English

Correlation energy of the one-dimensional Coulomb gas

Strongly Correlated Electrons 2012-08-15 v2 Mesoscale and Nanoscale Physics Other Condensed Matter Chemical Physics

Abstract

We introduce a new paradigm for finite and infinite strict-one-dimensional uniform electron gases. In this model, nn electrons are confined to a ring and interact via a bare Coulomb operator. In the high-density limit (small-rsr_s, where rsr_s is the Seitz radius), we find that the reduced correlation energy is \Ec(rs,n)=\eps(2)(n)+O(rs)\Ec(r_s,n) = \eps^{(2)}(n) + O(r_s), and we report explicit expressions for \eps(2)(n)\eps^{(2)}(n). In the thermodynamic (large-nn) limit of this, we show that \Ec(rs)=π2/360+O(rs)\Ec(r_s) = - \pi^2/360 + O(r_s). In the low-density (large-rsr_s) limit, the system forms a Wigner crystal and we find that \Ec(rs)=[ln(2π)3/4]rs1+0.359933rs3/2+O(rs2)\Ec(r_s) = -[\ln(\sqrt{2\pi})-3/4] r_s^{-1} + 0.359933 r_s^{-3/2} + O(r_s^{-2}). Using these results, we propose a correlation functional that interpolates between the high- and low-density limits. The accuracy of the functional for intermediate densities is established by comparison with diffusion Monte Carlo results. Application to a non-uniform system is also reported.

Keywords

Cite

@article{arxiv.1207.0908,
  title  = {Correlation energy of the one-dimensional Coulomb gas},
  author = {Pierre-François Loos and Peter M. W. Gill},
  journal= {arXiv preprint arXiv:1207.0908},
  year   = {2012}
}

Comments

4+ pages, 1 table, few typos corrected