Related papers: Understanding the Cavity Born-Oppenheimer Approxim…
Starting from a microscopic model, we investigate the optical spectra of molecules in strongly-coupled organic microcavities examining how they might self-consistently adapt their coupling to light. We consider both rotational and…
In pre-Born-Oppenheimer (pre-BO) theory a molecule is considered as a quantum system as a whole, including the electrons and the atomic nuclei on the same footing. This approach is fundamentally different from the traditional quantum…
In the previous paper [M. Tsang, Phys. Rev. A 81, 063837 (2010), e-print arXiv:1003.0116], I proposed a quantum model of a cavity electro-optic modulator, which can coherently couple an optical cavity mode to a microwave resonator mode and…
Laser-induced molecular alignment is well understood within the framework of the Born-Oppenheimer (BO) approximation Without the BO approximation, however, the concept of molecular structure is lost, making alignment hard to define…
We report the experimental study of a hybrid quantum solid state system comprising two-level artificial atoms coupled to cavity confined optical and vibrational modes. In this system combining cavity quantum electrodynamics and cavity…
We propose a theoretical protocol to create the entanglement of two qubits via the Born-Oppenheimer (BO) approximation. In our scheme, each qubit is coupled to a faster data bus whose frequency is much larger than the energy spacing of the…
We study entanglement of the cavity modes in a double-cavity optomechanical system in strong-coupling regime. The system consists of two optomechanical systems coupled by a single photon hopping between them. With the radiation pressure of…
Quantum computing has the potential to reduce the computational cost required for quantum dynamics simulations. However, existing quantum algorithms for coupled electron-nuclear dynamics simulation either require fault-tolerant devices, or…
Recent experiments have observed that the chemical and photophysical properties of molecules can be modified inside an optical Fabry-Perot microcavity under collective vibrational strong coupling (VSC) conditions, and such modification is…
A complex quantum system can be constructed by coupling simple quantum elements to one another. For example, trapped-ion or superconducting quantum bits may be coupled by Coulomb interactions, mediated by the exchange of virtual photons.…
The ground state of a cavity-electron system in the ultrastrong coupling regime is characterized by the presence of virtual photons. If an electric current flows through this system, the modulation of the light-matter coupling induced by…
We investigate the entanglement between electronic and vibrational degrees of freedom produced by a vibronic coupling in a molecular system described in the Born-Oppenheimer approximation. Entanglement in a pure state of the Hilbert space…
We present a quantum theory for a fully coupled hybrid optomechanical system where all mutual couplings between a two-level atom, a confined photon mode and a mechanical oscillator mode are considered. In such a configuration, new quantum…
We consider composite bosons (cobosons) comprised of two elementary particles, fermions or bosons, in an entangled state. First, we show that the effective number of cobosons implies the level of correlation between the two constituent…
The interaction of organic molecules and molecular aggregates with electromagnetic fields that are strongly confined inside optical cavities within nanoscale volumes, has allowed the observation of exotic quantum regimes of light-matter…
We compute the ab-initio electron density beyond the strict Born-Oppenheimer approximation in crystalline LiH and LiD with density functional methods. By taking into account the quantum mechanical nature of the nuclei, an aspect absent in…
The idea that excitonic state (electronic) coherences are of fundamental importance to natural photosynthesis gained popularity when, a decade ago, slowly dephasing quantum beats were observed in the two-dimensional electronic spectra of…
We address the question to what extent the centre-of-mass (COM) separation can change our view of the many-body problem in quantum chemistry and solid state physics. It was shown that the many-body treatment based on the…
The coherent strong coupling of molecules with confined light fields to create polaritons - part matter, part light - is opening exciting opportunities ranging from extended exciton transport and inter-molecular energy transfer to modified…
We investigate the effect of a cavity on nonlinear two-photon transitions of a molecular system and how such an effect depends on the cavity quality factor, the field enhancement and the possibility of dephasing. We find that the molecular…