Related papers: Understanding the Cavity Born-Oppenheimer Approxim…
Phase-space electronic structure theory offers up a new and powerful approach for tackling problems with coupled nuclear-electronic dynamics in a fashion that goes beyond Born-Oppenheimer (BO) theory. Whereas BO theory stipulates that we…
In quantum simulations and experiments on optomechanical cavities, coherence control is a challenging issue. We propose a scheme of two coupled optomechanical cavities to enhance the intracavity entanglement. Photon hopping is employed to…
We simulate vibrational strong (VSC) and ultrastrong coupling (V-USC) for liquid water with classical molecular dynamics simulations. When the cavity modes are resonantly coupled to the O-H stretch mode of liquid water, the infrared…
It has been experimentally demonstrated that reaction rates for molecules embedded in microfluidic optical cavities are altered when compared to rates observed under "ordinary" reaction conditions. However, precise mechanisms of how strong…
We illustrate and examine diverse approaches to the quantum matter-gravity system which refer to the Born-Oppenheimer (BO) method. In particular we first examine a quantum geometrodynamical approach introduced by other authors in a manner…
In this work, we present the analytical derivation and implementation of the quantum electrodynamics Hartree-Fock Hessian. We investigate how electronic strong coupling influences molecular vibrational properties, applying this framework to…
We study cavity quantum electrodynamics of Bose-condensed atoms that are subjected to continuous monitoring of the light leaking out of the cavity. Due to a given detection record of each stochastic realization, individual runs…
Cavity electro-(opto-)mechanics allows us to access not only single isolated but also multiple mechanical modes in a massive object. Here we develop a multi-mode electromechanical system in which a several membrane vibrational modes are…
A generalized approach of the Born-Oppenheimer approximation is developed to analytically deal with the influence exercised by the spatial motion of atom's mass-center on a two-level atom in an optical ring cavity with a quantized…
The rapid progress in quantum-optical experiments especially in the field of cavity quantum electrodynamics and nanoplasmonics, allows to substantially modify and control chemical and physical properties of atoms, molecules and solids by…
We develop a comprehensive theoretical model for the interaction strength between a pair of exciton-polaritons in microcavity devices. Ab initio numerical calculations for dipolar polaritons in one dimension are used as a starting point to…
We assess the cavity molecular dynamics method for the calculation of vibrational polariton spectra, using liquid water as a specific example. We begin by disputing a recent suggestion that nuclear quantum effects may lead to a broadening…
Basics of the Born-Oppenheimer (B-O) approximation are reviewed. Assuming the domain of applicability of B-O approximation is limited to 4 significant digits (s.d.) in energy spectrum, where mass, relativistic and QED corrections do NOT…
Using a controlled analytic non-perturbative treatment, that accounts for the quantum nature of the phonons, we derive a model that generically describes cooperative breathing-mode at strong electron-phonon interaction in one-band…
Experiments show that light-matter strong coupling affects chemical properties, though the underlying mechanism remains unclear. We present an ab initio quantum electrodynamics coupled cluster method for the collective strong coupling…
We present an efficient quantum algorithm for beyond-Born-Oppenheimer molecular energy computations. Our approach combines the quantum full configuration interaction method with the nuclear orbital plus molecular orbital (NOMO) method. We…
The ultrastrong and deep strong coupling regimes exhibit a variety of intriguing physical phenomena. In this work, we utilize the Hopfield model of a two-mode bosonic system, with each mode interacts with a heat reservoir, to research the…
The dispersive interaction of a Bose-Einstein condensate with a single mode of a high-finesse optical cavity realizes the radiation pressure coupling Hamiltonian. In this system the role of the mechanical oscillator is played by a single…
Several years ago, it was shown that strong coupling between an electronic transition in organic molecules and a resonant photonic structure can modify the electronic landscape of the molecules and affect their chemical behavior. Since…
In this work we develop tools that enable the study of non-adiabatic effects with variational and diffusion Monte Carlo methods. We introduce a highly accurate wave function ansatz for electron-ion systems that can involve a combination of…