相关论文: Dynamics of Counterion Condensation
We consider an overall neutral system consisting of two similarly charged plates and their oppositely charged counterions and analyze the electrostatic interaction between the two surfaces beyond the mean-field Poisson-Boltzmann…
We predict a condensation phenomenon in an overall neutral system, consisting of a single charged plate and its oppositely charged counterions. Based on the ``two-fluid'' model, in which the counterions are divided into a ``free'' and a…
We present a variational solution of the Langevin field equation describing the nonequilibrium dynamics of a harmonically trapped Bose-Einstein condensate. If the thermal cloud remains in equilibrium at all times, we find that the equation…
Molecular dynamics simulations are used to study the local dynamics of counterion-charged polymer association at charge densities above and below the counterion condensation threshold. Surprisingly, the counterions form weakly-interacting…
Realistic charged macromolecules are characterized by discrete (rather than homogeneous) charge distributions. We investigate the effects of surface charge discretization on the counterion distribution at the level of mean-field theory…
We consider a set of identical mobile point-like charges (counter-ions) confined to a domain with curved hard walls carrying a uniform fixed surface charge density, the system as a whole being electroneutral. Three domain geometries are…
A model for ionic solutions with an attractive short-range pair interaction between the ions is presented. The short-range interaction is accounted for by adding a quadratic non-local term to the Poisson-Boltzmann free energy. The model is…
We investigate the phenomenon of counterion condensation in a solution of highly charged rigid polyelectrolytes within the cell model. A method is proposed which -- based on the charge distribution function -- identifies both the fraction…
We describe a method to simulate the dynamics of charged colloidal particles suspended in a liquid containing dissociated ions and salt ions. Regimes of prime current interest are those of large volume fraction of colloids, highly charged…
We study the collision dynamics of two Bose-Einstein condensates with their dynamical wave functions modeled by a set of coupled, time-dependent Gross-Pitaevskii equations. Beginning with an effective one-dimensional system, we identify…
The dynamics of a Bose-Einstein condensate is studied theoretically in a combined periodic plus harmonic external potential. Different dynamical regimes of stable and unstable collective dipole and Bloch oscillations are analysed in terms…
The solution of the Poisson--Boltzmann equation for counterions confined between two charged plates is known analytically up to a constant, namely, the ion density in the middle of the channel. This quantity is relevant also because it…
A highly-charged spherical colloid in a salt-free environment exerts such a powerful attraction on its counterions that a certain fraction condenses onto the surface of a particle. The degree of condensation depends on the curvature of the…
We study condensation in several particle systems related to the inclusion process. For an asymmetric one-dimensional version with closed boundary conditions and drift to the right, we show that all but a finite number of particles condense…
We study the condensation transition of counterions on a charged cylinder via Monte Carlo simulations. Varying the cylinder radius systematically in relation to the system size, we find that all counterions are bound to the cylinder and the…
We study the bosonic Boltzmann-Nordheim kinetic equation, which describes the kinetic regime of weakly interacting bosons with s-wave scattering only. We consider a spatially homogeneous fluid with an isotropic momentum distribution. The…
The counterion-condensation transition at charged cylinders is studied using Monte-Carlo simulation methods. Employing logarithmically rescaled radial coordinates, large system sizes are tractable and the critical behavior is determined by…
We consider a macroion confined to a cylindrical cell and neutralized by oppositely charged counterions. Exact results are obtained for the two-dimensional version of this problem, in which ion-ion and ion-macroion interactions are…
Using Brownian dynamics computer simulations we show that a two-dimensional suspension of self-propelled ("active") colloidal particles crystallizes at sufficiently high densities. Compared to the equilibrium freezing of passive particles…
The temporal evolution of a perturbation of the equilibrium distribution of a condensed Bose gas is investigated using the kinetic equation which describes collision between condensate and noncondensate atoms. The dynamics is studied in the…