相关论文: New Pyrochlore Oxide Superconductor RbOs2O6
In the exploration of new osmium based double perovskites, Sr2FeOsO6 is a new insertion in the existing family. The polycrystalline compound has been prepared by solid state synthesis from the respective binary oxides. PXRD analysis shows…
We report the discovery of a new noncentrosymmetric superconductor CaPtAs. It crystallizes in a tetragonal structure (space group $I4_1md$, No.109), featuring three dimensional honeycomb networks of Pt-As and a much elongated $c$-axis ($a =…
We report appearance of superconductivity at 5K in NdO0.5F0.5BiS2 and supplement the discovery [1] of the same in layered sulfide based ZrCuSiAs type compounds. The bulk polycrystalline compound is synthesized by conventional solid state…
We have synthesized two iron fluo-arsenides $A$Ca$_2$Fe$_4$As$_4$F$_2$ with $A$ = Rb and Cs, analogous to the newly discovered superconductor KCa$_2$Fe$_4$As$_4$F$_2$. The quinary inorganic compounds crystallize in a body-centered…
We report a comprehensive investigation of the physical properties of LuOs3B2, characterized by an ideal Os-based kagome lattice. Resistivity and magnetization measurements confirm the emergence of type-II bulk superconductivity with a…
We propose a superlattice model to describe superconductivity in layered materials, such as the borocarbide families with the chemical formul\ae\ $RT_2$B$_2$C and $RT$BC, with $R$ being (essentially) a rare earth, and $T$ a transition…
A new BiS2-based superconductor Bi2(O,F)S2 was discovered. This is a layered compound consisting of alternate stacking structure of rock-salt-type BiS2 superconducting layer and fluorite-type Bi(O,F) blocking layer. Bi2(O,F)S2 was obtained…
We have investigated the superconducting properties in a single crystal of a new superconductor Pb$_{2}$Pd via various techniques including magnetization, AC transport, transverse field muon spin rotation and relaxation (TF-$\mu$SR), and…
We report synthesis, crystal structure and physical properties of a novel quinary compound RbGd$_2$Fe$_4$As$_4$O$_2$. The new iron oxyarsenide is isostructural to the fluo-arsenide KCa$_2$Fe$_4$As$_4$F$_2$, both of which contain separate…
The recent discovery of superconductivity at 190~K in highly compressed H$_{2}$S is spectacular not only because it sets a record high critical temperature, but because it does so in a material that appears to be, and we argue here that it…
Superconductivity is observed in a new nontoxic cuprate system Ga-Ba-Ca-Cu-O, with Tc = 82K for GaBa2Ca5Cu6O14+{\delta} (Ga-1256) and Tc = 116K probably for GaBa2Ca3Cu4O10+{\delta} (Ga-1234) or GaBa2Ca2Cu3O8+{\delta} (Ga-1223),…
We report appearance of superconductivity in CeO0.5F0.5BiS2. The bulk polycrystalline samples CeOBiS2 and CeO0.5F0.5BiS2 are synthesized by conventional solid state reaction route via vacuum encapsulation technique. Detailed structural…
Recently, a host/guest clathrate SrB3C3 with sp3-bonded boron-carbon framework was synthesized at around 50 GPa. On the basis of electron count, the structure is understood as guest Sr2+ cations intercalated in the (B3C3)3- framework.…
The discovery of high-temperature superconductivity in La3Ni2O7 and La4Ni3O10 under high pressure indicates that the Ruddlesden-Popper (RP) phase nickelates Rn+1NinO3n+1 (R = rare earth) is a new material family for high-temperature…
Satterthwaite and Toepke (1970 Phys. Rev. Lett. 25 741) predicted high-temperature superconductivity in hydrogen-rich metallic alloys, based on an idea that these compounds should exhibit high Debye frequency of the proton lattice, which…
Transition metal oxides of the $4d$ and $5d$ block have recently become the targets of materials discovery, largely due to their strong spin-orbit coupling that can generate exotic magnetic and electronic states. Here we report the high…
The newly discovered superconductor FeSe1-x (x=0.08, Tconset=13.5 K at ambient pressure rising to 27 K at 1.48 GPa) exhibits a structural phase transition from tetragonal to orthorhombic below 70 K at ambient pressure - the crystal…
Bulk superconductivity has been discovered in Tl_{0.6}Bi_{2}Te_{3}, which is derived from the topological insulator Bi2Te3. The superconducting volume fraction of up to 95% (determined from specific heat) with Tc of 2.28 K was observed. The…
By tackling the challenge of extending transparent oxide semiconductors to Ge based oxides, we have found a not-yet-reported crystal structure, named $\beta$-SrGe$_2$O$_5$, which is composed of edge-sharing GeO$_6$ octahedra interconnected…
We report the synthesis and characterization of a new compound Mg$_4$Pd$_7$As$_6$, which was found to be a superconductor with $T_c=5.45$~K. Powder X-ray diffraction confirms the U$_4$Re$_7$Si$_6$ structure (space group $Im$-$3m$, no. 229)…