English

A Tale of Two Electrons: Correlation at High Density

Chemical Physics 2011-01-14 v2 Other Condensed Matter Strongly Correlated Electrons Computational Physics

Abstract

We review our recent progress in the determination of the high-density correlation energy \Ec\Ec in two-electron systems. Several two-electron systems are considered, such as the well known helium-like ions (helium), and the Hooke's law atom (hookium). We also present results regarding two electrons on the surface of a sphere (spherium), and two electrons trapped in a spherical box (ballium). We also show that, in the large-dimension limit, the high-density correlation energy of two opposite-spin electrons interacting {\em via} a Coulomb potential is given by \Ec1/(8D2)\Ec \sim -1/(8D^2) for any radial external potential V(r)V(r), where DD is the dimensionality of the space. This result explains the similarity of \Ec\Ec in the previous two-electron systems for D=3.

Keywords

Cite

@article{arxiv.1008.2252,
  title  = {A Tale of Two Electrons: Correlation at High Density},
  author = {Pierre-François Loos and Peter M. W. Gill},
  journal= {arXiv preprint arXiv:1008.2252},
  year   = {2011}
}

Comments

10 pages, 2 figures, to appear in Chem. Phys. Lett. (Frontiers Article)

R2 v1 2026-06-21T16:00:19.567Z