Efficiency at maximum power of a chemical engine
Abstract
A cyclically operating chemical engine is considered that converts chemical energy into mechanical work. The working fluid is a gas of finite-sized spherical particles interacting through elastic hard collisions. For a generic transport law for particle uptake and release, the efficiency at maximum power takes the form 1/2+c\Delta \mu + O(\Delta \mu^2), with 1/2 a universal constant and the chemical potential difference between the particle reservoirs. The linear coefficient c is zero for engines featuring a so-called left/right symmetry or particle fluxes that are antisymmetric in the applied chemical potential difference. Remarkably, the leading constant in is non-universal with respect to an exceptional modification of the transport law. For a nonlinear transport model we obtain \eta = 1/(\theta +1), with \theta >0 the power of in the transport equation
Keywords
Cite
@article{arxiv.1306.3866,
title = {Efficiency at maximum power of a chemical engine},
author = {Hans Hooyberghs and Bart Cleuren and Alberto Salazar and Joseph O. Indekeu and Christian Van den Broeck},
journal= {arXiv preprint arXiv:1306.3866},
year = {2015}
}