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Transport and magnetic measurements and structural and NMR studies have been carried out on (Pr1-yR'y)1-xAxCoO3 {R'=(rare earth elements and Y); A=(Ca, Ba and Sr)} at ambient pressure or under high pressure. The system exhibits a phase…

The solid-state reaction was used to synthesize CoO2 nanostructured material. Cobalt nitrate tetrahydrate and sodium oxide (NaOH) were combined to produce CoO2 nanostructured material. The three synthesized working electrodes were each…

材料科学 · 物理学 2025-02-12 Shoaib Akram , Muneeb ur Rahman , Fazli Maula , Osama Tariq Satti , Shahbaz Afzal , Fawad Ali

A transition-metal oxide NaCo_2O_4 is a layered oxide in which CoO_2 and Na alternately stack along the c axis. Recently we have found that this compound shows unusually large thermopower with low resistivity, which is comparable to those…

材料科学 · 物理学 2007-05-23 I. Terasaki , Y. Sasago , K. Uchinokura

The temperature and pressure dependent electrical resistivity rho(T,P) studies have been performed on BaMn2As2 single crystal in the 4.2 to 300 K range upto of 8.2 GPa to investigate the evolution of its ground state properties. The rho(T)…

强关联电子 · 物理学 2015-05-30 A. T. Satya , Awadhesh Mani , A. Arulraj , N. V. Chandra Shekar , K. Vinod , C. S. Sundar , A. Bharathi

We have compared by $^{23}$Na NMR and magnetic susceptibility the magnetic properties of oriented powder samples of Na$_{x}$CoO$_{2}$ compounds. The NMR spectra are found identical for various samples with nominal $0.50\leq x\leq 0.70,$…

强关联电子 · 物理学 2007-05-23 I. R. Mukhamedchine , H. Alloul , G. Collin , N. Blanchard

We used quantum chemical ab initio methods to determine the effective parameters of Hubbard and $t-J$ models for the $\rm Na_{x}CoO_2$ compounds (x=0 and 0.5). As for the superconducting compound we found the $a_{1g}$ cobalt orbitals above…

强关联电子 · 物理学 2010-07-26 Sylvain Landron , Soret Julien , Marie-Bernadette Lepetit

Here we report the magnetic properties of the layered cobalt oxide system, LixCoO2, in the whole range of Li composition, 0 <= x <= 1. Based on dc-magnetic susceptibility data, combined with results of 59Co-NMR/NQR observations, the…

强关联电子 · 物理学 2009-10-17 T. Motohashi , T. Ono , Y. Sugimoto , Y. Masubuchi , S. Kikkawa , R. Kanno , M. Karppinen , H. Yamauchi

Thermoelectric properties of the layered cobalt oxide system LixCoO2 were investigated in a wide range of Li composition, 0.98 >= x >= 0.35. Single-phase bulk samples of LixCoO2 were successfully obtained through electrochemical…

强关联电子 · 物理学 2011-05-25 T. Motohashi , Y. Sugimoto , Y. Masubuchi , T. Sasagawa , W. Koshibae , T. Tohyama , H. Yamauchi , S. Kikkawa

Transition metal ditellurides with the CdI2-type structure are materials with intriguing superconducting and electronic properties as demonstrated by PdTe2. Gold substituted PdTe2, AuxPd1-xTe2, adopts the CdI2-type structure for a Pd…

Measurements of the superconducting transition temperature Tc have been performed by the inductive method on MgB2 at pressures up to 28 GPa. Tc decreases with applied pressure, exhibiting a cusp at about 9 GPa. We interpret the appearance…

超导电性 · 物理学 2009-11-07 V. G. Tissen , M. V. Nefedova , N. N. Kolesnikov , M. P. Kulakov

In order to investigate the relationship between superconductivity and magnetism in bilayer-hydrate cobaltate Na_x(H_3O)_zCoO_2 \cdot yH_2O, Co nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements were…

超导电性 · 物理学 2009-11-13 Y. Ihara , H. Takeya , K. Ishida , K. Yoshimura , K. Takada , T. Sasaki , H. Sakurai , E. Takayama-Muromachi

High-pressure electrical resistance measurements have been performed on single crystal Ba0.5Sr0.5Fe2As2 platelets to pressures of 16 GPa and temperatures down to 10 K using designer diamond anvils under quasi-hydrostatic conditions with an…

We present theoretical investigations of pressure and temperature driven phase transitions in HgTe quantum wells grown on CdTe buffer. Using the 8-band \textbf{k$\cdot$p} Hamiltonian we calculate evolution of energy band structure at…

材料科学 · 物理学 2016-12-07 S. S. Krishtopenko , I. Yahniuk , D. B. But , V. I. Gavrilenko , W. Knap , F. Teppe

The electronic transport properties and the magnetic susceptibility were measured in detail in $YBaCo_2O_{5.45}$. Close to the so-called metal-insulator transition, strong effects of resistance relaxation, a clear thermal hysteresis and a…

材料科学 · 物理学 2009-11-13 A. Pautrat , P. Boullay , S. Hebert , V. Caignaert

A set of stacked two-dimensional electron systems in a perpendicular magnetic field exhibits a three-dimensional version of the quantum Hall effect if interlayer tunneling is not too strong. When such a sample is in a quantum Hall plateau,…

介观与纳米尺度物理 · 物理学 2009-11-11 J. W. Tomlinson , J. -S. Caux , J. T. Chalker

By using pseudopotential method with local spin density functional approximation, the electronic band structures of Na$_{x}$CoO$_{2}$ are calculated for $x=0.25$, 0.5, 0.75, and $x=1$ in the presence of the structure relaxations. As…

材料科学 · 物理学 2007-05-23 N. Jun , G. -M. Zhang

We report infrared spectra of a Na$_{0.5}$CoO$_2$ single crystal which exhibits a sharp metal-insulator transition near 50 K due to the formation of charge ordering. In comparison with x=0.7 and 0.85 compounds, we found that the spectral…

强关联电子 · 物理学 2009-11-10 N. L. Wang , Dong Wu , G. Li , X. H. Chen , C. H. Wang , X. G. Luo

Na$_{2}$OsO$_{4}$ is an unusual quantum material that, in contrast to the common 5${d}^{2}$ oxides with spins = 1, owns a magnetically silent ground state with spin = 0 and a band gap at Fermi level attributed to a distortion in the…

The layered sodium cobalt oxide NaxCoO2 is studied by electron diffraction for a wide range of sodium contents, 0.15<x<0.75. An extensive series of ordered Na ion-Na vacancy superlattices is found beyond the simple hexagonal average…

超导电性 · 物理学 2007-05-23 H. W. Zandbergen , M. L. Foo , Q. Xu , V. Kumar , R. J. Cava

Rattling-induced superconductivity in the {\beta}-pyrochlore oxide KOs2O6 is investigated under high pressure up to 5 GPa. Resistivity measurements in a high-quality single crystal reveal a gradual decrease in the superconducting transition…