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Cu(In,Ga)Se2 based solar cells exceed power conversion efficiencies of 23 %. Yet, the fill factor of these solar cells, with best values around 80 %, is relatively low (Si reaches 84.9%) mostly due to diode factors greater than one.…

Interface recombination at the absorber buffer interface impedes the efficiency of a solar cell with an otherwise excellent absorber. The internal voltage or the quasi-Fermi level splitting (qFLs) measures the quality of the absorber.…

Solar cells are crucial for addressing global energy issues, with research focused on improving their efficiency. This study examines the impact of doping concentration gradients on solar cell performance. Doping involves adding impurities…

Applied Physics · Physics 2024-07-18 Jeonggyu Hwang

Recombination losses contribute to reduce $J_{SC}$, $V_{OC}$ and the fill factor of organic solar cells. Recent advances in non-fullerene organic photovoltaics have shown, nonetheless, that efficient charge generation can occur under small…

Materials Science · Physics 2022-11-24 Artur M. Andermann , Luis G. C. Rego

Most traditional semiconductor materials are based on the control of doping densities to create junctions and thereby functional and efficient electronic and optoelectronic devices. The technology development for halide perovskites had…

Materials Science · Physics 2021-12-08 Basita Das , Irene Aguilera , Uwe Rau , Thomas Kirchartz

We analysed self-consistently photoconversion efficiency of direct-gap A3B5 semicon-ductors based solar cells and optimised their main physical characteristics. Using gallium ar-senide (GaAs) as the example and new efficient optimization…

Materials Science · Physics 2014-02-14 A. V. Sachenko , V. P. Kostylyov , M. R. Kulish , I. O. Sokolovskyi , A. Chkrebtii

The InAs/InGaAs DWELL solar cell grown by MBE is a standard pin diode structure with six layers of InAs QDs embedded in InGaAs quantum wells placed within a 200-nm intrinsic GaAs region. The GaAs control wafer consists of the same pin…

Mesoscale and Nanoscale Physics · Physics 2019-06-05 Tingyi Gu , Mohamed A. El-Emawy , Kai Yang , Andreas Stintz , Luke F. Lester

The theoretical analysis of photovoltaic conversion efficiency of highly effective silicon solar cells (SC) is performed for n-type and p-type bases. The case is considered when the Shockley-Read-Hall recombination in the silicon bulk is…

Reducing the thickness of Cu(In,Ga)Se2 solar cells is a key objective in order to reduce production cost and to improve sustainability. The major challenge for sub-micron Cu(In,Ga)Se2 cells is the recombination at the backside. In standard…

CdTe-based thin film solar cell has been modeled and enumerated with a thin CuInTe2 (CIT) current booster layer. CdTe-based n-CdS/p-CdTe/p+-CIT/p++-WSe2 heterojunction device has been evaluated for the highest performance. It is revealed…

The observed open circuit voltages in best performing solar cells are explained outside of the recombination paradigm, based on such factors as electrostatic screening, Meyer-Neldel effect, and lateral nonuniformities. The underlying…

Materials Science · Physics 2023-07-04 Victor Karpov , Diana Shvydka

The enhancement of the fill factor in the current generation of perovskite solar cells is the key for further efficiency improvement. Thus, methods to quantify the fill factor losses are urgently needed. A classical method to quantify Ohmic…

Applied Physics · Physics 2022-07-07 David Grabowski , Zhifa Liu , Gunnar Schöpe , Uwe Rau , Thomas Kirchartz

We considered modification of the defect density of states in CdTe as influenced by a buffer layer in ZnO(ZnS, SnSe)/CdS/CdTe solar cells. Compared to the solar cells employing ZnO buffer layers, implementation of ZnSe and ZnS resulted in…

Materials Science · Physics 2016-01-15 Y. G. Fedorenko , J. D. Major , A. Pressman , L. Phillips , K. Durose

We develop a new approach to calculate the obtainable limit of photoconversion efficiency of tandem solar cells (SCs) and applied it to SCs with both vertical and lateral designs at AM0 and AM1.5 conditions. To get the maximum efficiency,…

Materials Science · Physics 2013-09-13 A. V. Sachenko , V. P. Kostylyov , N. P. Kulish , I. O. Sokolovskyi , A. I. Shkrebtii

Radiative and non-radiative charge carrier recombination in thin-film diodes plays a key role in determining the efficiency of electronic devices made of next generation semiconductors such as organic, perovskite and nanocrystals. In this…

Applied Physics · Physics 2019-08-06 Oskar J. Sandberg , Ardalan Armin

The recombination of charges is an important process in organic photonic devices because the process influences the device characteristics such as the driving voltage, efficiency and lifetime. By combining the dipole trap theory with the…

Materials Science · Physics 2017-08-04 Chang-Heon Lee , Jeong-Hwan Lee , Kwon-Hyeon Kim , Jang-Joo Kim

Unintentional doping of the active layer is a source for lowered device performance in organic solar cells. The effect of doping is to induce a space-charge region within the active layer, generally resulting in increased recombination…

The results of our researches of the influence of exponentially distributed surface centers on the effective surface recombination rate and the parameters of silicon solar cells (SCs) are reported. In our calculations, we assumed the…

Materials Science · Physics 2013-04-30 V. P. Kostylyov , A. V. Sachenko , I. O. Sokolovskyi , V. V. Chernenko , T. V. Slusar , A. V. Sushyi

Recently, much effort has been devoted to improve the efficiency of organic photovoltaic solar cells based on blends of donors and acceptors molecules in bulk heterojunction architecture. One of the major losses in organic photovoltaic…

Materials Science · Physics 2013-03-05 Ye Zhang , Tek P. Basel , Bhoj R. Gautam , Xiaomei Yang , Debra J. Mascaro , Feng Liu , Z. Valy Vardeny

There is evidence that interface recombination in Cu2ZnSnS4 solar cells contributes to the open-circuit voltage deficit. Our hybrid density functional theory calculations suggest that electron-hole recombination at the Cu2ZnSnS4/CdS…

Materials Science · Physics 2019-01-23 Ji-Sang Park , Sunghyun Kim , Samantha N. Hood , Aron Walsh
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