大原子电子角动量分布及其对马德鲁规则的偏离
数学物理
2025-06-18 v1 math.MP
摘要
我们证明，中性原子中电子的角动量分布（以占据数计）在原子序数趋于无穷大时，遵循Thomas-Fermi角动量分布。特别地，我们表明，大型原子的角动量分布偏离了广为人知的马德鲁规则。
引用
@article{arxiv.2506.14227,
title = {The angular momentum distribution of electrons in large atoms and its deviation from Madelung's rule},
author = {August Bjerg and Søren Fournais and Peter Hearnshaw and Jan Philip Solovej},
journal= {arXiv preprint arXiv:2506.14227},
year = {2025}
}