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Cross-sectional transmission electron microscopy (TEM) is used to characterize an amorphous layer observed at the interface in graphite and graphene films grown via thermal decomposition of C-face 4H-SiC. The amorphous layer does not to…

Materials Science · Physics 2015-05-28 R. Colby , M. L. Bolen , M. A. Capano , E. A. Stach

We have investigated the structure of hydrogen-intercalated quasi-free-standing monolayer graphene (QFMLG) grown on 6H-SiC(0001) by employing total-reflection high-energy positron diffraction (TRHEPD). At least nine diffraction spots of the…

Silicon carbide (SiC) is an excellent substrate for growth and manipulation of large scale, high quality epitaxial graphene. On the carbon face (the ($\bar{1}\bar{1}\bar{1}$) or $(000\bar{1}$) face, depending on the polytype), the onset of…

Materials Science · Physics 2019-10-23 Jan Kloppenburg , Lydia Nemec , Björn Lange , Matthias Scheffler , Volker Blum

The temperature-induced shift of the Raman G line in epitaxial graphene on SiC and Ni surfaces, as well as in graphene supported on SiO2, is investigated with Raman spectroscopy. The thermal shift rate of epitaxial graphene on 6H-SiC(0001)…

Mesoscale and Nanoscale Physics · Physics 2011-02-18 Nicola Ferralis , Roya Maboudian , Carlo Carraro

The formation of graphene on the (0001) surface of SiC (the Si-face) is studied by atomic force microscopy, low-energy electron microscopy, and scanning tunneling microscopy/spectroscopy. The graphene forms due to preferential sublimation…

Materials Science · Physics 2023-05-03 Luxmi , N. Srivastava , R. M. Feenstra , P. J. Fisher

Photoemission, from core levels and valence band, and low-energy electron diffraction (LEED) have been employed to investigate the electronic and structural properties of novel graphene-ferromagnetic (G-FM) systems,obtained by intercalation…

The adoption of graphene in electronics, optoelectronics and photonics is hindered by the difficulty in obtaining high quality material on technologically-relevant substrates, over wafer-scale sizes and with metal contamination levels…

A single-crystal sheet of graphene is synthesized on the low-symmetry substrate Ir(110) by thermal decomposition of C$_2$H$_4$ at 1500 K. Using scanning tunneling microscopy, low-energy electron diffraction, angle-resolved photoemission…

We present energy filtered electron emission spectromicroscopy with spatial and wave-vector resolution on few layer epitaxial graphene on SiC$(000-1) grown by furnace annealing. Low energy electron microscopy shows that more than 80% of the…

Materials Science · Physics 2015-05-27 C. Mathieu , N. Barrett , J. Rault , Y. Y. Mi , B. Zhang , W. A. de Heer , C. Berger , E. H. Conrad , O. Renault

Since the advent of graphene, a variety of studies have been performed to elucidate its fundamental physics, or to explore its practical applications. Gate-tunable resistance is one of the most important properties of graphene and has been…

Mesoscale and Nanoscale Physics · Physics 2018-09-28 Taiki Hirahara , Ryoya Ebisuoka , Takushi Oka , Tomoaki Nakasuga , Shingo Tajima , Kenji Watanabe , Takashi Taniguchi , Ryuta Yagi

Heterostructures made of stacked 2D materials with different electronic properties are studied for their potential in creating multifunctional devices. Graphene (G) and hexagonal boron nitride (h-BN) van der Waals (vdW) systems have been…

Materials Science · Physics 2023-03-16 D. P. de Andrade Deus , J. M. J. Lopes , Roberto H. Miwa

The structure of a graphene monolayer on Ir(111) has been investigated {\it in situ} in the growth chamber by surface x-ray diffraction including the specular rod, which allows disentangling the effect of the sample roughness from that of…

Materials Science · Physics 2015-06-25 Fabien Jean , Tao Zhou , Nils Blanc , Roberto Felici , Johann Coraux , Gilles Renaud

We carry out a computational study on the geometric and electronic properties of multi-layers of silicene in different stacking configurations using a state-of-art abinitio density functional theory based calculations. In this work we…

Materials Science · Physics 2015-02-26 C. Kamal , Aparna Chakrabarti , Arup Banerjee , S. K. Deb

Applying time-dependent photoemission we unravel the graphene growth process on a metallic surface by chemical vapor deposition (CVD). Graphene CVD growth is in stark contrast to the standard growth process of two--dimensional films because…

Materials Science · Physics 2015-05-13 Alexander Grüneis , Kurt Kummer , Denis V. Vyalikh

Graphene is formed on SiC(000-1) surfaces (the so-called C-face of the crystal) by annealing in vacuum, with the resulting films characterized by atomic force microscopy, Auger electron spectroscopy, scanning Auger microscopy and Raman…

Materials Science · Physics 2015-05-13 Luxmi , P. J. Fisher , N. Srivastava , R. M. Feenstra , Yugang Sun , J. Kedzierski , P. Healey , Gong Gu

All carbon electronics based on graphene has been an elusive goal. For more than a decade, the inability to produce significant band-gaps in this material has prevented the development of semiconducting graphene. While chemical…

Scanning tunneling microscopy (STM) images are obtained for the first time on few layer and twisted multilayer epitaxial graphene states synthesized on n+ 6H-SiC a-plane non-polar surface. The twisted graphene is determined to have a…

Mesoscale and Nanoscale Physics · Physics 2015-06-23 P. Xu , M. L. Ackerman , S. D. Barber , J. K. Schoelz , P. M. Thibado , V. D. Wheeler , L. O. Nyakiti , R. L. Myers-Ward , C. R. Eddy , D. K. Gaskill

The electronic structure of graphene on Cu(111) and Cu(100) single crystals is investigated using low energy electron microscopy, low energy electron diffraction and angle resolved photoemission spectroscopy. On both substrates the graphene…

We report graphene films composed mostly of one or two layers of graphene grown by controlled carbon precipitation on the surface of polycrystalline Ni thin films during atmospheric chemical vapor deposition(CVD). Controlling both the…

The fundamental properties of graphene are making it an attractive material for a wide variety of applications. Various techniques have been developed to produce graphene and recently we discovered the synthesis of large area graphene by…