Correlation energy of two electrons in the high-density limit
Other Condensed Matter
2010-02-19 v1
Abstract
We consider the high-density-limit correlation energy in dimensions for the ground states of three two-electron systems: helium (in which the electrons move in a Coulombic field), spherium (in which they move on the surface of a sphere), and hookium (in which they move in a quadratic potential). We find that the values are strikingly similar, depending strongly on but only weakly on the external potential. We conjecture that, for large , the limiting correlation energy in any confining external potential, where .
Keywords
Cite
@article{arxiv.1002.3402,
title = {Correlation energy of two electrons in the high-density limit},
author = {Pierre-François Loos and Peter M. W. Gill},
journal= {arXiv preprint arXiv:1002.3402},
year = {2010}
}
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