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A Markov state model of the dynamics of a protein-like chain immersed in an implicit hard sphere solvent is derived from first principles for a system of monomers that interact via discontinuous potentials designed to account for local…

统计力学 · 物理学 2015-06-22 Jeremy Schofield , Hanif Bayat

The effect of long wavelength fluctuations on the Mode-Coupling-Theory (MCT) dynamical singularity at $T_c$ in the $\beta$ regime is studied by means of the standard field-theoretical procedure for a genuine second-order phase transition.…

无序系统与神经网络 · 物理学 2015-06-19 Tommaso Rizzo

The influence of structural constraints on the relaxation dynamics of three polyurea networks with varying degree of crosslinking, has been studied by means of a thorough analysis of broadband dielectric spectroscopy measurements. Two…

软凝聚态物质 · 物理学 2018-10-03 Nerea Sebastián , Christophe Contal , Antoni Sánchez-Ferrer , Marco Pieruccini

Mode-coupling theory (MCT) of sheared dense granular liquids %in the vicinity of jamming transition is formulated. Starting from the Liouville equation of granular particles, the generalized Langevin equation is derived with the aid of the…

统计力学 · 物理学 2009-09-30 Hisao Hayakawa , Michio Otsuki

The binary Voronoi mixture is a fluid model whose interactions are local and many-body. Here we perform molecular-dynamics (MD) simulations of an equimolar mixture that is weakly polydisperse and additive. For the first time we study the…

无序系统与神经网络 · 物理学 2020-12-30 Céline Ruscher , Simone Ciarella , Chengjie Luo , Liesbeth M. C. Janssen , Jean Farago , Jörg Baschnagel

We review recent work on the phase behaviour of binary charged sphere mixtures as a function of particle concentration and composition. Both size ratios and charge ratios are varied over a wide range. By contrast to hard spheres the long…

Glauber dynamics of a bond-diluted Ising model on a Bethe lattice (a random graph with fixed connectivity) is investigated by an approximate theory which provides exact results for equilibrium properties. The time-dependent solutions of the…

统计力学 · 物理学 2015-05-18 Hiroki Ohta

Modelling electrolytes accurately on both a nanoscale and cell level can contribute to improving battery chemistries.[Armand and Tarascon, Nature, 2008, 451, 652-657] We previously presented a thermodynamic continuum model for…

化学物理 · 物理学 2024-08-09 Constantin Schwetlick , Max Schammer , Arnulf Latz , Birger Horstmann

We derive a simple system of equations to describe the magnetization relaxation of a molecular spin in weak interaction with a thermal bath for the whole temperature domain. Using this for the intermediate temperature domain where the…

材料科学 · 物理学 2022-12-27 Le Tuan Anh Ho , Liviu Ungur , Liviu F. Chibotaru

We investigate theoretically and numerically the dynamics of long-living oscillating coherent structures - bi-solitons - in the exact and approximate models for waves on the free surface of deep water. We generate numerically the…

斑图形成与孤子 · 物理学 2023-12-29 Andrey Gelash , Sergey Dremov , Rustam Mullyadzhanov , Dmitry Kachulin

The binodals and the non-ergodicity lines of a binary mixture of hard sphere-like particles with large size ratio are computed for studying the interplay between dynamic arrest and phase separation in depletion-driven colloidal mixtures.…

软凝聚态物质 · 物理学 2009-11-13 Ph. Germain , S. Amokrane

A study of the dynamics of a tunneling particle in a driven bistable potential which is moderately-to-strongly coupled to a bath is presented. Upon restricting the system dynamics to the Hilbert space spanned by the M lowest energy…

凝聚态物理 · 物理学 2009-11-07 M. Thorwart , M. Grifoni , P. Hänggi

Structural mechanisms in disordered materials like amorphous semi-conductors and glasses can be explored with the activation-relaxation technique (ART). The application of a sequence of such mechanisms allows for the generation of…

凝聚态物理 · 物理学 2009-10-31 G. T. Barkema , Normand Mousseau

Uncompensated charges do not occur in Nature and any local charge should be a result of charge separation. Dissociable chemical groups at interfaces in contact with ions in solution, whose chemical equilibrium depends both on short-range…

软凝聚态物质 · 物理学 2019-02-21 Yael Avni , David Andelman , Rudolf Podgornik

We investigate the effective interaction between two randomly charged but otherwise net-neutral, planar dielectric slabs immersed in an asymmetric Coulomb fluid containing a mixture of mobile monovalent and multivalent ions. The presence of…

软凝聚态物质 · 物理学 2016-01-25 Malihe Ghodrat , Ali Naji , Haniyeh Komaie-Moghaddam , Rudolf Podgornik

Molecular dynamics in pure water and aqueous salt solutions remain incompletely understood, partly due to the apparent contradictions between results from different spectroscopic techniques. In this work, we demonstrate, by detailed…

软凝聚态物质 · 物理学 2025-12-22 Rolf Zeißler , Florian Pabst , Thomas Blochowicz

We determined bulk crystal nucleation rates in aqueous suspensions of charged spheres at low metastability. Experiments were performed in dependence on electrolyte concen-tration and for two different particle number densities. The…

软凝聚态物质 · 物理学 2021-11-04 Jürgen Schwarz , Paul Leiderer , Thomas Palberg

Composite system is studied in noncommutative phase space with preserved rotational symmetry. We find conditions on the parameters of noncommutativity on which commutation relations for coordinates and momenta of the center-of-mass of…

量子物理 · 物理学 2018-02-27 Kh. P. Gnatenko , V. M. Tkachuk

We revisit the classical concept of near-decomposability in complex systems, introduced by Herbert Simon in his foundational article The Architecture of Complexity, by developing an explicit quantitative analysis based on singular…

动力系统 · 数学 2015-12-29 Gabriel D. Bousquet , Jean-Jacques E. Slotine

Within the Replica Symmetry Breaking (RSB) framework developed by M.Mezard and G.Parisi we investigate the occurrence of structural glass transitions in a model of fluid characterized by hard sphere repulsion together with short range…

统计力学 · 物理学 2009-11-11 A. Velenich , A. Parola , L. Reatto