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In this paper we elucidate the optical response resulting from the interplay of charge distribution (ionicity) and Peierls instability (dimerization) in the neutral-ionic, ferroelectric phase transition of tetrathiafulvalene-chloranil…

其他凝聚态物理 · 物理学 2021-11-23 A. Girlando , M. Masino , A. Painelli , N. Drichko , M. Dressel , A. Brillante , R. G. Della Valle , E. Venuti

The neutral-to-ionic phase transition in the mixed-stack charge-transfer complex tetrathiafulvalene-p-chloranil (TTF-CA) has been studied by pressure-dependent infrared spectroscopy up to p=11 kbar and down to low temperatures, T = 10 K. By…

强关联电子 · 物理学 2014-07-01 A. Dengl , R. Beyer , T. Peterseim , T. Ivek , G. Untereiner , M. Dressel

The dipole P(F) of systems with periodic boundary conditions (PBC) in a static electric field F is applied to one-dimensional Peierls-Hubbard models for organic charge-transfer (CT) salts. Exact results for P(F) are obtained for finite…

强关联电子 · 物理学 2009-11-10 Zoltan G. Soos , Sharon A. Bewick , Andrea Peri , Anna Painelli

For electronic states and photoinduced charge dynamics near the neutral-ionic transition in the mixed-stack charge-transfer complex tetrathiafulvalene-$p$-chloranil (TTF-CA), we review the effects of Peierls coupling to lattice phonons…

强关联电子 · 物理学 2015-05-28 Kenji Yonemitsu

We report a detailed spectroscopic investigation of temperature-induced valence and structural instability of the mixed-stack organic charge-transfer (CT) crystal 4,4'-dimethyltetrathiafulvalene-chloranil (DMTTF-CA). DMTTF-CA is a…

材料科学 · 物理学 2024-11-26 Paolo Ranzieri , Matteo Masino , Alberto Girlando , Marie-Helene Lemee-Cailleau

We investigated microscopic lattice states in the donor-acceptor ionic Mott insulator, TTF-BA, by $^{79}$Br-NQR spectroscopy to explore cross-correlated fluctuations between spin, charge and lattice. A ferroelectric transition with lattice…

强关联电子 · 物理学 2021-08-11 Keishi Sunami , Tomohiro Baba , Kazuya Miyagawa , Sachio Horiuchi , Kazushi Kanoda

Photoinduced dynamics of charge density and lattice displacements is calculated by solving the time-dependent Schr\"odinger equation for a one-dimensional extended Peierls-Hubbard model with alternating potentials for the mixed-stack…

强关联电子 · 物理学 2007-05-23 Kenji Yonemitsu

We report a detailed spectroscopic study of the pressure induced neutral-ionic phase transition (NIT) of the mixed-stack charge-transfer (CT) crystal tetrathiafulvalene-chloranil (TTF-CA). We show that the pressure induced phase transition…

材料科学 · 物理学 2013-05-29 Matteo Masino , Alberto Girlando , Aldo Brillante

Strong coupling of charge, spin, and lattice in solids brings about emergent elementary excitations with their intertwining and, in one dimension, solitons are known as such. The charge-transferred organic ferroelectric, TTF-CA, has been…

强关联电子 · 物理学 2023-04-12 R. Takehara , H. Adachi , K. Sunami , K. Miyagawa , T. Miyamoto , H. Okamoto , S. Horiuchi , K. Kanoda

We investigate the dynamics of correlated charge carriers in the vicinity of the Mott metal-to-insulator transition in various of the title quasi-two-dimensional organic charge-transfer salts by means of fluctuation (noise) spectroscopy.…

强关联电子 · 物理学 2015-03-19 Jens Brandenburg , Jens Müller , Dieter Schweitzer , John A. Schlueter

Charge-ordering phenomena have been highly topical over the last few years. A phase transition towards a charge ordered state has been observed experimentally in several classes of materials. Among them, many studies have been devoted to…

强关联电子 · 物理学 2013-08-01 Mariano de Souza , Jean-Paul Pouget

The quantum phase transition between a repulsive Luttinger liquid and an insulating Peierls state is studied in the framework of the one-dimensional spinless Holstein model. We focus on the adiabatic regime but include the full quantum…

强关联电子 · 物理学 2011-03-08 Martin Hohenadler , Holger Fehske , Fakher F. Assaad

Real-time dynamics of charge density and lattice displacements is studied during photoinduced ionic-to-neutral phase transitions by using a one-dimensional extended Peierls-Hubbard model with alternating potentials for the one-dimensional…

材料科学 · 物理学 2009-11-07 Naoyuki Miyashita , Makoto Kuwabara , Kenji Yonemitsu

The prototype compound for the neutral-ionic phase transition, namely TTF-CA, is theoretically investigated by first-principles density functional theory calculations. The study is based on three neutron diffraction structures collected at…

凝聚态物理 · 物理学 2009-11-07 V. Oison , C. Katan , P. Rabiller , M. Souhassou , C. Koenig

The quasi-one-dimensional organic conductors (TMTTF)$_2X$ with non-centrosymmetric anions commonly undergo charge- and anion-order transitions upon cooling. While for compounds with tetrahedral anions ($X$ = BF$_4^-$, ReO$_4^-$, and…

We consider an electron-phonon system in two and three dimensions on square, hexagonal and cubic lattices. The model is a modification of the standard Holstein model where the optical branch is appropriately curved in order to have a…

统计力学 · 物理学 2009-10-31 N. Macris , C. -A. Piguet

Dynamics of charge density and lattice displacements after the neutral phase is photoexcited is studied by solving the time-dependent Schr\"odinger equation for a one-dimensional extended Peierls-Hubbard model with alternating potentials.…

强关联电子 · 物理学 2007-05-23 Kenji Yonemitsu

The Peierls instability in one-dimensional electron-phonon systems is known to be qualitatively well described by the Mean-Field theory, however the related self-consistent problem so far has only been able to predict a partial suppression…

强关联电子 · 物理学 2021-10-04 Alain M. Dikande , C. Bourbonnais

We investigate the exotic Peierls state in the one-dimensional organic compound (EDO-TTF)_{2}X, wherein the Peierls transition is accompanied by the bending of molecules and also by a fourfold periodic array of charge disproportionation…

强关联电子 · 物理学 2008-06-26 M. Tsuchiizu , Y. Suzumura

We investigate the charge and lattice states in a quasi-one-dimensional organic ferroelectric material, TTF-QCl$_{4}$, under pressures of up to 35 kbar by nuclear quadrupole resonance experiments. The results reveal a global…

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