English

Leading-order behavior of the correlation energy in the uniform electron gas

Strongly Correlated Electrons 2011-04-26 v3 Other Condensed Matter Chemical Physics Computational Physics

Abstract

We show that, in the high-density limit, restricted M{\o}ller-Plesset (RMP) perturbation theory yields ERMP(2)=π2(1ln2)lnrs+O(rs0)E_{\text{RMP}}^{(2)} = \pi^{-2}(1-\ln 2) \ln r_s + O(r_s^0) for the correlation energy per electron in the uniform electron gas, where rsr_s is the Seitz radius. This contradicts an earlier derivation which yielded ERMP(2)=O(lnlnrs)E_{\text{RMP}}^{(2)} = O(\ln|\ln r_s|). The reason for the discrepancy is explained.

Keywords

Cite

@article{arxiv.1102.5103,
  title  = {Leading-order behavior of the correlation energy in the uniform electron gas},
  author = {Pierre-François Loos and Peter M. W. Gill},
  journal= {arXiv preprint arXiv:1102.5103},
  year   = {2011}
}

Comments

4 pages, accepted for publication in Int. J. Quantum Chem