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相关论文: Why are glass-forming liquids non-Arrhenius?

200 篇论文

We propose a simple dynamical model of the glass transition based on the results from a non-randomly frustrated spin model which is known to form a glassy state below a characteristic quench temperature. The model is characterized by a…

统计力学 · 物理学 2008-02-03 Michael Ignatiev , Lei Gu , Bulbul Chakraborty

Glasses derive their functional properties from complex relaxation dynamics that remain enigmatic under extreme conditions. While the temperature dependence of these relaxation processes is well-established, their behavior under…

The Adam-Gibbs view of the glass transition relates the relaxation time to the configurational entropy, which goes continuously to zero at the so-called Kauzmann temperature. We examine this scenario in the context of a dimer model with an…

统计力学 · 物理学 2007-05-23 Dibyendu Das , Greg Farrell , Jane' Kondev , Bulbul Chakraborty

A simple, non-disordered spin model has been studied in an effort to understand the origin of the precipitous slowing down of dynamics observed in supercooled liquids approaching the glass transition. A combination of Monte Carlo…

统计力学 · 物理学 2009-11-07 Hui Yin , Bulbul Chakraborty

The shear modulus of solid $^4$He exhibits an anomalous change of order 10%[1, 2] at low temperatures that is qualitatively similar to the much smaller frequency change in torsional oscillator experiments. We propose that in solid $^4$He…

统计力学 · 物理学 2015-03-13 Jung-Jung Su , Matthias J. Graf , Alexander V. Balatsky

A mesoscopic model is proposed to explain the anomalous dynamics in a supercooled liquid as its glass transition temperature is approached from above. The model is based on the assumption of $\beta$ organized $\alpha$ process, with the…

软凝聚态物质 · 物理学 2007-05-23 Dwaipayan Chakrabarti , Biman Bagchi

Upon rapid quenching of temperature of a glass forming liquid, the system falls out of equilibrium due its finite relaxation time. Additionally, the relaxation becomes progressively slower with time. The created nonequilibrium state of the…

统计力学 · 物理学 2025-12-16 Biman Bagchi

Understanding relaxation of supercooled fluids is a major challenge and confining such systems can lead to bewildering behaviour. Here we exploit an optically confined colloidal model system in which we use reduced pressure as a control…

软凝聚态物质 · 物理学 2020-11-10 Ian Williams , Erdal C. Oğuz , Paul Bartlettl , Hartmut Löwen , C. Patrick Royall

The concept of vibrational density of states in glasses has been mirrored in liquids by the instantaneous-normal-mode spectrum. While in glasses instantaneous configurations correspond to minima of the potential-energy hypersurface and all…

无序系统与神经网络 · 物理学 2023-02-07 Stefano Mossa , Taras Bryk , Giancarlo Ruocco , Walter Schirmacher

Using two extremely different models of glass formers in two and three dimensions we demonstrate how to encode the subtle changes in the geometric rearrangement of particles during the scenario of the glass transition. We construct a…

统计力学 · 物理学 2015-05-13 Laurent Boue , Edan Lerner , Itamar Procaccia , Jacques Zylberg

The dynamical behavior of a kind of models with hierarchically constrained dynamics is investigated. The models exhibit many properties resembling real structural glasses. In particular, we focus on the study of time-dependent temperature…

统计力学 · 物理学 2009-11-07 A. Prados , J. J. Brey

We present a three-dimensional lattice-gas model with trivial thermodynamics, but nontrivial dynamics. The model is characterized by each particle having its own random energy landscape. The equilibrium dynamics of the model were…

软凝聚态物质 · 物理学 2012-03-27 Ulf R. Pedersen , Tina Hecksher , Jeppe C. Dyre , Thomas B. Schrøder

We develop a model free energy from an expansion that basically includes graphs without loops. From this calculation, we derive the temperature dependence of the density (or specific volume), the typical time scale of the…

无序系统与神经网络 · 物理学 2016-10-28 Henrich Frielinghaus

The excitation-chain theory of the glass transition, proposed in an earlier publication, predicts diverging, super-Arrhenius relaxation times and, {\it via} a similarly diverging length scale, suggests a way of understanding the relations…

统计力学 · 物理学 2009-11-11 J. S. Langer

To study relaxation dynamics of the two-dimensional XY gauge glass, we integrate directly the equations of motion and investigate the energy function. As usual, it decays exponentially at high temperatures; at low but non-zero temperatures,…

超导电性 · 物理学 2008-02-03 Beom Jun Kim , M. Y. Choi , S. Ryu , D. Stroud

Glassy solids may undergo a fluidization (yielding) transition upon deformation whereby the material starts to flow plastically. It has been a matter of debate whether this process is controlled by a specific time scale, from among…

软凝聚态物质 · 物理学 2020-06-25 Alessio Zaccone , Eugene M. Terentjev

Low-energy excitations play a key role in all condensed-matter systems, yet there is limited understanding of their nature in glasses, where they correspond to local rearrangements of groups of particles. Here we introduce an algorithm to…

软凝聚态物质 · 物理学 2024-08-27 Wencheng Ji , Massimo Pica Ciamarra , Matthieu Wyart

The Gilroy-Phillips model of relaxational jumps in asymmetric double-well potentials, developed for the Arrhenius-type secondary relaxations of the glass phase, is extended to a formal description of the breakdown of the shear modulus at…

无序系统与神经网络 · 物理学 2007-05-23 U. Buchenau

We assess the validity of "microscopic" approaches of glass-forming liquids based on the sole k nowledge of the static pair density correlations. To do so we apply them to a benchmark provided by two liquid models that share very similar…

统计力学 · 物理学 2011-10-10 Ludovic Berthier , Gilles Tarjus

We consider the relaxation process and the out-of-equilibrium dynamics of natural generalizations to arbitrary dimensions of the well known one dimensional East process. These facilitated models are supposed to catch some of the main…

统计力学 · 物理学 2015-06-22 Paul Chleboun , Alessandra Faggionato , Fabio Martinelli