English

High-density correlation energy expansion of the one-dimensional uniform electron gas

Strongly Correlated Electrons 2013-08-19 v3 Chemical Physics Computational Physics

Abstract

We show that the expression of the high-density (i.e small-rsr_s) correlation energy per electron for the one-dimensional uniform electron gas can be obtained by conventional perturbation theory and is of the form \Ec(rs)=π2/360+0.00845rs+...\Ec(r_s) = -\pi^2/360 + 0.00845 r_s + ..., where rsr_s is the average radius of an electron. Combining these new results with the low-density correlation energy expansion, we propose a local-density approximation correlation functional, which deviates by a maximum of 0.1 millihartree compared to the benchmark DMC calculations.

Keywords

Cite

@article{arxiv.1207.6849,
  title  = {High-density correlation energy expansion of the one-dimensional uniform electron gas},
  author = {Pierre-François Loos},
  journal= {arXiv preprint arXiv:1207.6849},
  year   = {2013}
}

Comments

7 pages, 2 figures, 3 tables, accepted for publication in J. Chem. Phys