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This work aims to study the energy transfer and recombination processes in N$_{2}$$\left(^{1}\sum^{+}_{g}\right)$+N$\left(^{4}S_{u}\right)$ and O$_{2}$$\left(^{3}\sum^{+}_{g}\right)$+O$\left(^{3}P_{2}\right)$ chemical systems when the…

化学物理 · 物理学 2025-07-15 Aakanksha Notey , Sung Min Jo , Marco Panesi

This work presents a general unifying theoretical framework for quantum non-equilibrium systems. It is based on a re-statement of the dynamical problem as one of inferring the distribution of collision events that move a system toward…

量子物理 · 物理学 2015-03-30 David M. Rogers

Biochemical processes typically involve many chemical species, some in abundance and some in low molecule numbers. Here we first identify the rate constant limits under which the concentrations of a given set of species will tend to…

定量方法 · 定量生物学 2016-01-20 Stephen Smith , Claudia Cianci , Ramon Grima

In Boltzmannian statistical mechanics macro-states supervene on micro-states. This leads to a partitioning of the state space of a system into regions of macroscopically indistinguishable micro-states. The largest of these regions is…

统计力学 · 物理学 2015-10-09 Charlotte Werndl , Roman Frigg

The general Ericksen-Leslie system for the flow of nematic liquid crystals is reconsidered in the non-isothermal case aiming for thermodynamically consistent models. The non-isothermal model is then investigated analytically. A fairly…

偏微分方程分析 · 数学 2015-04-07 Matthias Hieber , Jan Pruess

Using methods of kinetic theory and liquid state theory we propose a description of the non-equilibrium behavior of molecular fluids which takes into account their microscopic structure and thermodynamic properties. The present work…

统计力学 · 物理学 2009-02-24 Umberto Marini Bettolo Marconi , Simone Melchionna

Transition rates in continuously driven steady states were derived in [Evans R M L, 2005 J. Phys. A: Math. Gen. 38, 293] by demanding that no information other than the microscopic laws of motion and the macroscopic observables of the…

统计力学 · 物理学 2009-11-05 Aditi Simha , R. M. L. Evans

We study the non-equilibrium statistical mechanics of a system of freely moving particles, in which binary encounters lead either to an elastic collision or to the disappearance of the pair. Such a system of {\em ballistic annihilation}…

统计力学 · 物理学 2009-11-13 M. I. Garcia de Soria , P. Maynar , G. Schehr , A. Barrat , E. Trizac

The present work revisits the reduction of the nonlinear dynamics of an electromechanical system through a quasi-steady state hypothesis, discussing the fundamental aspects of this type of approach and clarifying some confusing points found…

In self-gravitating stars, two dimensional or geophysical flows and in plasmas, long range interactions imply a lack of additivity for the energy; as a consequence, the usual thermodynamic limit is not appropriate. However, by contrast with…

统计力学 · 物理学 2009-11-13 Freddy Bouchet , Julien Barré , Antoine Venaille

We examine the question of whether the formal expressions of equilibrium statistical mechanics can be applied to time independent non-dissipative systems that are not in true thermodynamic equilibrium and are nonergodic. By assuming the…

统计力学 · 物理学 2007-11-09 Stephen R. Williams , Denis J. Evans

Equilibrium thermodynamics describes the energy exchange of a body with its environment. Here, we describe the global energy exchange of an ideal gas in the Coutte flow in a thermodynamic-like manner. We derive a fundamental relation…

统计力学 · 物理学 2023-07-31 Karol Makuch , Konrad Giżyński , Robert Hołyst , Anna Maciołek , Paweł J. Żuk

We derive a functional for the entropy contributed by any microscopic degrees of freedom as arising from their measurable pair correlations. Applicable both in and out of equilibrium, this functional yields the maximum entropy which a…

统计力学 · 物理学 2023-02-17 Benjamin Sorkin , Joshua Ricouvier , Haim Diamant , Gil Ariel

In this article, we consider a dynamic model of a three-phase power system including nonlinear generator dynamics, transmission line dynamics, and static nonlinear loads. We define a synchronous steady-state behavior which corresponds to…

最优化与控制 · 数学 2018-11-29 Dominic Groß , Catalin Arghir , Florian Dörfler

We describe and demonstrate a method to reconstruct an amplitude equation from the nonlinear relaxation dynamics in the succession of the Rosensweig instability. A flat layer of a ferrofluid is cooled such that the liquid has a relatively…

斑图形成与孤子 · 物理学 2015-05-19 Christian Gollwitzer , Ingo Rehberg , Reinhard Richter

Minimal models of active and driven particles have recently been used to elucidate many properties non-equilibrium systems. However, the relation between energy consumption and changes in the structure and transport properties of these…

软凝聚态物质 · 物理学 2017-08-03 Clara del Junco , Laura Tociu , Suriyanarayanan Vaikuntanathan

The extension of thermodynamic principles to active matter remains a challenge due to the non-equilibrium nature inherent to active systems. In this study, we introduce a framework to assess entropy in our minimal macroscopic experiment…

软凝聚态物质 · 物理学 2024-09-26 Francesco Romanò , Michael Riedl

We propose a novel approach in the study of transport phenomena in dense systems or systems with long range interactions where multiple particle interactions must be taken into consideration. Within Boltzmann's kinetic formalism, we study…

经典物理 · 物理学 2015-06-26 Travis J. Sherman , Johann Rafelski

A positive rate of entropy production at steady state is a distinctive feature of truly non-equilibrium processes. Exact results, while being often limited to simple models, offer a unique opportunity to explore the thermodynamic features…

统计力学 · 物理学 2022-06-29 Henry Alston , Luca Cocconi , Thibault Bertrand

In this paper, explicit method of constructing approximations (the Triangle Entropy Method) is developed for nonequilibrium problems. This method enables one to treat any complicated nonlinear functionals that fit best the physics of a…

统计力学 · 物理学 2016-08-31 A. N. Gorban , I. V. Karlin