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When an ionic liquid adsorbs onto a porous electrode, its ionic arrangement is deeply modified due to a screening of the Coulombic interactions by the metallic surface and by the confinement imposed upon it by the electrode's morphology. In…

Nanopores in solid state membranes are a tool able to probe nanofluidic phenomena or can act as a single molecular sensor. They also have diverse applications in filtration, desalination or osmotic power generation. Many of these…

Electrochemical phenomena in biology often unfold in confined geometries where micrometer- to millimeter-scale domains coexist with nanometer-scale interfacial diffuse charge layers. We analyze a model lipid membrane-electrolyte system…

软凝聚态物质 · 物理学 2025-08-20 Joshua B. Fernandes , Hyeongjoo Row , Kranthi K. Mandadapu , Karthik Shekhar

The Donnan model describes the electric double layer structure inside carbon micropores and is an essential element of larger-scale models for capacitive porous carbon electrodes for energy storage and water desalination. The Donnan model…

化学物理 · 物理学 2020-05-04 P. M. Biesheuvel

We study the Schloegl model in a vesicle with semi-permeable membrane. The diffusion constant takes a smaller value in the membrane region, which prevents the outflow of self-catalytic product. A nonequilibrium state is stably maintained…

统计力学 · 物理学 2009-11-11 Hidetsugu Sakaguchi

In recent years, ionic microgels have garnered much attention due to their unique properties, especially their stimulus-sensitive swelling behavior. The tunable response of these soft, permeable, compressible, charged colloidal particles is…

软凝聚态物质 · 物理学 2023-12-18 Mohammed O. Alziyadi , Alan R. Denton

The rectification of electro-osmotic flows is important in micro/nano fluidics applications such as micro-pumps and energy conversion devices. Here, we propose a simple electro-osmotic diode in which colloidal particles are contained…

介观与纳米尺度物理 · 物理学 2021-10-04 Shihori Koyama , Daisuke Inoue , Akihisa Okada , Hiroaki Yoshida

The movement of small particles and molecules through membranes is widespread and has far-reaching implications. Consequently, the development of mathematical models is essential for understanding these processes on a micro level, leading…

We investigate numerically and on the scaling level the adsorption of a charged colloid on an oppositely charged flexible membrane. We show that the long ranged character of the electrostatic interaction leads to a wrapping reentrance of…

生物物理 · 物理学 2009-11-10 Christian C. Fleck , Roland R. Netz

Spatial interaction effects between charge carriers in ionic systems play a sizable role beyond a classical Maxwellian description. We develop a nonlocal, two-fluid, hydrodynamic theory of charges and study ionic plasmon effects, i. e.…

光学 · 物理学 2020-06-30 Christin David

Understanding the electrodes' surface morphology influence on the ions' distribution is essential for designing the supercapacitors with enhanced energy density characteristics. We develop a model for the structure of electrolytes near the…

统计力学 · 物理学 2021-06-30 Timur Aslyamov , Konstantin Sinkov , Iskander Akhatov

In this paper we study a mathematical model that represents the concentration polarization and osmosis effects in a reverse osmosis cross-flow channel with porous membranes at some of its boundaries. The fluid is modeled using the…

数值分析 · 数学 2022-12-19 Nicolás Carro , David Mora , Jesus Vellojin

A model of dense plasmas relying on the superconfiguration approximation is presented. In each superconfiguration the nucleus is totally screened by the electrons in a Wigner-Seitz sphere (ion-sphere model). Superconfigurations of the same…

原子物理 · 物理学 2007-06-26 Jean-Christophe Pain

I derive formulas for the electrostatic potential of a charge in or near a membrane modeled as one or more dielectric slabs lying between two semi-infinite dielectrics. One can use these formulas in Monte Carlo codes to compute the…

定量方法 · 定量生物学 2015-05-27 Kevin Cahill

An ideal conductor electrode in contact with a semi-infinite two-dimensional two-component plasma in an external potential is considered. The model is mapped onto an integrable sine-Gordon theory with Dirichlet boundary conditions. The…

统计力学 · 物理学 2011-07-19 L. Šamaj , B. Jancovici

A continuum electromechanical model is proposed to describe the membrane curvature induced by electrostatic interactions in a solvated protein-membrane system. The model couples the macroscopic strain energy of membrane and the…

定量方法 · 定量生物学 2015-05-19 Y. C. Zhou , Benzhuo Lu , Alemayehu A. Gorfe

We give an explicit formula for the membrane potential of cells in terms of the intracellular and extracellular ionic concentrations, and derive equations for the ionic currents that flow through channels, exchangers and electrogenic pumps.…

生物物理 · 物理学 2007-05-23 L. P. Endresen , K. Hall , J. S. Hoye , J. Myrheim

The paper presents a theoretical model that allows the dynamic description of osmotic flows through a semi-permeable interface. To depict the out-of-equilibrium transfer, the interface is represented by an energy barrier that colloids have…

软凝聚态物质 · 物理学 2017-09-18 Patrice Bacchin

We consider equilibrium statistical mechanics of a simplified model for the ideal conductor electrode in an interface contact with a classical semi-infinite electrolyte, modeled by the two-dimensional Coulomb gas of pointlike $\pm$ unit…

统计力学 · 物理学 2009-11-11 L. Samaj , Z. Bajnok

A membrane can be represented by an energy landscape that solutes or colloids must cross. A model accounting for the momentum and the mass balances on the membrane energy landscape establishes a new way of writing for the Darcy law. The…

软凝聚态物质 · 物理学 2018-06-12 Patrice Bacchin