English

Homogeneous electron gas in arbitrary dimensions

Strongly Correlated Electrons 2020-07-14 v2 Quantum Physics

Abstract

The homogeneous electron gas is one of the most studied model systems in condensed matter physics. It is also at the basis of the large majority of approximations to the functionals of density functional theory. As such, its exchange-correlation energy has been extensively studied, and is well-known for systems of 1, 2, and 3 dimensions. Here, we extend this model and compute the exchange and correlation energy, as a function of the Wigner-Seitz radius rsr_s, for arbitrary dimension DD. We find a very different behavior for reduced dimensional spaces (D=1D=1 and 2), our three dimensional space, and for higher dimensions. In fact, for D>3D > 3, the leading term of the correlation energy does not depend on the logarithm of rsr_s (as for D=3D=3), but instead scales polynomialy: cD/rsγD -c_D /r_s^{\gamma_D}, with the exponent γD=(D3)/(D1)\gamma_D=(D-3)/(D-1). In the large-DD limit, the value of cDc_D is found to depend linearly with the dimension. In this limit, we also find that the concepts of exchange and correlation merge, sharing a common 1/rs1/r_s dependence.

Keywords

Cite

@article{arxiv.2005.04934,
  title  = {Homogeneous electron gas in arbitrary dimensions},
  author = {Robert Schlesier and Carlos L. Benavides-Riveros and Miguel A. L. Marques},
  journal= {arXiv preprint arXiv:2005.04934},
  year   = {2020}
}

Comments

9 pages, 2 figure, minor changes

R2 v1 2026-06-23T15:26:55.780Z