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Spontaneous liquid-liquid phase separation is commonly understood in terms of phenomenological mean-field theories. These theories correctly predict the structural features of the fluid at sufficiently long time scales and wavelengths.…

软凝聚态物质 · 物理学 2019-07-11 Charley Schaefer , Stefan Paquay , Tom C. B. McLeish

We propose a hybrid Molecular Dynamics/Multi-particle Collision Dynamics model to simulate a set of self-assembled semiflexible filaments and free monomers. Further, we introduce a Monte-Carlo scheme to deal with single monomer addition…

软凝聚态物质 · 物理学 2012-02-29 Mathieu Caby , Priscilla Hardas , Sanoop Ramachandran , Jean-Paul Ryckaert

We study a two-component mixture of fermionic dipoles in two dimensions at zero temperature, interacting via a purely repulsive $1/r^3$ potential. This model can be realized with ultracold atoms or molecules, when their dipole moments are…

We present a Monte Carlo method to simulate asymmetric binary mixtures in the grand canonical ensemble. The method is used to study the colloid-polymer model of Asakura and Oosawa. We determine the phase diagram of the fluid-fluid unmixing…

软凝聚态物质 · 物理学 2007-05-23 R. L. C. Vink , J. Horbach

The sedimentation process of granular materials exists ubiquitously in nature and many fields which involve the solid-liquid separation. This paper employs the coupled computational fluid dynamics and discrete element method (CFD-DEM) to…

流体动力学 · 物理学 2017-11-07 Shan-Lin Xu , Rui Sun , Yuan-Qiang Cai , Hong-Lei Sun

Steady simple shear flow of a low-density binary mixture of inelastic smooth hard spheres is studied in the context of the Boltzmann equation. This equation is solved by using two different and complementary approaches: a Sonine polynomial…

软凝聚态物质 · 物理学 2009-11-07 J. M. Montanero , V. Garzo

The separation of substances into different phases is ubiquitous in nature and important scientifically and technologically. This phenomenon may become drastically different if the species involved, whether molecules or supramolecular…

We describe a Monte Carlo scheme for the grand canonical simulation study of fluid phase equilibria in highly size-asymmetrical binary mixtures. The method utilizes an expanded ensemble in which the insertion and deletion of large particles…

软凝聚态物质 · 物理学 2015-05-18 Douglas J. Ashton , Nigel B. Wilding

Colloidal suspensions with free polymer coils which are larger than the colloidal particles are considered. The polymer-colloid interaction is modeled by an extension of the Asakura-Oosawa model. Phase separation occurs into dilute and…

软凝聚态物质 · 物理学 2009-10-31 Richard P. Sear

Field-theoretical method is efficient in predicting the assembling structures of polymeric systems. However, for the polymer/nanoparticle mixture, the continuous density description is not suitable to capture the realistic assembly of…

软凝聚态物质 · 物理学 2017-05-17 Hui-shu Li , Bo-kai Zhang , Jian Li , Wen-de Tian , Kang Chen

Much work has been devoted to analysing thermodynamic models for solid dispersions with a view to identifying regions in the phase diagram where amorphous phase separation or drug recrystallization can occur. However, detailed partial…

软凝聚态物质 · 物理学 2020-06-26 Martin Meere , Giuseppe Pontrelli , Sean McGinty

We report the application of the Monte Carlo simulation to phase separation dynamics. First, we deal with the phase separation under shear flow. The thermal effect on the phase separation is discussed, and the anisotropic growth exponents…

统计力学 · 物理学 2015-06-25 Yutaka Okabe , Tsukasa Miyajima , Toshiro Ito , Toshihiro Kawakatsu

We present a theoretical model for predicting the phase behavior of polymer solutions in which phase separation competes with oligomerization. Specifically, we consider scenarios in which the assembly of polymer chains into stoichiometric…

软凝聚态物质 · 物理学 2024-07-31 Tianhao Li , W. Benjamin Rogers , William M. Jacobs

A semi-grand-canonical Monte Carlo algorithm is employed in conjunction with the bond fluctuation model to investigate the critical properties of an asymmetric binary (AB) polymer mixture. By applying the equal peak-weight criterion to the…

凝聚态物理 · 物理学 2009-10-22 M. Mueller , N. B. Wilding

In solution-processing of thin films, the material layer is deposited from a solution composed of several solutes and solvents. The final morphology and hence the properties of the film often depend on the time needed for the evaporation of…

We study by Monte Carlo simulation a binary mixture of neutral and dipolar hard-spheres with non-additive diameters. With a view to understanding the interplay between population inversion for an open pore and the demixing phase…

经典物理 · 物理学 2011-09-02 Charles Brunet , Jean Guillaume Malherbe , Said Amokrane

We theoretically study sedimentation-diffusion equilibrium of dilute binary, ternary, and polydisperse mixtures of colloidal particles with different buoyant masses and/or charges. We focus on the low-salt regime, where the entropy of the…

软凝聚态物质 · 物理学 2009-11-11 Jos Zwanikken , rene van Roij

A grand canonical Monte Carlo method for the simulation of a simple colloid-polymer mixture called the AO model will be described. The phase separation known to occur in this model is driven by entropy. The phase diagram of the unmixing…

软凝聚态物质 · 物理学 2007-05-23 R. L. C. Vink

Phase separation of two phase separating solutes in a common solvent can result in mesoscale (micron-sized) droplets with complex topologies of the domains of each solute within each droplet. Such topologies have been observed in-vitro in…

软凝聚态物质 · 物理学 2025-07-31 Amit Kumar , Gary H. Karpen , Samuel A. Safran

We present a new and general Monte Carlo iteration method for generalized ensembles. It consists of two elements: (1) a simple algorithm to distinguish between distributions arising from respectively equilibrium- and non-equilibrium…

凝聚态物理 · 物理学 2007-05-23 J. Borg