相关论文: Theory of Systematic Computational Error in Free E…
We develop a self-consistent first-principle method based on the density functional theory. Physical quantities, such as the density of states, Fermi energy and electron density are obtained using a time-dependent random state method…
[This is the unpublished supplemental information from 1989 to the paper: J.M. Deutsch, "Quantum statistical mechanics in a closed system." Phys. Rev. A, 43(4), 2046 (1991).] A closed quantum mechanical system does not necessarily give time…
In this article we study the problem of quantifying the uncertainty in an experiment with a technical system. We propose new density estimates which combine observed data of the technical system and simulated data from an (imperfect)…
Atmospheric flows exhibit long-range spatiotemporal correlations manifested as the fractal geometry to the global cloud cover pattern concomitant with inverse power-law form for power spectra of temporal fluctuations of all scales ranging…
We show, through a refinement of the work theorem, that the average dissipation, upon perturbing a Hamiltonian system arbitrarily far out of equilibrium in a transition between two canonical equilibrium states, is exactly given by…
We derive the optimal estimates of the free energies of an arbitrary number of thermodynamic states from nonequilibrium work measurements; the work data are collected from forward and reverse switching processes and obey a fluctuation…
Dynamic factor models are often estimated by point-estimation methods, disregarding parameter uncertainty. We propose a method accounting for parameter uncertainty by means of posterior approximation, using variational inference. Our…
Atmospheric flows exhibit selfsimilar fractal spacetime fluctuations manifested as the fractal geometry to global cloud cover pattern and inverse power law form for power spectra of meteorological parameters such as windspeed, temperature,…
Modern digital electronics support remarkably reliable computing, especially given the challenge of controlling nanoscale logical components that interact in fluctuating environments. However, we demonstrate that the high-reliability limit…
We introduce the concept of fidelity for dynamical maps in an open quantum system scenario. We derive an inequality linking this quantity to the distinguishability of the inducing environmental states. Our inequality imposes constraints on…
We propose a fundamental theory on ensemble learning that answers the central question: what factors make an ensemble system good or bad? Previous studies used a variant of Fano's inequality of information theory and derived a lower bound…
In various disordered systems or non-equilibrium dynamical models, the large deviations of some observables have been found to display different scalings for rare values bigger or smaller than the typical value. In the present paper, we…
The Wald development of statistical decision theory addresses decision making with sample data. Wald's concept of a statistical decision function (SDF) embraces all mappings of the form [data -> decision]. An SDF need not perform…
Temperature of a finite-sized system fluctuates due to the thermal fluctuations. However, a systematic mathematical framework for measuring or estimating the temperature is still underdeveloped. Here, we incorporate the estimation theory in…
Stochastic reaction networks are a fundamental model to describe interactions between species where random fluctuations are relevant. The master equation provides the evolution of the probability distribution across the discrete state space…
We derive general discrimination of quantum states chosen from a certain set, given initial $M$ copies of each state, and obtain the matrix inequality, which describe the bound between the maximum probability of correctly determining and…
This paper considers a strongly connected network of agents, each capable of partially observing and controlling a discrete-time linear time-invariant (LTI) system that is jointly observable and controllable. Additionally, agents…
There are only a very few known relations in statistical dynamics that are valid for systems driven arbitrarily far-from-equilibrium. One of these is the fluctuation theorem, which places conditions on the entropy production probability…
Freidlin-Wentzell theory of large deviations can be used to compute the likelihood of extreme or rare events in stochastic dynamical systems via the solution of an optimization problem. The approach gives exponential estimates that often…
A main goal of single-molecule experiments is to evaluate equilibrium free energy differences by applying fluctuation relations to repeated work measurements along irreversible processes. We quantify the error that is made in a free energy…