English

Uniform electron gases. I. Electrons on a ring

Strongly Correlated Electrons 2013-08-19 v2 Other Condensed Matter Chemical Physics

Abstract

We introduce a new paradigm for one-dimensional uniform electron gases (UEGs). In this model, nn electrons are confined to a ring and interact via a bare Coulomb operator. We use Rayleigh-Schr\"odinger perturbation theory to show that, in the high-density regime, the ground-state reduced (i.e. per electron) energy can be expanded as \eps(rs,n)=\eps0(n)rs2+\eps1(n)rs1+\eps2(n)+\eps3(n)rs+\eps(r_s,n) = \eps_0(n) r_s^{-2} + \eps_1(n) r_s^{-1} + \eps_2(n) +\eps_3(n) r_s + \ldots, where rsr_s is the Seitz radius. We use strong-coupling perturbation theory and show that, in the low-density regime, the reduced energy can be expanded as \eps(rs,n)=η0(n)rs1+η1(n)rs3/2+η2(n)rs2+\eps(r_s,n) = \eta_0(n) r_s^{-1} + \eta_1(n) r_s^{-3/2} + \eta_2(n) r_s^{-2} + \ldots. We report explicit expressions for \eps0(n)\eps_0(n), \eps1(n)\eps_1(n), \eps2(n)\eps_2(n), \eps3(n)\eps_3(n), η0(n)\eta_0(n) and η1(n)\eta_1(n) and derive the thermodynamic (large-nn) limits of each of these. Finally, we perform numerical studies of UEGs with n=2,3,,10n = 2, 3, \ldots, 10, using Hylleraas-type and quantum Monte Carlo methods, and combine these with the perturbative results to obtain a picture of the behavior of the new model over the full range of nn and rsr_s values.

Keywords

Cite

@article{arxiv.1302.6661,
  title  = {Uniform electron gases. I. Electrons on a ring},
  author = {Pierre-François Loos and Peter M. W. Gill},
  journal= {arXiv preprint arXiv:1302.6661},
  year   = {2013}
}

Comments

13 pages, 6 tables and 1 figure, accepted for publication in J. Chem. Phys

R2 v1 2026-06-21T23:33:18.058Z