相关论文: Thermodynamics of the glassy state

A picture for thermodynamics of the glassy state is introduced. It assumes that one extra parameter, the effective temperature, is needed to describe the glassy state. This explains the classical paradoxes concerning the Ehrenfest relations…

A system is glassy when the observation time is much smaller than the equilibration time. A unifying thermodynamic picture of the glassy state is presented. Slow configurational modes are in quasi-equilibrium at an effective temperature. It…

Glass is an under-cooled liquid that very slowly relaxes towards the equilibrium crystalline state. Its energy balance is ill understood, since it is widely believed that the glassy state cannot be described thermodynamically. However, the…

A picture for thermodynamics of the glassy state was introduced recently by us (Phys. Rev. Lett. {\bf 79} (1997) 1317; {\bf 80} (1998) 5580). It starts by assuming that one extra parameter, the effective temperature, is needed to describe…

In order to find out whether there exists a thermodynamic description of the glass phase, the Ehrenfest relations along the glass transition line are reconsidered. It is explained that the one involving the compressibility is always…

It has been recently shown that one can understand the Prigogine-Defay ratio at the glass transition in terms of freezing into one of the many inherent states of the undercooled liquid. In the present paper, the treatment is extended to the…

For the dynamical glassy transition in the $p$-spin mean field spin glass model a thermodynamic description is given. The often considered marginal states are not the relevant ones for this purpose. This leads to consider a cooling…

In a glassy system different degrees of freedom have well-separated characteristic times, and are described by different temperatures. The stationary state is essentially non-equilibrium. A generalized statistical thermodynamics is…

We review a statistical picture of the glassy state derived from the analysis of the off-equilibrium fluctuation-dissipation relations. We define an ultra-long time limit where ``one time quantities'' are close to equilibrium while response…

A thermodynamic-like formalism is developed for superstatistical systems based on conditional entropies. This theory takes into account large-scale variations of intensive variables of systems in nonequilibrium stationary states. Ordinary…

Thermodynamic properties of matter are conveniently expressed as functional relations between variables known as equations of state. Here we experimentally determine the compressibility, density and pressure equations of state for an…

We propose a theory based on simple physical arguments that describes a non equilibrium steady-state by a temperature-like parameter (an "effective temperature"). We show how one can predict the effective temperature as a function of the…

The dynamical behavior of a kind of models with hierarchically constrained dynamics is investigated. The models exhibit many properties resembling real structural glasses. In particular, we focus on the study of time-dependent temperature…

We review an scenario for the non-equilibrium dynamics of glassy systems that has been motivated by the exact solution of simple models. This approach allows one to set on firmer grounds well-known phenomenological theories. The old ideas…

Diffusivity, a measure for how rapidly a fluid self-mixes, shows an intimate, but seemingly fragmented, connection to thermodynamics. On one hand, the "configurational" contribution to entropy (related to the number of mechanically-stable…

This work assembles some basic theoretical elements on thermal equilibrium, stability conditions, and fluctuation theory in self-gravitating systems illustrated with a few examples. Thermodynamics deals with states that have settled down…

We show how statistical thermodynamics can be formulated in situations in which thermodynamics applies, while equilibrium statistical mechanics does not. A typical case is, in the words of Landau and Lifshitz, that of partial (or…

We extend the recently developed non-gaussian thermodynamic formalism \cite{tre98} of a (presumably strongly turbulent) non-Markovian medium to its most general form that allows for the formulation of a consistent thermodynamic theory. All…

The limit of small entropy production is reached in relaxing systems long after preparation, and in stationary driven systems in the limit of small driving power. Surprisingly, for extended systems this limit is not in general the…

Heat can flow from cold to hot at any phase separation. Therefore Lynden-Bell's gravo-thermal catastrophe must be reconsidered. The original objects of Thermodynamics, the separation of phases at first order phase transitions, like boiling…