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The density profile and surface tension for the interface of phase-separated colloid-polymer mixtures have been studied in the framework of the square gradient approximation for both ideal and interacting polymers in good solvent. The…

软凝聚态物质 · 物理学 2009-11-10 A. Moncho-Jorda , B. Rotenberg , A. A. Louis

The impact of impenetrable obstacles on the energetics and equilibrium structure of strongly repulsive directed polymers is investigated. As a result of the strong interactions, regions of severe polymer depletion and excess are found in…

软凝聚态物质 · 物理学 2013-08-30 Anton Souslov , D. Zeb Rocklin , Paul M. Goldbart

Coagulation-flocculation of pollutants and chelation of heavy metal ions are two widely used techniques in wastewater purification. Despite the differences between their respective mechanisms and inherent length scales, they bear much…

软凝聚态物质 · 物理学 2025-11-21 V. Blavatska , Ja. Ilnytskyi , E. Lähderanta

By means of extensive Monte Carlo simulations of the bond fluctuation model, we study the effect of adding AB diblock copolymers on the properties of an interface between demixed homopolymer phases. The parameters are chosen such that the…

软凝聚态物质 · 物理学 2009-10-31 A. Werner , F. Schmid , M. Mueller

A popular concept which describes the structure of polymer interfaces by ``intrinsic profiles'' centered around a two dimensional surface, the ``local interface position'', is tested by extensive Monte Carlo simulations of interfaces…

软凝聚态物质 · 物理学 2009-10-31 A. Werner , F. Schmid , M. Mueller , K. Binder

We investigate the scattering and absorption of light by random ballistic aggregates of spherical monomers. We present a general measure for the porosity of an irregular particle. Three different classes of ballistic aggregates are…

天体物理学 · 物理学 2009-11-13 Yue Shen , B. T. Draine , Eric T. Johnson

We systematically studied the validity and transferability of effective, coarse-grained, pair potentials in ultrasoft colloidal systems. We focused on amphiphilic dendrimers, macromolecules which can aggregate into clusters of overlapping…

软凝聚态物质 · 物理学 2018-02-01 Marta Montes-Saralegui , Gerhard Kahl , Arash Nikoubashman

We study the localisation of lattice polymer models near a permeable interface in two dimensions. Localisation can arise due to an interaction between the polymer and the interface, and can be altered by a preference for the bulk solvent on…

统计力学 · 物理学 2024-07-24 C J Bradly , N R Beaton , A L Owczarek

The effective quasistatic conductivity of composite polymeric electrolytes is studied in terms of a hard-core--penetrable-layer model. Used to incorporate the interface phenomena (such as amorphization of the polymer matrix around filler…

材料科学 · 物理学 2019-11-05 M. Ya. Sushko , A. K. Semenov

Using small-angle neutron scattering and liquid integral equation theory, we relate the structure factor of flexible dendrimers of 4th generation to their average shape. The shape is measured as a radial density profile of monomers…

软凝聚态物质 · 物理学 2009-10-31 C. N. Likos , M. Schmidt , H. Loewen , M. Ballauff , D. Poetschke , P. Lindner

We present results from molecular dynamics simulations of a spherically confined neutral polymer in the presence of crowding agents, studying polymer shapes and conformations as a function of the confining potential, solvent quality and the…

软凝聚态物质 · 物理学 2020-01-29 Kamal Tripathi , Gautam I. Menon , Satyavani Vemparala

A lattice model is presented for the simulation of dynamics in polymeric systems. Each polymer is represented as a chain of monomers, residing on a sequence of nearest-neighbor sites of a face-centered-cubic lattice. The polymers are self-…

软凝聚态物质 · 物理学 2009-11-10 Alexander van Heukelum , G. T. Barkema

The universal density-force relation is analyzed and the correspondent universal amplitude ratio $B_{real}$ is obtained using the massive field theory approach in fixed space dimensions d=3 up to one-loop order. The layer monomer density…

软凝聚态物质 · 物理学 2015-05-20 Z. Usatenko

Obtaining a rigorous and reliable method for linking computer simulations of polymer blends and composites at different length scales of interest is a highly desirable goal in soft matter physics. In this paper a multiscale modeling…

软凝聚态物质 · 物理学 2015-05-19 J. McCarty , M. G. Guenza

The distance-resolved effective interaction between two star polymers in a good solvent is calculated by Molecular Dynamics computer simulations. The results are compared with a pair potential proposed recently by Likos et al. [Phys. Rev.…

软凝聚态物质 · 物理学 2009-10-31 A. Jusufi , M. Watzlawek , H. Loewen

We investigate numerically using the bond--fluctuation model the adsorption of a random AB--copolymer at the interface between two solvents. From our results we infer several scaling relations: the radius of gyration of the copolymer in the…

凝聚态物理 · 物理学 2009-10-28 Gongwen Peng , Jens-Uwe Sommer , Alexander Blumen

We use the lattice model of directed walks to investigate the conformational as well as the adsorption properties of a semiflexible homopolymer chain immersed in a good solvent in two and three dimensions. To account for the stiffness in…

统计力学 · 物理学 2009-11-07 P. K. Mishra , S. Kumar , Y. Singh

A mean-field monomer-dimer model which includes an attractive interaction among both monomers and dimers is introduced and its exact solution rigorously derived. The Heilmann-Lieb method for the pure hard-core interacting case is used to…

数学物理 · 物理学 2015-06-18 Diego Alberici , Pierluigi Contucci , Emanuele Mingione

The conformational behavior of a coarse-grained finite polymer chain near an attractive spherical surface was investigated by means of multicanonical Monte Carlo computer simulations. In a detailed analysis of canonical equilibrium data…

软凝聚态物质 · 物理学 2018-01-03 Handan Arkin , Wolfhard Janke

We study numerically the effective pair potential between star polymers with equal arm lengths and equal number $f$ of arms. The simulations were done for the soft core Domb-Joyce model on the simple cubic lattice, to minimize corrections…

软凝聚态物质 · 物理学 2009-11-10 Hsiao-Ping Hsu , Peter Grassberger