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The fragment of the 1-methylpyrene cation, C17H11+, is expected to exist in two isomeric forms, 1-pyrenemethylium PyrCH2+ and the tropylium containing species PyrC7+ . We measured the infrared (IR) action spectrum of cold C17H11+ tagged…

化学物理 · 物理学 2018-03-20 Pavol Jusko , Aude Simon , Gabi Wenzel , Sandra Brünken , Stephan Schlemmer , Christine Joblin

Self-assembled monolayers (SAMs) of organic molecules are widely employed in surface chemistry and biology, and serve as ultra-fine lithographic resists. Due to their small thickness of only a few nanometers, the analysis of patterned…

材料科学 · 物理学 2014-10-28 Hadas Alon , Idan Bakish , Josh Nehrer , Assaf Y. Anderson , Chaim N. Sukenik , Avi Zadok , Doron Naveh

Polymorphism, which describes the occurrence of different lattice structures in a crystalline material, is a critical phenomenon in material science and condensed matter physics. It has emerged as a major focus for industry and regulatory…

材料科学 · 物理学 2021-01-26 Kyoung Hwan Choi , Da Young Hwang , Dong Hack Suh

Poly-vinlyacetate (PVAc) forms very stable and reproducible monolayers on the surface of water, a model system to understand polymer physics on two dimensions. A recently introduced technique is applied here to to study viscoelasticity of…

软凝聚态物质 · 物理学 2009-11-11 Toby A. M. Ferenczi , Pietro Cicuta

Synchrotron-X-ray and surface tension studies of a strong polyelectrolyte (PE) in the semi-dilute regime (~ 0.1M monomer-charges) with varying surfactant concentrations show that minute surfactant concentrations induce the formation of a…

软凝聚态物质 · 物理学 2009-11-10 D. Vaknin , S. Dahlke , A. Travesset , G. Nizri , S. Magdassi

We theoretically analyze possible multiple conformations of protein molecules immobilized by 1-pyrenebutanoic-acid-succinimidyl-ester (PASE) linkers on graphene. The activation barrier between two bi-stable conformations exhibited by PASE…

化学物理 · 物理学 2023-12-15 Yasuhiro Oishi , Motoharu Kitatani , Koichi Kusakabe

We report measurements of the x-ray scattering intensity as mesoporous glasses are filled with Neon. We outline a simple model to account for the non-linear increase in the intensity of the first peak in a liquid-like diffraction pattern as…

材料科学 · 物理学 2009-11-13 Duncan Kilburn , Paul E. Sokol

Determination of the pairing symmetry in monolayer FeSe films on SrTiO3 is a requisite for understanding the high superconducting transition temperature in this system, which has attracted intense theoretical and experimental studies but…

Surface sensitive x-ray scattering techniques with atomic scale resolution are employed to investigate the microscopic structure of the surface of three classes of liquid binary alloys: (i) Surface segregation in partly miscible binary…

无序系统与神经网络 · 物理学 2007-05-23 Holger Tostmann , Elaine DiMasi , Oleg G. Shpyrko , Ben M. Ocko , Peter S. Pershan , Moshe Deutsch

The resistance of chemically synthesized polypyrrole (PPy) thin films is investigated as a function of the pressure of various gases as well as of the film thickness. A physical, piezoresistive response is found to coexist with a chemical…

材料科学 · 物理学 2010-05-06 S. Barnoss , H. Shanak , C. Bof Bufon , T. Heinzel

The first three-dimensional simulation of shear-induced phase transitions in a polymeric system has been performed. The method is based on dynamic density-functional theory. The pathways between a bicontinuous phase with developing gyroid…

软凝聚态物质 · 物理学 2009-10-31 A. V. Zvelindovsky , G. J. A. Sevink , J. G. E. M. Fraaije

The structure of an adsorption octadecanamide film at the planar toluene-water interface is studied by X-ray reflectometry using synchrotron radiation with photon energy of 15 keV. The electron density (polarizability) profiles, according…

软凝聚态物质 · 物理学 2020-04-22 Aleksey M. Tikhonov , Yurii O. Volkov

t has been shown that the flow of a simple liquid over a solid surface can violate the so-called no-slip boundary condition. We investigate the flow of polar liquids, water and glycerol, on a hydrophilic Pyrex surface and a hydrophobic…

软凝聚态物质 · 物理学 2009-11-07 C. Cottin-Bizonne , S. Jurine , J. Baudry , J. Crassous , F. Restagno , Charlaix

We calculate the static polarizability of multilayer graphene and study the effect of stacking arrangement, carrier density, and onsite energy difference on graphene screening properties. At low densities, the energy spectrum of multilayer…

材料科学 · 物理学 2012-08-14 Hongki Min , E. H. Hwang , S. Das Sarma

The equilibrium properties of block copolymer micelles confined in polymer thin films are investigated using self-consistent field theory. The theory is based on a model system consisting of AB diblock copolymers and A homopolymers. Two…

软凝聚态物质 · 物理学 2014-01-16 Jiajia Zhou , An-Chang Shi

We propose a model addressing the coupling mechanism between two spatially modulated monolayers. We obtain the mean-field phase diagrams of coupled bilayers when the two monolayers have the same preferred modulation wavelength. Various…

软凝聚态物质 · 物理学 2014-04-22 Yuichi Hirose , Shigeyuki Komura , David Andelman

The growing trend towards engineering interfacial complexion (or phase) transitions has been seen in the grain boundary and solid surface systems.Meanwhile, little attention has been paid to the chemically heterogeneous solid/liquid…

材料科学 · 物理学 2023-05-10 Jiaojiao Liu , Hongtao Liang , Jinfu Li , Brian B. Laird , and Yang Y

Recent experiments and simulations have demonstrated that particle-covered interfaces can exist in stable non-spherical shapes as a result of the steric jamming of the interfacially trapped particles, which confers the interface with…

软凝聚态物质 · 物理学 2010-11-23 Anand Bala Subramaniam , Manouk Abkarian , L. Mahadevan , Howard A. Stone

Within self-consistent field theory we study the phase behaviour of a symmetric binary AB polymer blend confined into a thin film. The film surfaces interact with the monomers via short range potentials. One surface attracts the A component…

统计力学 · 物理学 2009-10-31 M. Mueller , K. Binder , E. V. Albano

We study the phase diagram of a system of spherical particles interacting in three dimensions through a potential consisting of a strict hard core plus a linear repulsive shoulder at larger distances. The phase diagram (obtained…

统计力学 · 物理学 2009-10-31 E. A. Jagla