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This note summarizes the motivation for extending current density-functional theory to include nonlocal one-electron potentials, and proposes methodology for practical calculations. The theoretical model, orbital functional theory, has been…

凝聚态物理 · 物理学 2007-05-23 R. K. Nesbet

The capability of density-functional theory to deal with the ground-state of strongly correlated low-dimensional systems, such as semiconductor quantum dots, depends on the accuracy of functionals developed for the exchange and correlation…

强关联电子 · 物理学 2009-02-25 S. Pittalis , E. Rasanen , C. Proetto , E. K. U. Gross

We address the question of the degree of spatial non-locality of the self energy in the iron-based superconductors, a subject which is receiving considerable attention. Using LiFeAs as a prototypical example, we extract the self energy from…

强关联电子 · 物理学 2021-04-07 Minjae Kim , Hu Miao , Sangkook Choi , Manuel Zingl , Antoine Georges , Gabriel Kotliar

We present a theory for the construction of renormalized kinetic equations to describe the dynamics of classical systems of particles in or out of equilibrium. A closed, self-consistent set of evolution equations is derived for the…

经典物理 · 物理学 2011-06-09 Jerome Daligault

The Hohenberg-Kohn density functional was long ago shown to reduce to the Thomas-Fermi approximation in the non-relativistic semiclassical (or large-$Z$) limit for all matter, i.e, the kinetic energy becomes local. Exchange also becomes…

材料科学 · 物理学 2016-08-24 Kieron Burke , Antonio Cancio , Tim Gould , Stefano Pittalis

The key feature of nonlocal kinetic energy functionals is their ability to reduce to the Thomas-Fermi functional in the regions of high density and to the von Weizs\"acker functional in the region of low density/high density gradient. This…

材料科学 · 物理学 2021-03-31 Xuecheng Shao , Wenhui Mi , Michele Pavanello

In this paper I report a pedagogical derivation of the unconventional electronic hydrodynamics in graphene on the basis of the kinetic theory. While formally valid in the weak coupling limit, this approach allows one to derive the…

介观与纳米尺度物理 · 物理学 2019-10-30 Boris N. Narozhny

This article generalizes the notion of the local density of a many-body system to introduce collective coordinates as explicit degrees of freedom. It is shown that the energy of the system can be expressed as a functional of this object.…

核理论 · 物理学 2014-04-23 Thomas Lesinski

Density functional theory (DFT) is a powerful theoretical tool widely used in such diverse fields as computational condensed matter physics, atomic physics, and quantum chemistry. DFT establishes that a system of $N$ interacting electrons…

等离子体物理 · 物理学 2020-04-29 Giovanni Manfredi

Direct correlation functions (DCFs), linked to the second functional derivative of the free energy with respect to the one-particle density, play a fundamental role in a statistical mechanics description of matter. This holds in particular…

软凝聚态物质 · 物理学 2021-08-25 S. -C. Lin , M. Oettel , J. M. Hring , R. Haussmann , M. Fuchs , G. Kahl

Density functional theory (DFT) offers a desirable balance between quantitative accuracy and computational efficiency in practical many-electron calculations. Its central component, the exchange-correlation energy functional, has been…

The frequency-dependent exchange-correlation potential, which appears in the usual Kohn-Sham formulation of a time-dependent linear response problem, is a strongly nonlocal functional of the density, so that a consistent local density…

凝聚态物理 · 物理学 2009-10-28 G. Vignale , Walter Kohn

Kohn-Sham density functional theory is the base of modern computational approaches to electronic structures. Their accuracy vitally relies on the exchange-correlation energy functional, which encapsulates electron-electron interaction…

计算物理 · 物理学 2019-11-04 Ryo Nagai , Ryosuke Akashi , Osamu Sugino

Time-dependent density functional theory, proposed recently in the context of atomic diffusion and non-equilibrium processes in solids, is tested against Monte Carlo simulation. In order to assess the basic approximation of that theory, the…

统计力学 · 物理学 2009-11-07 M. Kessler , W. Dieterich , H. L. Frisch , J. F. Gouyet , P. Maass

A theory of freezing of a dense hard sphere gas is presented. Starting from a revised Enskog theory, hydrodynamic equations that account for non-local variations in the density but local variations in the flow field are derived using a…

统计力学 · 物理学 2015-06-17 Arvind Baskaran , Aparna Baskaran , John Lowengrub

The practical success of density functional theory (DFT) is largely credited to the Kohn-Sham approach, which enables the exact calculation of the non-interacting electron kinetic energy via an auxiliary noninteracting system. Yet, the…

计算物理 · 物理学 2025-03-21 Sangita Majumdar , Zekun Shi , Giovanni Vignale

We propose an ansatz without adjustable parameters for the calculation of dynamical structure factor. The ansatz combines quasi-particle Green's function, especially the contribution from the renormalization factor, and the…

材料科学 · 物理学 2024-03-12 Yupei Zhang , Chongjie Mo , Ping Zhang , Wei Kang

We analytically construct the wave function that, for a given initial state, produces a prescribed density for a quantum ring with two non-interacting particles in a singlet state. In this case the initial state is completely determined by…

强关联电子 · 物理学 2013-08-23 M. Ruggenthaler , S. E. B. Nielsen , R. van Leeuwen

Predictivity of the Kohn-Sham approach to dynamical problems, when regarded as an initial value problem in a time-dependent density functional framework, is analysed for a class of models for which the argument devised in the work of Maitra…

其他凝聚态物理 · 物理学 2015-06-16 Walter Tarantino

Density Functional Theory's Kohn-Sham (KS) potential emerges as the minimizing effective potential in an unconstrained variational scheme that does not involve fixing the unknown single-electron density. The physical content behind the…

其他凝聚态物理 · 物理学 2007-05-23 N. I. Gidopoulos
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