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We study the attractive interactions between rod-like charged polymers in solution that appear in the presence of multi-valence counterions. The counterions condensed to the rods exhibit both a strong transversal polarization and a…

软凝聚态物质 · 物理学 2009-10-31 Francisco J. Solis , Monica Olvera de la Cruz

We describe arrangements of ions capable of producing short-range attractive interactions between pairs of charged colloidal spheres in the low temperature strongly correlated limit. For particles of radius $R$ with bare charge $Z$ and…

强关联电子 · 物理学 2007-05-23 Francisco J. Solis , Monica Olvera de la Cruz

We propose a mean-field analytical model to account for the observed asymmetry in the ability to form long-range attraction by the negatively charged colloidal particles and not their equivalently charged positive counterpart. We conjecture…

软凝聚态物质 · 物理学 2009-11-13 William Kung , Monica Olvera de la Cruz

Screening of a strongly charged macroion by multivalent counterions is considered. It is shown that counterions form a strongly correlated liquid at the surface of the macroion. Cohesive energy of this liquid leads to additional attraction…

软凝聚态物质 · 物理学 2009-10-31 B. I. Shklovskii

The effective force between two parallel DNA molecules is calculated as a function of their mutual separation for different valencies of counter- and salt ions and different salt concentrations. Computer simulations of the primitive model…

软凝聚态物质 · 物理学 2009-11-10 E. Allahyarov , G. Gompper , H. Löwen

Experiments with polymer latex solutions show the coexistence of order-disorder structures of macroions. Because of the large macroions' sizes, this order-disorder phase coexistence imply the existence of very long-range attractive and…

软凝聚态物质 · 物理学 2019-02-20 Alfredo González-Calderón , Enrique González-Tovar , Marcelo Lozada-Cassou

We use Molecular Dynamics simulations to study attractive interactions and the underlying ionic correlations between parallel like-charged rods in the absence of additional salt. For a generic bulk system of rods we identify a reduction of…

软凝聚态物质 · 物理学 2009-11-07 Markus Deserno , Axel Arnold , Christian Holm

We study the effective electrostatic interactions between a pair of charged colloidal particles without salt ions while the system is confined in two dimensions. In particular we use a simplified model to elucidate the effects of rotational…

软凝聚态物质 · 物理学 2010-09-09 Chi-Lun Lee , Sio-Kit Ng

We calculate the interaction potential between two colloids immersed in an aqueous mixture containing salt near or above the critical temperature. We find an attractive interaction far from the coexistence curve due to the combination of…

软凝聚态物质 · 物理学 2015-06-03 Sela Samin , Yoav Tsori

A model system of highly asymmetric polyelectrolyte with directional short-range attractive interactions was studied by canonical Monte Carlo computer simulations. Comparison of MC data with previously published theoretical results shows…

软凝聚态物质 · 物理学 2021-10-12 J. Rescic

The nature of electrostatic interaction between like-charged particles at water-air interface is analyzed in this paper. We show that long-ranged electrostatic dipolar attraction between these objects generally exists. Our result provides a…

软凝聚态物质 · 物理学 2007-05-23 Yi Zhou , Tai-Kai Ng

The effective potential between charged colloids trapped at water interfaces is analyzed. It consists of a repulsive electrostatic and an attractive capillary part which asymptotically both show dipole--like behavior. For sufficiently large…

软凝聚态物质 · 物理学 2016-08-31 M. Oettel , A. Dominguez , S. Dietrich

The behavior of polyelectrolytes between charged surfaces immersed in semi-dilute solutions is investigated theoretically. A continuum mean field approach is used for calculating numerically concentration profiles between two electrodes…

软凝聚态物质 · 物理学 2007-05-23 I. Borukhov , D. Andelman , H. Orland

We examine the force between two charged surfaces immersed in aqueous mixtures having a coexistence curve. For a homogeneous water-poor phase, as the distance between the surfaces is decreased, a water-rich phase condenses at a distance…

统计力学 · 物理学 2015-05-27 Sela Samin , Yoav Tsori

From cement cohesion to DNA condensation, a proper statistical physics treatment of systems with long range forces is important for a number of applications in physics, chemistry, and biology. We compute here the effective force between…

软凝聚态物质 · 物理学 2018-03-14 E. Trizac , G. Téllez

We study the effective interaction mediated by strongly coupled Coulomb fluids between dielectric surfaces carrying quenched, random monopolar charges with equal mean and variance, both when the Coulomb fluid consists only of mobile…

软凝聚态物质 · 物理学 2020-10-01 Malihe Ghodrat , Ali Naji , Haniyeh Komaie-Moghaddam , Rudolf Podgornik

Screening of a macroion by multivalent counterions is considered. It is shown that ions form strongly correlated liquid at the macroion surface. Cohesive energy of this liquid leads to strong additional attraction of counterions to the…

软凝聚态物质 · 物理学 2009-10-31 V. I. Perel , B. I. Shklovskii

We consider the interactions between two uncharged planar macroscopic surfaces immersed in an electrolyte solution which are induced by interfacial selectivity. These forces are taken into account by introducing a depletion free-energy…

软凝聚态物质 · 物理学 2009-10-31 M. N. Tamashiro , P. Pincus

We study the interactions between two negatively charged macroscopic surfaces confining positive counterions. A density-functional approach is introduced which, besides the usual mean-field interactions, takes into account the correlations…

软凝聚态物质 · 物理学 2015-06-25 A. Diehl , M. N. Tamashiro , Marcia C. Barbosa , Yan Levin

For like charged colloidal particles two mechanisms of attraction between them survive when the interparticle distance is larger than the Debye screening length. One of them is the conventional van der Waals attraction and the second one is…

软凝聚态物质 · 物理学 2009-08-25 T. Ocampo-Delgado , B. Ivlev