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By combining scanning probe microscopy with Raman and x-ray photoelectron spectroscopies, we investigate the evolution of CVD-grown graphene/Ge(001) as a function of the deposition temperature in close proximity to the Ge melting point,…

The effect of oxygen adsorption on the local structure and electronic properties of monolayer graphene grown on SiC(0001) has been studied by means of Low Energy Electron Microscopy (LEEM), microprobe Low Energy Electron Diffraction…

Materials Science · Physics 2015-06-05 C. Mathieu , B. Lalmi , T. O. Mentes , E. Pallecchi , A. Locatelli , S. Latil , R. Belkhou , A. Ouerghi

Graphene has many unique properties that make it an ideal material for fundamental studies as well as for potential applications. Here we review the recent results on the Raman spectroscopy and imaging of graphene. Raman spectroscopy and…

Materials Science · Physics 2008-10-17 Zhen hua Ni , Ying ying Wang , Ting Yu , Ze xiang Shen

Research on graphene and other two-dimensional (2D) materials, such as silicene, germanene, phosphorene, hexagonal boron nitride (h-BN), graphitic carbon nitride (g-C3N4), graphitic zinc oxide (g-ZnO) and molybdenum disulphide (MoS2), has…

Materials Science · Physics 2016-03-03 Wei Hu , Jinlong Yang

Systematic studies of the gradual fabrication by means of carbon ion-implantation of high-quality 6H-SiC layers on silicon surfaces have been carried out. The fluence of carbon ions varied from 5*10^15 cm-2 to 10^17 cm-2. Results of…

The transition-metal dichalcogenide (TMDC) in the family of $\mathrm{MX}_2$ ($\mathrm{M}=\mathrm{Mo},\mathrm{W}$; $\mathrm{X}=\mathrm{S},\mathrm{Se}$) and the graphene monolayer are atomically thin semiconductors and semimetal,…

Materials Science · Physics 2022-06-15 Cheng-Hsien Yang , Shu-Tong Chang

When epitaxial graphene layers are formed on SiC(0001), the first carbon layer (known as the "buffer layer"), while relatively easy to synthesize, does not have the desirable electrical properties of graphene. The conductivity is poor due…

Materials Science · Physics 2015-05-18 S. Oida , F. R. McFeely , J. B. Hannon , R. M. Tromp , M. Copel , Z. Chen , Y. Sun , D. B. Farmer , J. Yurkas

We present an investigation of the atomic and electronic structure of graphene monolayer islands on the 6H-SiC(000-1)(3x3) (SiC(3x3)) surface reconstruction using scanning tunneling microscopy (STM) and spectroscopy (STS). The orientation…

Materials Science · Physics 2010-01-04 F. Hiebel , P. Mallet , L. Magaud , J. -Y. Veuillen

Uniform, mostly single-layer graphene with enhanced stability is demonstrated over Co film. The polycrystalline Co film deposited on a SiO2/Si substrate gives a continuous graphene layer that is easily transferred without the aid of any…

Materials Science · Physics 2016-04-21 Giampiero Amato , Federico Beccaria , Umberto Vignolo , Federica Celegato

We induced periodic biaxial tensile strain in polycrystalline graphene by wrapping it over a substrate with repeating pillar-like structures with a periodicity of 600 nm. Using Raman spectroscopy, we determined to have introduced biaxial…

Materials Science · Physics 2015-11-09 Marjan Aslani , C. Michael Garner , Suhas Kumar , Dennis Nordlund , Piero Pianetta , Yoshio Nishi

Techniques for mass-production of large area graphene using an industrial scale thin film deposition tool could be the key to the practical realization of a wide range of technological applications of this material. Here, we demonstrate the…

Materials Science · Physics 2013-02-20 Genhua Pan , Mark Heath , David Horsell , M. Lesley Wears

An in vacuo thermal desorption process has been accomplished to form epitaxial graphene (EG) on 4H- and 6H-SiC substrates using a commercial chemical vapor deposition reactor. Correlation of growth conditions and the morphology and…

Single-layer graphene exhibits exceptional mechanical properties attractive for optomechanics: it combines low mass density, large tensile modulus, and low bending stiffness. However, at visible wavelengths, graphene absorbs weakly and…

Optics · Physics 2014-06-10 S. Hossein Mousavi , Peter T. Rakich , Zheng Wang

Path-integral Monte Carlo calculations have been performed to study the $^4$He adsorption on $\gamma$-graphyne, a planar network of benzene rings connected by acetylene bonds. Assuming the $^4$He-substrate interaction described by a…

Materials Science · Physics 2014-09-05 Jeonghwan Ahn , Hoonkyung Lee , Yongkyung Kwon

Optical and electronic properties of two dimensional few layers graphitic silicon carbide (GSiC), in particular monolayer and bilayer, are investigated by density functional theory and found different from that of graphene and silicene.…

Mesoscale and Nanoscale Physics · Physics 2012-05-25 Xiao Lin , Yang Xu , Shisheng Lin , Ayaz Ali Hakro , Te Cao , Hongsheng Chen , Baile Zhang

We report total-energy calculations based on the density-functional theory that clarify microscopic mechanisms of initial stage of graphene formation on the SiC(0001) surface. We explore favorable reactions for desorption of either Si or C…

Materials Science · Physics 2016-11-21 Fumihiro Imoto , Jun-Ichi Iwata , Mauro Boero , Atsushi Oshiyama

In this study, we first show that the argon flow during epitaxial graphene growth is an important parameter to control the quality of the buffer and the graphene layer. Atomic force microscopy (AFM) and low-energy electron diffraction…

Previous experimental observations for H intercalation under graphene on SiC surfaces motivate clarification of configuration stabilities and kinetic processes related to intercalation. From first-principles density-functional-theory (DFT)…

Mesoscale and Nanoscale Physics · Physics 2021-12-08 Yong Han , James W. Evans , Michael C. Tringides

We have demonstrated a new method for the large-area graphene growth, which can lead to a scalable low-cost high-throughput production technology. The method is based on growing single-layer or few-layer graphene films from a molten phase.…

Materials Science · Physics 2010-11-19 Shaahin Amini , Javier Garay , Guanxiong Liu , Alexander A. Balandin , Reza Abbaschian

We use ab initio density functional calculations to determine the interaction of a graphene monolayer with the Si(111) surface. We found that graphene forms strong bonds to the bare substrate and accommodates the 12% lattice mismatch by…

Materials Science · Physics 2015-06-15 Ceren Tayran , Zhen Zhu , Matteo Baldoni , Daniele Selli , Gotthard Seifert , David Tománek