ordering temperature by…

强关联电子 · 物理学 2015-05-13 N. Hur , I. K. Jeong , M. F. Hundley , S. B. Kim , S. -W. Cheong

A dielectric anomaly has been found near the incommensurate to commensurate antiferromagnetic phase transition (TN2=230 K) in YBaCuFeO5 ceramics, a compound which crystallizes in an ordered perovskite structure. The existence of electric…

材料科学 · 物理学 2009-03-13 B. Kundys , A. Maignan , Ch. Simon

By directly measuring electrical hysteresis loops using the Positive-Up Negative-Down (PUND) method, we accurately determined the remanent ferroelectric polarization Pr of orthorhombic RMnO3 (R = Ho, Tm, Yb, and Lu) compounds below their…

材料科学 · 物理学 2015-05-30 Y. S. Chai , Y. S. Oh , L. J. Wang , N. Manivannan , S. M. Feng , Y. S. Yang , L. Q. Yan , C. Q. Jin , Kee Hoon Kim

Perovskite manganites with small A-site ions, as the first and canonical branch of type-II multiferroics, are ideal systems to exhibit magnetism-induced ferroelectricity. Despite their established magnetoelectric phase diagrams under low…

材料科学 · 物理学 2026-01-15 Ming Yang , Jun Chen , Junfeng Wang , Chao Dong , Chengliang Lu , Gang Xu , Jinguang Cheng , Jianshi Zhou , Shuai Dong

Multiferroics where at least two primary ferroic orders are present and coupled in a single system constitute an important class of materials. They attracted special consideration as they present both intriguing fundamental physics problems…

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