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We report here an experimental setup to perform three-pulse pump-probe measurements over a wide wavelength and temperature range. By combining two pump pulses in the visible (650-900 nm) and mid-IR (5-20 $\mu$m) range, with a broadband…

Accelerator mass spectrometry (AMS) is a widely-used technique with multiple applications, including geology, molecular biology and archeology. In order to achieve a high dynamic range, AMS requires tandem accelerators and large magnets,…

Quantum Physics · Physics 2023-05-23 Radu Ionicioiu

Nonlinear spectroscopy provides a unique perspective to understand time-resolved molecular dynamics under vibrational strong coupling (VSC). Herein, equilibrium-nonequilibrium cavity molecular dynamics simulations are performed to compute…

Chemical Physics · Physics 2026-03-26 Xinwei Ji , Tomislav Begusic , Tao E. Li

Mid infrared (MIR) photonics is a key region for molecular physics [1]. High-resolution spectroscopy in the 1--10 {\mu}m region, though, has never been fully tackled for the lack of widely-tunable and practical light sources. Indeed, all…

Nonlinear optical microscopy allows rapid high-resolution microscopy with image contrast generated from intrinsic properties of the sample. Established modalities such as multiphoton excited fluorescence and second/third-harmonic generation…

Quantum spectroscopy seeks to probe chemical systems using nonclassical light, which has properties that are qualitatively and quantitatively different than conventional light sources. One promising technique uses intensity-correlated twin…

Infrared vibrational spectroscopy in the gas phase has emerged as a powerful tool to determine complex molecular structures with Angstrom accuracy. Among the different approaches IRMPD (InfraRed Multiple Photon Dissociation), which requires…

Chemical Physics · Physics 2024-06-24 Oznur Yeni , Baptiste Schindler , Baptiste Moge , Isabelle Compagnon

Dual-comb spectroscopy has been proven a powerful tool in molecular characterization, which remains challenging to implement in the mid-infrared region due to difficulties in the realization of two mutually locked comb sources and efficient…

Mid-infrared spectroscopy probes molecular vibrations to identify chemical species and functional groups. Therefore, mid-infrared hyperspectral imaging is one of the most powerful and promising candidates for chemical imaging using optical…

Optics · Physics 2023-07-06 Yue Zhao , Shota Kusama , Yuji Furutani , Wei-Hong Huang , Chih-Wei Luo , Takao Fuji

In the realm of cerebrovascular monitoring, primary metrics typically include blood pressure, which influences cerebral blood flow (CBF) and is contingent upon vessel radius. Measuring CBF non-invasively poses a persistent challenge,…

High resolution and fast detection of molecular vibrational absorption is important for organic synthesis, pharmaceutical process and environmental monitoring, and is enabled by mid-infrared (mid-IR) laser frequency combs via dual-comb…

The structures of interfaces of nano- and microscale objects in aqueous solution are important for a wide variety of physical, chemical and biological processes. Vibrational sum frequency scattering has emerged as a useful and unique probe…

Chemical Physics · Physics 2020-07-22 Sergey Kulik , Saranya Pullanchery , Sylvie Roke

We describe a new approach based on semiclassical molecular dynamics that allows to simulate infrared absorption or emission spectra of molecular systems with inclusion of anharmonic intensities. This is achieved from semiclassical power…

Chemical Physics · Physics 2018-11-12 Marco Micciarelli , Riccardo Conte , Jaime Suarez , Michele Ceotto

The broad and equidistant spectrum of frequency combs has had a profound impact on spectroscopic studies. Particularly, experiments involving the coupling of frequency combs to cavities have already enabled unprecedented broadband and…

Optics · Physics 2024-12-10 Andrei Diakonov , Konstantin Khrizman , Eliran Zano , Liron Stern

Broadband, high resolution and rapid measurement of dual-comb spectroscopy (DCS) generates a large amount of data stream. We numerically demonstrate significant data compression of DCS spectra by using a compressive sensing technique. Our…

Signal Processing · Electrical Eng. & Systems 2025-05-06 Akira Kawai , Takahiro Kageyama , Ryoichi Horisaki , Takuro Ideguchi

Vibrational spectroscopy is a ubiquitous technology that derives the species, constituents, and morphology of an object from its natural vibrations. However, the vibrational spectra of mesoscopic particles - including most biological cells…

Optical two-dimensional coherent spectroscopy (2DCS) has become a powerful tool for studying energy level structure, dynamics, and coupling in many systems including atomic ensembles. Various types of two-dimensional (2D) spectra, including…

Atomic Physics · Physics 2022-05-25 Jieli Yan , Stephen Revesz , Danfu Liang , Hebin Li

We extend the technique of multiplex coherent Raman spectroscopy with two femtosecond mode-locked lasers to oscillators of a pulse repetition frequency of 1 GHz. We demonstrate spectra of liquids, which span 1100 cm$^{-1}$ of Raman shifts.…

Cavity-enhanced direct frequency comb spectroscopy combines broad spectral bandwidth, high spectral resolution, precise frequency calibration, and ultrahigh detection sensitivity, all in one experimental platform based on an optical…

Optics · Physics 2009-11-13 Michael J. Thorpe , Jun Ye

We report on broad instantaneous bandwidth microwave spectrum analysis with hot $^{87}\mathrm{Rb}$ atoms in a microfabricated vapor cell in a large magnetic field gradient. The sensor is a MEMS atomic vapor cell filled with isotopically…

Atomic Physics · Physics 2024-08-13 Yongqi Shi , Thomas Ruster , Melvyn Ho , Sylvain Karlen , Jacques Haesler , Philipp Treutlein