通过多重“头 - 体”静电相互作用调控结构可控聚电解质的凝胶形成
软凝聚态物质
2016-02-23 v1
摘要
利用 ATRP 聚合步骤中所用引发剂的性质,调节短链阳离子均聚物的链端官能团,可介导该聚电解质在水中的凝胶形成。流变仪和扩散 NMR 表征表明,中性端基产生低粘度溶液,而带有膦酸阴离子基团则可获得高度均匀的凝胶。这种对聚电解质凝胶形成的新型超分子控制方式,有望在电活性材料领域的多种应用中得到应用。
引用
@article{arxiv.1411.0978,
title = {Mediating gel formation from structurally controlled poly(electrolytes) through multiple "head-to-body" electrostatic interactions},
author = {Hassan Srour and Olivier Ratel and Mathieu Leocmach and Emma A. Adams and Sandrine Denis-Quanquin and Vinukrishnan Appukuttan and Nicolas Taberlet and Sébastien Manneville and Jean-Charles Majesté and Christian Carrot and Chantal Andraud and Cyrille Monnereau},
journal= {arXiv preprint arXiv:1411.0978},
year = {2016}
}