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From magnetic susceptibility, dielectric permittivity, electric polarization and specific heat measurements, we discover spin-induced ferroelectricity and magnetoelectric coupling in Mn3TeO6 and observe two successive magnetic transitions…

材料科学 · 物理学 2015-12-01 L. Zhao , Z. Hu , C. Y. Kuo , T. -W. Pi , M. -K. Wu , L. H. Tjeng , A. C. Komarek

Two novel room-temperature phase transitions are observed, via synchrotron x-ray diffraction and Raman spectroscopy, in the Pb(Zr0.52Ti0.48)O3 alloy under hydrostatic pressures up to 16 GPa. A monoclinic (M)-to-rhombohedral (R1) phase…

凝聚态物理 · 物理学 2009-11-10 A. Sani , B. Noheda , I. A. Kornev , L. Bellaiche , P. Bouvier , J. Kreisel

Identification of novel multiferroic materials with high-ordering temperatures remains at the forefront of condensed matter physics research. In this regard, the antiferromagnetic RCrO$_3$ compounds (like GdCrO$_3$) constitute a promising…

We have investigated multiple caloric effects in multiferroic Y2CoMnO6. Polycrystalline sample prepared by solid state method has shown a ferromagnetic Curie temperature 75 K with second order phase transition; a maximum magneto entropy…

材料科学 · 物理学 2014-10-14 J. Krishna Murthy , A. Venimadhav

The controversy regarding the ferroelectric behavior of hexagonal InMnO$_3$ is resolved by using a combination of x-ray diffraction (XRD), piezoresponse force microscopy (PFM), second harmonic generation (SHG), and density functional theory…

The structure and the dielectric properties of Pb(Zn1/3Nb2/3)O3 (PZN) crystal have been investigated by means of high-resolution synchrotron x-ray diffraction (with an x-ray energy of 32 keV) and dielectric spectroscopy (in the frequency…

材料科学 · 物理学 2009-11-10 Y. -H. Bing , A. A. Bokov , Z. -G. Ye , B. Noheda , G. Shirane

We used inelastic neutron scattering to show that well below its N\'{e}el temperature, $T_{\rm N}$, the two-dimensional (2D) XY nearly-triangular antiferromagnet YMnO$_{3}$ has a prominent {\it central peak} associated with 2D…

材料科学 · 物理学 2009-11-10 T. J. Sato , S. -H. Lee , T. Katsufuji , M. Masaki , S. Park , J. R. D. Copley , H. Takagi

The coexistence of multiple ferroic orders, i.e. multiferroicity, is a scarce property to be found in materials. Historically, this state has been found mainly in 3-dimensional complex oxides, but so far this state has still been elusive…

The intermediate valence compound YbAl$_3$ is known to undergo a hybridization process between itinerant and localized electrons. The resulting heavy Fermi liquid remains non-magnetic and non-superconducting. A microscopic understanding of…

强关联电子 · 物理学 2014-11-27 W. K. Park , S. M. Narasiwodeyar , M. Dwyer , P. C. Canfield , L. H. Greene

The limited operational range of phase transition-based luminescence thermometers necessitates the exploration of new host materials exhibiting first-order structural phase transitions to broaden the applicability of this approach.…

材料科学 · 物理学 2025-04-03 M. Tahir Abbas , M. Szymczak , V. Kinzhybalo , D. Szymanski , M. Drozd , L. Marciniak

Ferroelectric films usually have phase states and physical properties very different from those of bulk ferroelectrics. Here we propose free-standing ferroelectric-elastic multilayers as a bridge between these two material systems. Using a…

材料科学 · 物理学 2011-10-18 S. Prokhorenko , N. A. Pertsev

Piezoelectric and ferroelectric ceramics with a high Curie temperature (Tc) have attracted a growing attention owning to their applications under severe environments. In this work, phase structure, dielectric, ferroelectric and…

BiMnO3 (BMO), ferromagnetic (FM) below Tc = 100 K, was believed to be also ferroelectric (FE) due to a non-centro-symmetric C2 structure, until diffraction data indicated that its space group is the centro-symmetric C2/c. Here we present…

强关联电子 · 物理学 2016-02-12 W. S. Mohamed , A. Nucara , G. Calestani , F. Mezzadri , E. Gilioli , F. Capitani , P. Postorino , P. Calvani

High real-space-resolution atomic pair distribution functions of La_(1-x)Ca_(x)MnO_3 (x=0.12, 0.25 and 0.33) have been measured using high-energy x-ray powder diffraction to study the size and shape of the MnO_6 octahedron as a function of…

材料科学 · 物理学 2009-10-31 S. J. L. Billinge , Th. Proffen , V. Petkov , J. L. Sarrao , S. Kycia

The interaction of coexisting structural instabilities in multiferroic materials gives rise to intriguing coupling phenomena and extraordinarily rich phase diagrams, both in bulk materials and strained thin films. Here we investigate the…

We have measured the photoemission spectra of Nd$_{1-x}$Sm$_{x}$NiO$_{3}$, where the metal-insulator transition and the N\'{e}el ordering occur at the same temperature for $x \lesssim 0.4$ and the metal-insulator transition temperature…

强关联电子 · 物理学 2009-11-07 K. Okazaki , T. Mizokawa , A. Fujimori , E. V. Sampathkumaran , M. J. Martinez-Lope , J. A. Alonso

Iron-pnictides Ca(Fe1-xRhx)2As2 (x = 0, 0.035, and 0.19) were studied across the tetragonal-orthorhombic and uncollapsed to collapsed tetragonal phase transitions using Raman spectroscopy. The effect of the phase separation was observed in…

超导电性 · 物理学 2023-08-21 V. P. Gnezdilov , A. Yu. Glamazda , P. Lemmens , K. Kudo , M. Nohara

LiCu_2O_2 single crystals were studied in the temperature range 300-1100 K by means of heating-cooling curves of differential thermal analysis (DTA), thermogravimetry (TG), X-ray powder diffraction and electrical measurements. A reversible…

材料科学 · 物理学 2013-09-19 S. A. Ivanov , A. A. Bush , K. E. Kamentsev , E. A. Tishchenko , M. Ottosson , R. Mathieu , P. Nordblad

The perovskite (1-x)YMnO$_3$-xBiFeO$_3$ binary system is very promising because of its multiferroic end members. Nanocrystalline phases have been recently obtained by mechanosynthesis across the system, and the perovskite structural…

We present direct evidence of above room temperature magneto-electricity in single-phase Li0.05Ti0.02Ni0.93O with above-ambient antiferromagnetic ordering. Temperature-hysteresis in warming/cooling heat-flow thermograms establishes a…

材料科学 · 物理学 2015-09-15 Jitender Kumar , Pankaj K. Pandey , A. M. Awasthi