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Using muon spin rotation, well-defined bulk ~ 100% magnetic phases in NaxCoO2 are revealed. A novel magnetic phase is detected for x = 0.85 with the highest transition temperature ever observed for x >= 0.75. This stresses the diversity of…

Transmission electron microscopy observations reveal the presence of complex superstructures and remarkable phase separation in association with Na-ordering phenomenon in y-Na0.5CoO2. Resistivity and magnetization measurements indicate that…

强关联电子 · 物理学 2007-05-23 H. X. Yang , Y. G. Shi , C. J. Nie , D. Wu , L. X. Yang , C. Dong , H. C. Yu , H. R. Zhang , C. Q. Jin , J. Q. Li

Using a combination of low-temperature nanocalorimetry and x-ray diffraction we identify three temperature regimes characterized by distinct Na ordering patterns (low temperature up to 290 K, intermediate 290-340 K, and high above 340 K).…

强关联电子 · 物理学 2016-10-11 Stanislaw Galeski , Kurt Mattenberger , Bertram Batlogg

We prove the direct link between low temperature magnetism and high temperature sodium ordering in NaxCoO2 using the example of a heretofore unreported magnetic transition at 8 K which involves a weak ferromagnetic moment. The 8 K feature…

强关联电子 · 物理学 2009-11-13 T. F. Schulze , P. S. Häfliger , C. Niedermayer , K. Mattenberger , S. Bubenhofer , B. Batlogg

Co-oxides beta-Na0.5CoO2 and gamma-K0.5CoO2 have been prepared by the Na de-intercalation from alpha-NaCoO2 and by the floating-zone method, respectively. It has been found that successive phase transitions take place at temperatures Tc1…

强关联电子 · 物理学 2009-11-11 H. Watanabe , Y. Mori , M. Yokoi , T. Moyoshi , M. Soda , Y. Yasui , Y. Kobayashi , M. Sato , N. Igawa , K. Kakurai

New electronic phases have been identified and placed in the (T,H) phase diagram of metallic NaxCoO2. At low Na-content (x = 0.36), the magnetic susceptibility diverges with a power law T^(-n), n<1, and shows (T,H) scaling, indicating the…

强关联电子 · 物理学 2007-05-23 F. Rivadulla , M. Banobre-Lopez , M. Garcia-Hernandez , M. A. Lopez-Quintela , J. Rivas

The magnetic properties of $\alpha$-NaFeO$_2$ are studied by neutron diffraction and magnetization measurements. An ordered phase with spins aligned along the b$_hex$ axis exists at low temperatures (T < 4 K). At intermediate temperatures…

强关联电子 · 物理学 2009-02-02 T. M. McQueen , Q. Huang , J. W. Lynn , R. F. Berger , T. Klimczuk , B. G. Ueland , P. Schiffer , R. J. Cava

We have performed specific heat and electric resistivity measurements of Na$_{x}$CoO$_{2}$ ($x=0.70$-0.78). Two anomalies have been observed in the specific heat data for $x=0.78$, corresponding to magnetic transitions at $T_{c}=22$ K and…

材料科学 · 物理学 2009-11-10 H. Sakurai , N. Tsujii , E. Takayama-Muromachi

Data taken by various kinds of methods including NMR/NQR and neutron scattering are presented for NaxCoO2, in particular, for Na0.5CoO2. Attentions have also been paid to the x dependence of the electronic nature. The pseudo-gap-like…

Thermodynamic and transport measurements on NaxCoO2 (x ~ 0.7-0.75) over a wide temperature range reveal a strongly enhanced low energy excitation spectrum. The zero-field specific heat and resistance at low temperature are proportional to…

强关联电子 · 物理学 2007-05-23 M. Brühwiler , B. Batlogg , S. M. Kazakov , J. Karpinski

The structure of Na0.5CoO2, the low temperature insulator that separates the magnetic and superconducting regions in the NaxCoO2.yH2O phase diagram, is studied by high resolution powder neutron diffraction at temperatures between 10 and 300…

强关联电子 · 物理学 2007-05-23 A. J. Williams , J. P. Attfield , M. L. Foo , R. J. Cava

Here we report an unconventional magnetic and transport phenomenon in a layered cobalt oxide, NaxCoO2. Only for x = 0.75, a magnetic transition of the second order was clearly detected at Tm ~ 22 K where an apparent specific-heat jump, an…

强关联电子 · 物理学 2009-11-07 T. Motohashi , R. Ueda , E. Naujalis , T. Tojo , I. Terasaki , T. Atake , M. Karppinen , H. Yamauchi

Powder Na$_{x}$CoO$_{2}$ ($0.70\leq x\leq 0.84$) samples were synthesized and characterized carefully by X-ray diffraction analysis, inductive-coupled plasma atomic emission spectroscopy, and redox titration. It was proved that…

材料科学 · 物理学 2009-11-10 H. Sakurai , S. Takenouchi , N. Tsujii , E. Takayama-Muromachi

The magnetic properties of alkali-metal peroxychromate K$_2$NaCrO$_8$ are governed by the $S = 1/2$ pentavalent chromium cation, Cr$^{5+}$. Specific heat, magnetocalorimetry, ac magnetic susceptibility, torque magnetometry, and inelastic…

We have investigated the preparation and bulk magnetic properties of NaxCoO2 in the range 0.5<x<0.95, including those for single crystals grown by the floating-zone method in an image furnace. To characterize the samples and ascertain their…

材料科学 · 物理学 2007-05-23 D. Prabhakaran , A. T. Boothroyd , R. Coldea , L. M. Helme , D. A. Tennant

We report results of specific heat measurements on polycrystalline samples of the layered superconductor, Na(0.3)CoO(2).1.3H(2)O. The electronic contribution to the specific heat, gamma, is found to be 12.2 mJ/mol-K2. The feature at the…

超导电性 · 物理学 2015-06-24 B. G. Ueland , P. Schiffer , R. E. Schaak , M. L. Foo , V. L. Miller , R. J. Cava

To evaluate the self-heating effects of FeCo magnetic nanoparticles, the surface oxidized FeCo nanoparticles were synthesized by co-precipitation method with the reduction reaction without any post treatments. As-synthesized FeCo…

介观与纳米尺度物理 · 物理学 2016-05-11 Jinu Kim , Baekil Nam , Ki Hyeon Kim

We report muon-spin rotation, heat capacity, magnetization, and ac magnetic susceptibility measurements of the layered spin-1/2 antiferromagnet NaNiO2. These show the onset of long-range magnetic order below T_N = 19.5K. Rapid muon…

强关联电子 · 物理学 2010-07-08 P. J. Baker , T. Lancaster , S. J. Blundell , M. L. Brooks , W. Hayes , D. Prabhakaran , F. L. Pratt

Phase diagram of Na$_x$CoO$_2$ (x $\gtrsim$ 0.71) has been reinvestigated using electrochemically fine tuned single crystals. Both phase separation and staging phenomena as a result of sodium multi-vacancy cluster ordering have been found.…

强关联电子 · 物理学 2009-07-13 G. J. Shu , F. -T. Huang , M. -W. Chu , J. -Y. Lin , Patrick A. Lee , F. C. Chou

We study thin films and magnetic tunnel junction nanopillars based on Ta/Co$_{20}$Fe$_{60}$B$_{20}$/MgO multilayers by electrical transport and magnetometry measurements. These measurements suggest that an ultrathin magnetic oxide layer…

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