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Molecular dynamics simulations were carried out on a Lennard-Jones binary mixture of rigid (fixed bond length) diatomic molecules. The translational and rotational correlation functions, and the corresponding susceptibilities, exhibit two…

Soft Condensed Matter · Physics 2015-06-16 D. Fragiadakis , C. M. Roland

Broadband dielectric spectroscopy was used to study the molecular orientational dynamics of the glass-forming, thioether-linked cyanobiphenyl liquid crystal dimers. As was expected theoretically, two different relaxation processes that…

Soft Condensed Matter · Physics 2023-04-18 M. Czarnecka , Y. Arakawa , A. Kocot , K. Merkel

We report observations of unusal \emph{first} plastic events in silica and metallic glasses in the shear startup regime at applied strain two orders of magnitude smaller than yield strain. The (non-Affine) particle displacement field during…

We have performed a detailed dielectric investigation of the relaxational dynamics of glass-forming benzophenone. Our measurements cover a broad frequency range of 0.1 Hz to 120 GHz and temperatures from far below the glass temperature well…

Disordered Systems and Neural Networks · Physics 2008-04-15 P. Lunkenheimer , L. C. Pardo , M. Köhler , A. Loidl

The frequency and temperature dependence of the dielectric constant and the electrical conductivity of the transparent glasses in the composition 0.5Cs2O-0.5Li2O-3B2O3 (CLBO) were investigated in the 100 Hz - 10 MHz frequency range. The…

Materials Science · Physics 2010-08-02 Rahul Vaish , K. B. R. Varma

Fragility, quantifying the rapidity of variation of relaxation times, is analysed for a series of model glass formers, which differ in the softness of their interparticle interactions. In an attempt to rationalize experimental observations…

Soft Condensed Matter · Physics 2017-05-30 Anshul D. S. Parmar , Pallabi Kundu , Srikanth Sastry

The particle motion associated to the {\alpha}-relaxation in supercooled liquids is still challenging scientists due to its difficulty to be probed experimentally. By combining synchrotron techniques, we found the existence of microscopic…

We have performed a thorough examination of the reorientational relaxation dynamics and the ionic charge transport of three typical deep eutectic solvents, ethaline, glyceline and reline by broadband dielectric spectroscopy. Our experiments…

Soft Condensed Matter · Physics 2019-03-28 D. Reuter , C. Binder , P. Lunkenheimer , A. Loidl

Molecular-dynamics simulations are presented for two correlation functions formed with the partial density fluctuations of binary hard-sphere mixtures in order to explore the effects of mixing on the evolution of glassy dynamics upon…

Soft Condensed Matter · Physics 2007-05-23 G. Foffi , W. Gotze , F. Sciortino , P. Tartaglia , Th. Voigtmann

We observe two thresholds in the variations of electrical conductivity of dry solid electrolyte (AgI)x(AgPO3)1-x glasses, when the AgI additive concentration x increases to 9.5% and to 37.8%. Raman scattering complemented by calorimetric…

Soft Condensed Matter · Physics 2009-11-13 Deassy I. Novita , P. Boolchand , M. Malki , M. Micoulaut

A detailed investigation of the charge-ordered charge-transfer salt \delta-(EDT-TTF-CONMe$_{2}$)$_{2}$Br by thermal-expansion measurements and dielectric spectroscopy reveals three dynamic processes of relaxational character. The slowest…

Strongly Correlated Electrons · Physics 2018-07-04 J. K. H. Fischer , P. Lunkenheimer , C. Leva , S. M. Winter , M. Lang , C. Mézière , P. Batail , A. Loidl , R. S. Manna

We study the pressure and temperature dependences of the dielectric relaxation of two molecular glassforming liquids, dibutyl phtalate and m-toluidine. We focus on two characteristics of the slowing down of relaxation, the fragility…

Soft Condensed Matter · Physics 2015-06-25 Kristine Niss , Cecile Dalle-Ferrier , Gilles Tarjus , Christiane Alba-Simionesco

Using a combination of resistance fluctuation (noise) and dielectric spectroscopy we investigate the nature of relaxor-type electronic ferroelectricity in the organic conductor $\kappa$-(BETS)$_2$Mn[N(CN)$_2$]$_3$, a system representative…

By using dielectric spectroscopy in a broad range of temperatures and frequencies, we have investigated dipolar relaxations, the dc conductivity, and the possible occurrence of polar order in AgCN. Conductivity contributions dominate the…

Disordered Systems and Neural Networks · Physics 2023-05-09 P. Lunkenheimer , A. Loidl , G. P. Johari

The thermal conductivity of polycrystalline semiconductors with type-I clathrate hydrate crystal structure is reported. Ge clathrates (doped with Sr and/or Eu) exhibit lattice thermal conductivities typical of amorphous materials.…

Materials Science · Physics 2009-10-31 J. L. Cohn , G. S. Nolas , V. Fessatidis , T. H. Metcalf , G. A. Slack

Dielectric loss spectra of glass-forming propylene carbonate and glycerol at temperatures above and below T_g are presented. By performing aging experiments lasting up to five weeks, equilibrium spectra below T_g have been obtained. During…

Soft Condensed Matter · Physics 2009-10-31 U. Schneider , R. Brand , P. Lunkenheimer , A. Loidl

Glass-like materials are nonequilibrium systems where the relaxation time may exceed reasonable time scales of observations. In the present paper a dynamic percolation model is introduced in order to explain the principal properties of…

Condensed Matter · Physics 2007-05-23 A. Vazquez , O. Sotolongo-Costa

Large fluctuations of conductivity with time are observed in a low-mobility two-dimensional electron system in silicon at low electron densities $n_s$ and temperatures. A dramatic increase of the noise power ($\propto 1/f^{\alpha}$) as…

Strongly Correlated Electrons · Physics 2009-11-07 Snezana Bogdanovich , Dragana Popovic

We report filling-fraction dependent dielectric spectroscopy measurements on the relaxation dynamics of the rod-like nematogen 7CB condensed in 13 nm silica nanochannels. In the film-condensed regime, a slow interface relaxation dominates…

Soft Condensed Matter · Physics 2015-04-21 Sylwia Calus , Andriy V. Kityk , Manfred Eich , Patrick Huber

We present nonlinear dielectric measurements of glass-forming 1-propanol, a prototypical example for the monohydroxy alcohols that are known to exhibit unusual relaxation dynamics, namely an additional Debye relaxation, slower than the…

Soft Condensed Matter · Physics 2014-12-04 Th. Bauer , M. Michl , P. Lunkenheimer , A. Loidl