Uniform electron gases. I. Electrons on a ring
Abstract
We introduce a new paradigm for one-dimensional uniform electron gases (UEGs). In this model, electrons are confined to a ring and interact via a bare Coulomb operator. We use Rayleigh-Schr\"odinger perturbation theory to show that, in the high-density regime, the ground-state reduced (i.e. per electron) energy can be expanded as , where is the Seitz radius. We use strong-coupling perturbation theory and show that, in the low-density regime, the reduced energy can be expanded as . We report explicit expressions for , , , , and and derive the thermodynamic (large-) limits of each of these. Finally, we perform numerical studies of UEGs with , using Hylleraas-type and quantum Monte Carlo methods, and combine these with the perturbative results to obtain a picture of the behavior of the new model over the full range of and values.
Cite
@article{arxiv.1302.6661,
title = {Uniform electron gases. I. Electrons on a ring},
author = {Pierre-François Loos and Peter M. W. Gill},
journal= {arXiv preprint arXiv:1302.6661},
year = {2013}
}
Comments
13 pages, 6 tables and 1 figure, accepted for publication in J. Chem. Phys