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Mid-infrared (mid-IR) spectroscopy offers unparalleled sensitivity for the detection of trace gases, solids and liquids, which is based on the existence of strong telltale vibrational bands in this part of the spectrum. It was shown more…

Optics · Physics 2016-08-29 Viktor O. Smolski , Honglei Yang , Jia Xu , Konstantin L. Vodopyanov

Molecular spectroscopy in the mid-infrared portion of the electromagnetic spectrum (3--25 um) has been a cornerstone interdisciplinary analytical technique widely adapted across the biological, chemical, and physical sciences. Applications…

Instrumentation and Detectors · Physics 2018-09-18 Abijith S. Kowligy , Henry Timmers , Alex Lind , Ugaitz Elu , Flavio C. Cruz , Peter G. Schunemann , Jens Biegert , Scott A. Diddams

We demonstrate low-frequency interferometric impulsive stimulated Raman scattering (ISRS) imaging with high robustness to distortions by optical scattering. ISRS is a pump-probe coherent Raman spectroscopy that can capture Raman vibrational…

The potential of frequency comb spectroscopy has aroused great interest in generating mid-infrared frequency combs in the integrated photonic setting. However, despite remarkable progress in microresonators and quantum cascade lasers, the…

Quantum cascade laser (QCL) frequency combs have revolutionized mid-infrared (MIR) spectroscopy by their high brightness and fast temporal resolution, and are a promising technology for fully-integrated and cost-effective sensors. As for…

The development of accurate tools to characterize Intramolecular Vibrational Redistribution (IVR) is of major interest in chemistry. In this context, surface-enhanced vibrational spectroscopies stand up as well-established techniques to…

Dual comb spectroscopy (DCS) is a powerful technique for broadband spectroscopy with high precision and fast data acquisition. High-frequency resolution requires long data acquisition times, limiting the temporal resolution in time-resolved…

Optics · Physics 2022-12-06 Sutapa Ghosh , Gadi Eisenstein

The optical frequency comb has made a significant impact in precision spectroscopy and on our ability to probe atomic, molecular and, recently, nuclear transitions to further our understanding of their fundamental properties and how their…

Optics · Physics 2026-02-17 John J. McCauley , DylanP. Tooley , R. Jason Jones

To reduce the complexity of infrared spectroscopy hardware while maintaining performance, a data informed, task-specific, spectral collection approach termed Sparse Infrared Spectroscopy (SIRS) is developed. Using a numerically based…

Chemical Physics · Physics 2025-06-27 Mira Welner , Andre Hazbun , Thomas Beechem

Mid-infrared (MIR) spectrometers are invaluable tools for molecular fingerprinting and hyper-spectral imaging. Among the available spectroscopic approaches, GHz MIR dual-comb absorption spectrometers have the potential to simultaneously…

Frequency-modulation (FM) spectroscopy has been extended to the vacuum-ultraviolet (VUV) range of the electromagnetic spectrum. Coherent VUV laser radiation is produced by resonance-enhanced sum-frequency mixing…

Spectral measurements in the infrared (IR) optical range provide unique fingerprints of materials which are useful for material analysis, environmental sensing, and health diagnostics. Current IR spectroscopy techniques require the use of…

Quantum Physics · Physics 2016-02-05 Dmitry A. Kalashnikov , Anna V. Paterova , Sergei P. Kulik , Leonid A. Krivitsky

Raman spectroscopy is one of the key techniques in the study of vibrational modes and molecular structures. In Coherent Anti-Stokes Raman Scattering (CARS) spectroscopy, a molecular vibrational spectrum is resolved via the third-order…

Optics · Physics 2010-12-02 Ori Katz , Jonathan M. Levitt , Eran Grinvald , Yaron Silberberg

We continue our work on developing techniques for studying turbulence with spectroscopic data. We show that Doppler-broadened absorption spectral lines, in particularly, saturated absorption lines, can be used within the framework of the…

Astrophysics · Physics 2009-11-13 A. Lazarian , D. Pogosyan

We demonstrate cantilever-enhanced photoacoustic spectroscopy in the mid-infrared using a supercontinuum source. The approach is broadband, compact, and allows for higher photoacoustic signal intensity and enhanced signal-to-noise ratio as…

Instrumentation and Detectors · Physics 2018-11-14 Tommi Mikkonen , Caroline Amiot , Antti Aalto , Kim Patokoski , Goëry Genty , Juha Toivonen

The mid-infrared (mid-IR) regime (typically the wavelength regime of $\lambda \sim 2.5-20 \ \mathrm{\mu m}$) is an important spectral range for spectroscopy as many molecules have their fundamental rotational-vibrational absorption in this…

Precise astronomical spectroscopic analyses routinely assume that individual pixels in charge-coupled devices (CCDs) have uniform sensitivity to photons. Intra-pixel sensitivity (IPS) variations may already cause small systematic errors in,…

Instrumentation and Methods for Astrophysics · Physics 2015-06-04 Michael T. Murphy , Clayton R. Locke , Philip S. Light , Andre N. Luiten , Jon S. Lawrence

We have recently introduced the Vernier-based Direct Frequency Comb Cavity-Enhanced Spectroscopy technique and we present the corresponding formalism for quantitative broadband spectroscopy. We achieve high sensitivity and broadband…

Optics · Physics 2016-11-23 Lucile Rutkowski , Jérôme Morville

Mid-infrared (mid-IR) spectroscopy is a crucial workhorse for a plethora of analytical applications and is suitable for diverse materials, including gases, polymers or biological tissue. However, this technologically significant wavelength…

Optics · Physics 2022-02-23 Paul Kaufmann , Helen M. Chrzanowski , Aron Vanselow , Sven Ramelow

We present a system for molecular spectroscopy using a broadband mid-infrared laser with near infrared detection. Difference frequency generation of a Yb:fiber femtosecond laser produced a mid-infrared (MIR) source tunable from 2100-3700…

Optics · Physics 2015-05-30 Todd A. Johnson , Scott A. Diddams