A Tale of Two Electrons: Correlation at High Density
Abstract
We review our recent progress in the determination of the high-density correlation energy in two-electron systems. Several two-electron systems are considered, such as the well known helium-like ions (helium), and the Hooke's law atom (hookium). We also present results regarding two electrons on the surface of a sphere (spherium), and two electrons trapped in a spherical box (ballium). We also show that, in the large-dimension limit, the high-density correlation energy of two opposite-spin electrons interacting {\em via} a Coulomb potential is given by for any radial external potential , where is the dimensionality of the space. This result explains the similarity of in the previous two-electron systems for D=3.
Cite
@article{arxiv.1008.2252,
title = {A Tale of Two Electrons: Correlation at High Density},
author = {Pierre-François Loos and Peter M. W. Gill},
journal= {arXiv preprint arXiv:1008.2252},
year = {2011}
}
Comments
10 pages, 2 figures, to appear in Chem. Phys. Lett. (Frontiers Article)