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An optical cavity enhances the interaction between atoms and light, and the rate of coherent atom-photon coupling can be made larger than all decoherence rates of the system. For single atoms, this strong coupling regime of cavity quantum…

Quantum Physics · Physics 2007-11-10 Yves Colombe , Tilo Steinmetz , Guilhem Dubois , Felix Linke , David Hunger , Jakob Reichel

We show that a phase space electronic Hamiltonian $\hat{H}_{PS}(\mathbf{X},\mathbf{P})$, parameterized by both nuclear position $\mathbf{X}$ and momentum $\mathbf{P}$, can recover not just experimental vibrational circular dichroism (VCD)…

We show that coupling ultracold atoms in optical lattices to quantized modes of an optical cavity leads to quantum phases of matter, which at the same time posses properties of systems with both short- and long-range interactions. This…

Quantum Gases · Physics 2016-07-06 Santiago F. Caballero-Benitez , Gabriel Mazzucchi , Igor B. Mekhov

Energy transfer between chromophores in photosynthesis proceeds with near unity quantum efficiency. Understanding the precise mechanisms of these processes is made difficult by the complexity of the electronic structure and interactions…

Chemical Physics · Physics 2015-03-03 Gethin H. Richards , Krystyna E. Wilk , Paul M. G. Curmi , Jeffrey A. Davis

The fields of cavity quantum electrodynamics and magnetism have recently merged into \textit{`cavity spintronics'}, investigating a quasiparticle that emerges from the strong coupling between standing electromagnetic waves confined in a…

Room temperature cavity quantum electrodynamics with molecular materials in optical cavities offers exciting prospects for controlling electronic, nuclear and photonic degrees of freedom for applications in physics, chemistry and materials…

Quantum Physics · Physics 2025-01-15 Felipe Herrera , William L. Barnes

Cavity cooling of an atom works best on a cyclic optical transition in the strong coupling regime near resonance, where small cavity photon numbers suffice for trapping and cooling. Due to the absence of closed transitions a straightforward…

Quantum Physics · Physics 2012-11-13 R. J. Schulze , C. Genes , H. Ritsch

When atoms come together and bond, we call these new states molecules, and their properties determine many aspects of our daily life. Strangely enough, it is conceivable for light and molecules to bond, creating new hybrid light-matter…

Materials Science · Physics 2018-02-19 Branko Kolaric , Bjorn Maes , Koen Clays , Thomas Durt , Yves Caudano

Achieving strong coupling between light and matter is usually a challenge in Cavity Quantum Electrodynamics (cQED), especially in solid state systems. For this reason is useful taking advantage of alternative approaches to reach this…

Mesoscale and Nanoscale Physics · Physics 2018-03-07 J. E. Ramírez-Muñoz , J. P. Restrepo Cuartas , H. Vinck-Posada

One of the most popular subjects now being researched in molecular science is strong light-matter coupling. The introduction of vibrational strong coupling and the formation vibro-polaritonic states tend to modify chemical reactivity,…

Chemical Physics · Physics 2023-08-10 Akhila Kadyan , Monu P. Suresh , Ben Johns , Jino George

Cavity optomechanics aims to establish optical control over vibrations of mechanical systems, to heat, cool or to drive them toward coherent, or nonclassical states. This field was recently extended to include molecular optomechanics, which…

Quantum Physics · Physics 2023-06-28 Mikołaj K. Schmidt , Michael J. Steel

The Born-Oppenheimer (BO) approximation is less accurate in the presence of a strong magnetic field than in the absence of a field. This is due to the complicated and unpredictable response of electronic structure to the field, especially…

Chemical Physics · Physics 2023-03-29 Tanner Culpitt , Laurens D. M. Peters , Erik I. Tellgren , Trygve Helgaker

We determine the quantum ground-state properties of ultracold bosonic atoms interacting with the mode of a high-finesse resonator. The atoms are confined by an external optical lattice, whose period is incommensurate with the cavity mode…

Quantum Gases · Physics 2013-02-14 Hessam Habibian , André Winter , Simone Paganelli , Heiko Rieger , Giovanna Morigi

Recent progress in the field of molecular electronics has revealed the fundamental importance of the coupling between the electronic degrees of freedom and specific vibrational modes. Considering the examples of a molecular dimer and a…

Mesoscale and Nanoscale Physics · Physics 2017-02-22 Jakub K. Sowa , Jan A. Mol , G. Andrew D. Briggs , Erik M. Gauger

The interaction of atoms and molecules with quantum light as realized in cavities has become a highly topical and fast growing field of research. This interaction leads to the formation of hybrid light-matter states giving rise to new…

Chemical Physics · Physics 2022-12-15 Lorenz S. Cederbaum , Jacqueline Fedyk

Cavity quantum electrodynamics (cavity QED) describes the coherent interaction between matter and an electromagnetic field confined within a resonator structure, and is providing a useful platform for developing concepts in quantum…

The observation that materials can change their properties when placed inside or near an optical resonator, has sparked a fervid interest in understanding the effects of strong light-matter coupling on molecular dynamics, and several…

Chemical Physics · Physics 2024-03-20 Ilia Sokolovskii , Gerrit Groenhof

We describe a qualitatively new regime of cavity quantum electrodynamics, the super strong coupling regime. This regime is characterized by atom-field coupling strengths of the order of the free spectral range of the cavity, resulting in a…

Quantum Physics · Physics 2009-11-13 D. Meiser , P. Meystre

Within the nuclear-electronic orbital (NEO) framework, the real-time NEO time-dependent density functional theory (RT-NEO-TDDFT) approach enables the simulation of coupled electronic-nuclear dynamics. In this approach, the electrons and…

Chemical Physics · Physics 2023-03-22 Tao E. Li , Sharon Hammes-Schiffer

The spectacular experimental results of the last few years in cavity quantum electrodynamics and trapped ions research has led to very high level laboratory performances. Such a stimulating situation essentially stems from two decisive…

Quantum Physics · Physics 2015-06-26 A. Messina , S. Maniscalco , A. Napoli
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