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We perform quantum Monte Carlo (QMC) calculations to determine minimum energy pathways of simple chemical reactions, and compare the computed geometries and reaction barriers with those obtained with density functional theory (DFT) and…

化学物理 · 物理学 2015-06-12 Sebastiano Saccani , Claudia Filippi , Saverio Moroni

This work describes methodologies to successfully implement the Implicit Monte Carlo (IMC) scheme for thermal radiative transfer in reduced-precision floating-point arithmetic. The methods used can be broadly categorized into scaling…

计算物理 · 物理学 2025-10-27 Simon Butson , Mathew Cleveland , Alex Long , Todd Palmer

We reduce Dirac's spinor formalism for a spin 1/2 particle to a complex wavefunction description in curved spacetimes. We consider a localized fermionic particle in curved spacetimes and perform an expansion in terms of the acceleration and…

广义相对论与量子宇宙学 · 物理学 2022-06-07 T. Rick Perche , Jonas Neuser

Multi-degree splines are piecewise polynomial functions having sections of different degrees. They offer significant advantages over the classical uniform-degree framework, as they allow for modeling complex geometries with fewer degrees of…

数值分析 · 数学 2021-02-08 Carolina Vittoria Beccari , Giulio Casciola

Quantum computing has the potential to significantly speed up complex computational tasks, and arguably the most promising application area for near-term quantum computers is the simulation of quantum mechanics. To make the most of our…

量子物理 · 物理学 2019-12-10 Sean A. Fischer , Daniel Gunlycke

In recent years efficient algorithms have been developed for the numerical computation of relativistic single-particle path integrals in quantum field theory. Here, we adapt this "worldline Monte Carlo" approach to the standard problem of…

We formulate a quantum Monte Carlo (QMC) method for calculating the ground state of many-boson systems. The method is based on a field-theoretical approach, and is closely related to existing fermion auxiliary-field QMC methods which are…

计算物理 · 物理学 2009-11-10 Wirawan Purwanto , Shiwei Zhang

We study the Hubbard model using the Cellular Dynamical Mean-Field Theory (CDMFT) with quantum Monte Carlo (QMC) simulations. We present the algorithmic details of CDMFT with the Hirsch-Fye QMC method for the solution of the…

强关联电子 · 物理学 2009-11-11 B. Kyung , G. Kotliar , A. -M. S. Tremblay

The feature vector mapping used to represent chemical systems is a key factor governing the superior data-efficiency of kernel based quantum machine learning (QML) models applicable throughout chemical compound space. Unfortunately, the…

化学物理 · 物理学 2023-08-02 Danish Khan , Stefan Heinen , O. Anatole von Lilienfeld

Quantum computers have a potential for solving quantum chemistry problems with higher accuracy than classical computers. Quantum computing quantum Monte Carlo (QC-QMC) is a QMC with a trial state prepared in quantum circuit, which is…

量子物理 · 物理学 2024-06-07 Shu Kanno , Hajime Nakamura , Takao Kobayashi , Shigeki Gocho , Miho Hatanaka , Naoki Yamamoto , Qi Gao

We present an efficient low-rank updating algorithm for updating the trial wavefunctions used in Quantum Monte Carlo (QMC) simulations. The algorithm is based on low-rank updating of the Slater determinants. In particular, the computational…

材料科学 · 物理学 2009-06-25 Phani K. V. V. Nukala , P. R. C. Kent

High-dimensional multimodal sampling problems from lattice field theory (LFT) have become important benchmarks for machine learning assisted sampling methods. We show that GPU-accelerated particle methods, Sequential Monte Carlo (SMC) and…

机器学习 · 统计学 2025-11-20 David Yallup

Phaseless Auxiliary-Field Quantum Monte Carlo (ph-AFQMC) has recently emerged as a promising method for the production of benchmark-level simulations of medium to large-sized molecules, due to its accuracy and favorable polynomial scaling…

It is often computationally advantageous to model space as a discrete set of points forming a lattice grid. This technique is particularly useful for computationally difficult problems such as quantum many-body systems. For reasons of…

量子气体 · 物理学 2021-10-13 Young-Ho Song , Youngman Kim , Ning Li , Bing-Nan Lu , Rongzheng He , Dean Lee

The Quantum Monte Carlo method for spin 1/2 fermions at finite temperature is formulated for dilute systems with an s-wave interaction. The motivation and the formalism are discussed along with descriptions of the algorithm and various…

统计力学 · 物理学 2009-02-05 Aurel Bulgac , Joaquin E. Drut , Piotr Magierski

Microscopic processes on surfaces such as adsorption, desorption, diffusion and reaction of interacting particles can be simulated using kinetic Monte Carlo (kMC) algorithms. Even though kMC methods are accurate, they are computationally…

数学物理 · 物理学 2013-12-24 Yannis Pantazis , Markos Katsoulakis

Quasi-Monte Carlo (qMC) methods are a powerful alternative to classical Monte-Carlo (MC) integration. Under certain conditions, they can approximate the desired integral at a faster rate than the usual Central Limit Theorem, resulting in…

计量经济学 · 经济学 2019-11-22 Jean-Jacques Forneron

High order perturbation theory has seen an unexpected recent revival for controlled calculations of quantum many-body systems, even at strong coupling. We adapt integration methods using low-discrepancy sequences to this problem. They…

The paper is devoted to problem of spline approximation. A new method of nodes location for curves and surfaces computer construction by means of B-splines and results of simulink-modeling is presented. The advantages of this paper is that…

数值分析 · 计算机科学 2011-07-22 Annapurna Sharma , Hakimjon Zaynidinov , Hoon Jae Lee

Local constraint is closely related to the gauge field, so constrained models are usually effective low energy descriptions and important in condensed matter physics. On the other hand, local restriction hinders the application of numerical…

统计力学 · 物理学 2022-10-11 Zheng Yan