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The ideality factor determined by measuring the open circuit voltage (VOC) as function of light intensity is often used as a means to identify the dominant recombination mechanism in solar cells. However, applying this Suns-VOC technique to…

Since the photoconversion efficiency $\eta$ of the silicon-based solar cells (SCs) under laboratory conditions is approaching the theoretical fundamental limit, further improvement of their performance requires theoretical modeling and/or…

Materials Science · Physics 2024-09-04 V. P. Kostylyov , A. V. Sachenko , M. Evstigneev , I. O. Sokolovskyi , A. I. Shkrebtii

A theoretical approach to photoconversion efficiency modeling in perovskite p-i-n structures is developed. The results of this modeling compare favorably with the experiment and indicate that the surfaces of the perovskite solar cells (SCs)…

Mesoscale and Nanoscale Physics · Physics 2017-04-06 A. V. Sachenko , V. P. Kostylyov , A. V. Bobyl , V. M. Vlasyuk , I. O. Sokolovskyi , E. I. Terukov , M. Evstigneev

The ability to reduce energy loss at semiconductor surfaces through passivation or surface field engineering has become an essential step in the manufacturing of efficient photovoltaic (PV) and optoelectronic devices. Similarly, surface…

The thermodynamic limit for the efficiency of solar cells is predominantly defined by the energy bandgap of the used semiconductor. In case of organic solar cells both energetics and kinetics of three different species play role: excitons,…

Applied Physics · Physics 2021-07-02 Oskar J Sandberg , Ardalan Armin

In this research, the effect of Magnesium Fluoride (MgF2) Anti-Reflection (AR) layer was investigated in quantum dot sensitized solar cells (QDSCs). MgF2 nanoparticles with the dominant size of 20 nm were grown by a thermal evaporation…

Materials Science · Physics 2020-06-30 Farzaneh Ahangarani Farahani , Atila Poro , Maryam Rezaee , Mehdi Sameni

The presence of unreacted lead iodide in organic-inorganic lead halide perovskite solar cells is widely correlated with an increase in power conversion efficiency. We investigate the mechanism for this increase by identifying the role of…

Electronic structure calculations within screened-exchange hybrid density functional theory show that Cu(In,Ga) antisites in both CuInSe2 and CuGaSe2 are localized hole traps, which can be attributed to the experimentally observed N2 level.…

Materials Science · Physics 2012-05-14 Johan Pohl , Thomas Unold , Karsten Albe

Previous studies of reverse-bias stability in perovskite solar cells have focused primarily on voltage controlled reverse-bias tests. Here we instead present an investigation of perovskite solar cell degradation under well-defined, constant…

The density of states (DOS) is fundamentally important for understanding physical processes in organic disordered semiconductors, yet hard to determine experimentally. We evaluated the DOS by considering recombination via tail states and…

Surface recombination has a major impact on the open-circuit voltage ($V_\text{oc}$) of organic photovoltaics. Here, we study how this loss mechanism is influenced by imbalanced charge transport in the photoactive layer. As a model system,…

The purpose of this work is to look for a practical structure for application of quantum dots (QD) in solar cells in order to enhance sub-band gap photon absorption. We focuse on a stack of strain-compensated GaSb/GaAs type-II QDs. We…

Mesoscale and Nanoscale Physics · Physics 2014-10-17 A. Kechiantz , A. Afanasev , J. -L. Lazzari

The increase of cell efficiency resulting from using a diffraction grating as a back reflector is investigated. An enhancement coefficient is introduced as a figure of merit that accounts for the ability of the rear grating to increase the…

Optics · Physics 2008-11-20 Mario M. Jakas , Francisco Llopis

A combination of transient photovoltage (TPV), voltage dependent charge extraction (CE) and time delayed collection field (TDCF) measurements is applied to poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl]…

Applied Physics · Physics 2021-06-21 A. Foertig , J. Kniepert , M. Gluecker , T. Brenner , V. Dyakonov , D. Neher , C. Deibel

Thin-film solar cells suffer from various types of recombination, of which leakage current usually dominates at lower voltages. Herein, we demonstrate first a three-order reduction of the shunt loss mechanism in planar methylammonium lead…

Record efficiency in chalcopyrite-based solar cells Cu(In,Ga)(S,Se)2 is achieved using a gallium gradient to increase the band gap of the absorber towards the back side. Although this structure has successfully reduced recombination at the…

Traditional CdS buffer layer in selenium-free Cu(In,Ga)S2 solar cells leads to reduced open-circuit voltage because of a negative conduction band offset at the Cu(In,Ga)S2/CdS interface. Reducing this loss necessitates the substitution of…

CdTe is a key thin-film photovoltaic technology. Non-radiative electron-hole recombination reduces the solar conversion efficiency from an ideal value of 32% to a current champion performance of 22%. The cadmium vacancy (V_Cd) is a…

Materials Science · Physics 2021-06-21 Seán R. Kavanagh , Aron Walsh , David O. Scanlon

In this article, we investigate the effect of prolonged light exposure on silicon heterojunction solar cells. We show that, although light exposure systematicallyimproves solar cell efficiency in the case of devices using intrinsic and…

The thickness dependences of the photocurrent quantum yield and photoenergy parameters of silicon backside contact solar cells (BC SC) are investigated theoretically and experimentally. The surface recombination rate on the irradiated…

Materials Science · Physics 2011-03-15 A. P. Gorban , V. P. Kostylyov , A. V. Sachenko , O. A. Serba , I. O. Sokolovskyi , V. V. Chernenko