相关论文: Equilibrium Chemical Engines
The Carnot engine sets an upper limit to the efficiency of a practical heat engine. An arbitrary irreversible engine is sometimes believed to behave closely as the Curzon-Ahlborn engine. Efficiency of the latter is obtained commonly by…
A cyclic thermodynamic heat engine runs most efficiently if it is reversible. Carnot constructed such a reversible heat engine by combining adiabatic and isothermal processes for a system containing an ideal gas. Here, we present an example…
We propose a simple theoretical model for a molecular chemical engine that catalyzes a chemical reaction and converts the free energy released by the reaction into mechanical work. Binding and unbinding processes of reactant and product…
A simple model of the two-state ratchet type is proposed for molecular chemical engines that convert chemical free energy into mechanical work and vice versa. The engine works by catalyzing a chemical reaction and turning a rotor.…
Conversion of chemical energy into mechanical work is the fundamental mechanism of several natural phenomena at the nanoscale, like molecular machines and Brownian motors. Quantum mechanical effects are relevant for optimising these…
It is known that an engine with ideal efficiency ($\eta =1$ for a chemical engine and $e = e_{\rm Carnot}$ for a thermal one) has zero power because a reversible cycle takes an infinite time. However, at least from a theoretical point of…
Based on quantum thermodynamic processes, we make a quantum-mechanical (QM) extension of the typical heat engine cycles, such as the Carnot, Brayton, Otto, and Diesel cycles, etc. The temperature is not included in these QM engine cycles,…
A quantum-mechanical analog of the Carnot engine reversibly working at vanishing temperature, shortly termed the quantum-mechanical Carnot engine, is discussed. A general formula for the efficiency of such an engine with an arbitrary…
In this work we include, for the Carnot cycle, irreversibilities of linear finite rate of heat transferences between the heat engine and its reservoirs, heat leak between the reservoirs and internal dissipations of the working fluid. A…
Engines are systems and devices that convert one form of energy into another, typically into a more useful form that can perform work. In the classical setup, physical, chemical, and biological engines largely involve the conversion of heat…
The aim of this paper is to determine lost works in a molecular engine and compare results with macro (classical) heat engines. Firstly, irreversible thermodynamics are reviewed for macro and molecular cycles. Secondly, irreversible…
The quantum engine cycle serves as an analogous representation of the macroscopic nature of heat engines and the quantum regime of thermal devices composed of a single element. In this work, we follow the formalism of a quantum engine…
The Carnot heat engine sets an upper bound on the efficiency of a heat engine. As an ideal, reversible engine, a single cycle must be performed in infinite time, and so the Carnot engine has zero power. However, there is nothing in…
The article sets forth comprehensive basics of thermodynamics of chemical equilibrium as balance of the thermodynamic forces. Based on the linear equations of irreversible thermodynamics, De Donder definition of the thermodynamic force, and…
Living systems efficiently use chemical fuel to do work, process information, and assemble patterns despite thermal noise. Whether high efficiency arises from general principles or specific fine-tuning is unknown. Here, applying a recent…
The Carnot cycle is a prototype of ideal heat engine to draw mechanical energy from the heat flux between two thermal baths with the maximum efficiency, dubbed as the Carnot efficiency $\eta_{\mathrm{C}}$. Such efficiency can only be…
A theoretical thermodynamic cycle more efficient than an infinite set of Carnot engines is presented. This result is unexpected from the point of view of classical thermodynamics.
Biomolecular machines are protein complexes that convert between different forms of free energy. They are utilized in nature to accomplish many cellular tasks. As isothermal nonequilibrium stochastic objects at low Reynolds number, they…
Optimizing the performance of thermal machines is an essential task of thermodynamics. We here consider the optimization of information engines that convert information about the state of a system into work. We concretely introduce a…
A cyclically operating chemical engine is considered that converts chemical energy into mechanical work. The working fluid is a gas of finite-sized spherical particles interacting through elastic hard collisions. For a generic transport law…