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The standard formulation of thermostatistics, being based on the Boltzmann-Gibbs distribution and logarithmic Shannon entropy, describes idealized uncorrelated systems with extensive energies and short-range interactions. In this letter, we…

统计力学 · 物理学 2020-07-01 S. N. Saadatmand , Tim Gould , E. G. Cavalcanti , J. A. Vaccaro

The issue of relaxation has been addressed in terms of ergodic theory in the past. However, the application of that theory to models of physical interest is problematic, especially when dealing with relaxation to nonequilibrium steady…

统计力学 · 物理学 2018-12-18 Denis J. Evans , Stephen R. Williams , Debra J. Searles , Lamberto Rondoni

Thermodynamics is a well developed tool to study systems in equilibrium but no such general framework is available for non-equilibrium processes. Only hope for a quantitative description is to fall back upon the equilibrium language as…

统计力学 · 物理学 2015-05-14 Poulomi Sadhukhan , Somendra M. Bhattacharjee

Let (M,J) be a dynamical model of macroscopic systems and (N,K) a less microscopic model (i.e. a model involving less details) of the same macroscopic systems; M and N are manifolds, J are vector fields on M, and K are vector fields on N.…

数学物理 · 物理学 2021-03-17 Miroslav Grmela , Vaclav Klika , Michal Pavelka

We derive various exact results for Markovian systems that spontaneously relax to a non-equilibrium steady-state by using joint probability distributions symmetries of different entropy production decompositions. The analytical approach is…

统计力学 · 物理学 2012-02-10 Reinaldo García-García , Vivien Lecomte , A. B. Kolton , D. Domínguez

There are only a very few known relations in statistical dynamics that are valid for systems driven arbitrarily far-from-equilibrium. One of these is the fluctuation theorem, which places conditions on the entropy production probability…

统计力学 · 物理学 2009-09-25 Gavin E. Crooks

The backbone of nonequilibrium thermodynamics is the stability structure, where entropy is related to a Lyapunov function of thermodynamic equilibrium. Stability is the background of natural selection: unstable systems are temporary, and…

物理与社会 · 物理学 2024-10-01 Peter Ván

Stochastic thermodynamics and the associated fluctuation relations provide the means to extend the fundamental laws of thermodynamics to small scales and systems out of equilibrium. The fluctuating thermodynamic variables are usually…

统计力学 · 物理学 2015-05-29 Aki Kutvonen , Tapio Ala-Nissilä , Jukka P. Pekola

Thermodynamics have been applied to astronomy, biology, psychology, some social systems and so on. But, various evolutions from astronomy to biology and social systems cannot be only increase of entropy. When fluctuations are magnified due…

综合物理 · 物理学 2009-10-06 Yi-Fang Chang

We study quantum conditional entropy production, which quantifies the irreversibility of system-environment evolution from the perspective of a third system, called the reference. The reference is initially correlated with the system. We…

量子物理 · 物理学 2022-08-01 Kun Zhang , Xuanhua Wang , Qian Zeng , Jin Wang

For stochastic non-equilibrium dynamics like a Langevin equation for a colloidal particle or a master equation for discrete states, entropy production along a single trajectory is studied. It involves both genuine particle entropy and…

统计力学 · 物理学 2012-05-21 Udo Seifert

Systems with interacting degrees of freedom play a prominent role in stochastic thermodynamics. Our aim is to use the concept of detached path probabilities and detached entropy production for bipartite Markov processes and elaborate on a…

统计力学 · 物理学 2017-10-17 Jannik Ehrich , Andreas Engel

We demonstrate that the Gibbs-Shannon entropy is applicable to non-equilibrium systems of any size and boundary conditions. The change in microscopic entropy can be attributed to the stochastic nature of dynamic processes and to the…

统计力学 · 物理学 2020-10-13 Jianzhong Wu

A historical perspective is presented on thermodynamics from the pioneering contributions by Carnot and Clausius to recent advances on active matter. Non-equilibrium thermodynamics develops from the identification of the irreversible…

综合物理 · 物理学 2025-12-22 Pierre Gaspard

Reciprocal relations correlate fairly accurately a great variety of experimental results. Nevertheless, the concepts of statistical fluctuations, and microscopic reversibility - the bases of the accepted proof of the relations by Onsager -…

化学物理 · 物理学 2007-05-23 Elias P. Gyftopoulos

The laws of thermodynamics provide a clear concept of the temperature for an equilibrium system in the continuum limit. Meanwhile, the equipartition theorem allows one to make a connection between the ensemble average of the kinetic energy…

统计力学 · 物理学 2009-11-13 Alex V. Popov , Rigoberto Hernandez

To the student of thermodynamics the most difficult subject is entropy. In this paper we examine the actual, practical application of entropy to two simple systems, the homogeneous slab with fixed boundary values of the temperature, and an…

统计力学 · 物理学 2015-05-28 Christian Frønsdal , Abhishek Pathak

To describe the nonequilibrium states of a system we introduce a new thermodynamic parameter - the lifetime of a system. The statistical distributions which can be obtained out of the mesoscopic description characterizing the behaviour of a…

统计力学 · 物理学 2007-05-23 V. V. Ryazanov , S. G. Shpyrko

Life is fundamentally a scientific enigma. The interplay between chaos, entropy dynamics, and Prigogine's dissipative systems offers profound insights into the emergence, stabilization, and eventual collapse of far-from-equilibrium systems.…

亚细胞过程 · 定量生物学 2025-02-20 Salvatore Chirumbolo , Antonio Vella

A microscopic definition of the thermodynamic entropy in an isolated quantum system must satisfy (i) additivity, (ii) extensivity and (iii) the second law of thermodynamics. We show that the diagonal entropy, which is the Shannon entropy in…

统计力学 · 物理学 2015-03-30 Tatsuhiko N. Ikeda , Naoyuki Sakumichi , Anatoli Polkovnikov , Masahito Ueda