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Patterned surfaces with large effective slip lengths, such as super-hydrophobic surfaces containing trapped gas bubbles, have the potential to greatly enhance electrokinetic phenomena. Existing theories assume either homogeneous flat…

流体动力学 · 物理学 2015-05-13 Supreet S. Bahga , Olga I. Vinogradova , Martin Z. Bazant

Possible mechanisms for over-limiting current (OLC) through aqueous ion-exchange membranes (exceeding diffusion limitation) have been debated for half a century. Flows consistent with electro-osmotic instability (EOI) have recently been…

化学物理 · 物理学 2013-12-12 M. B. Andersen , M. van Soestbergen , A. Mani , H. Bruus , P. M. Biesheuvel , M. Z. Bazant

Selectivity towards positive and negative ions in nanopores is often associated with electroosmotic flow, the control of which is pivotal in several micro-nanofluidic technologies. Selectivity is traditionally understood to be a consequence…

流体动力学 · 物理学 2022-04-21 Giovanni Di Muccio , Blasco Morozzo della Rocca , Mauro Chinappi

Traditional models of electrokinetic transport in porous media are based on homogenized material properties, which neglect any macroscopic effects of microscopic fluctuations. This perspective is taken not only for convenience, but also…

It has been suggested that superhydrophobic surfaces, due to the presence of a no-shear zone, can greatly enhance transport of surface charges, leading to a considerable increase in the streaming potential. This could find potential use in…

流体动力学 · 物理学 2015-06-15 Gowrishankar Seshadri , Tobias Baier

In this paper, we develop a general mathematical framework for enhanced hydrodynamic near-cloaking of electro-osmotic flow for more complex shapes, which is obtained by simultaneously perturbing the inner and outer boundaries of the perfect…

偏微分方程分析 · 数学 2023-10-24 Hongyu Liu , Zhi-Qiang Miao , Guang-Hui Zheng

Numerical analyses of transient electro-osmosis of a typical non-Newtonian liquid induced by DC and AC electric fields in a rectangular microchannel are conducted in the framework of continuum fluid mechanics. The famous power-law…

流体动力学 · 物理学 2015-07-23 Cunlu Zhao , Chun Yang

Ionic current through a charge-selective interface in a binary electrolyte is a basic element of many electrochemical engineering and microfluidic processes. Such current passage is diffusion-limited: it induces a decrease of electrolyte…

流体动力学 · 物理学 2016-07-06 Isaak Rubinstein , Boris Zaltzman

Thermo-osmotic flows - flows generated in micro and nanofluidic systems by thermal gradients - could provide an alternative approach to harvest waste heat. However, such use would require massive thermo-osmotic flows, which are up to now…

流体动力学 · 物理学 2022-01-21 Cecilia Herrero , Michael De San Féliciano , Samy Merabia , Laurent Joly

Theoretical modeling of electroosmosis through conducting (ideally polarizable) nanochannels is reported. Based on the theory of induced charge electrokinetics, a novel nanofluidic system which possesses both adjustable ion selective…

流体动力学 · 物理学 2015-07-23 Cunlu Zhao , Chun Yang

In this paper, we develop a general mathematical framework for the electro-osmosis problem to design simultaneous microscale electric and hydrodynamic cloaking in a Hele-Shaw configuration. A novel approach to achieving simultaneously…

偏微分方程分析 · 数学 2024-04-04 Hongyu Liu , Zhi-Qiang Miao , Guang-Hui Zheng

We describe theoretically ``electrolubrication'' in liquid mixtures, the phenomenon where an electric field applied transverse to the confining surfaces leads to concentration gradients that alter the flow profile significantly. When the…

流体动力学 · 物理学 2024-05-08 Roni Kroll , Yoav Tsori

We propose an electro-hydrodynamics model to describe the dynamic evolution of a slender drop containing a dilute ionic surfactant on a naturally wettable surface, with a varying external electric field. This unified model reproduces…

流体动力学 · 物理学 2023-06-30 Weiqi Chu , Hangjie Ji , Qining Wang , Chang-jin "CJ'' Kim , Andrea L. Bertozzi

We characterize the electro-phoretic motion of charged sphere suspensions in the presence of substantial electro-osmotic flow using a recently introduced small angle super-heterodyne dynamic light scattering instrument (ISASH-LDV).…

软凝聚态物质 · 物理学 2018-08-22 Denis Botin , Jennifer Wenzl , Ran Niu , Thomas Palberg

Shock electrodialysis (shock ED), an emerging electrokinetic process for water purification, leverages the new physics of deionization shock waves in porous media. In previous work, a simple leaky membrane model with surface conduction can…

流体动力学 · 物理学 2021-03-16 Huanhuan Tian , Mohammad A. Alkhadra , Martin Z. Bazant

The sliding motion of aqueous droplets on hydrohobic surfaces leads to charge separation at the trailing edge, with implications from triple-line friction to hydrovoltaic energy generation. Charges deposited on the solid surface have been…

软凝聚态物质 · 物理学 2025-09-12 Zouhir Benrahla , Tristan Saide , Louis Burnaz , Emilie Verneuil , Simon Gravelle , Jean Comtet

We discuss an electro-osmotic flow near charged porous coatings of a finite hydrodynamic permeability, impregnated with an outer electrolyte solution. It is shown that their electrokinetic (zeta) potential is generally augmented compared to…

流体动力学 · 物理学 2020-10-28 Olga I. Vinogradova , Elena F. Silkina , Naren Bag , Evgeny S. Asmolov

We consider two charged semipermeable membranes, which bound bulk electrolyte solutions and are separated by a thin film of salt-free liquid. Small counter-ions permeate into the gap, which leads to a steric charge separation in the system.…

软凝聚态物质 · 物理学 2016-11-23 Salim R. Maduar , Olga I. Vinogradova

This fluid dynamics video showcases how optically induced electrowetting can be used to manipulate liquid droplets in open space and particulate phases inside the droplet. A photoconductive layer is added to a conventional…

流体动力学 · 物理学 2009-10-20 Han-Sheng Chuang , Aloke Kumar , Steven T. Wereley

Based on the capillary pore model (space-charge theory) for combined fluid and ion flow through cylindrical nanopores or nanotubes, we derive the continuum equations modified to include wall slip. We focus on the ionic conductance and…

化学物理 · 物理学 2016-03-31 J. Catalano , R. G. H. Lammertink , P. M. Biesheuvel