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An extensive theoretical investigation of the nonpolar (10$\bar{1}$0) and (11$\bar{2}$0) surfaces as well as the polar zinc terminated (0001)--Zn and oxygen terminated (000$\bar{1}$)--O surfaces of ZnO is presented. Particular attention is…

材料科学 · 物理学 2009-11-07 B. Meyer , Dominik Marx

Using density-functional theory in combination with a thermodynamic formalism we calculate the relative stability of various structural models of the polar O-terminated (000-1)-O surface of ZnO. Model surfaces with different concentrations…

材料科学 · 物理学 2009-11-10 B. Meyer

We report results of density-functional theory calculations on the structural, magnetic, and electronic properties of (1x1)-structures of Co on Cu(001) for coverages up to two monolayers. In particular we discuss the tendency towards phase…

材料科学 · 物理学 2009-10-31 R. Pentcheva , M. Scheffler

In this work we have employed density-functional theory with hybrid functionals to investigate the atomic and electronic structure of bare and hydrogenated Co doped ZnO nanowires. We find that in the absence of passivation on the nanowire…

材料科学 · 物理学 2018-08-09 A. L. Rosa , L. L. Tacca , Th. Frauenheim

The adsorption of hydrogen on the polar Zn-ended ZnO(0001) surface has been investigated by density functional {\it ab-initio} calculations. An on top H(1x1) ordered overlayer with genuine H-Zn chemical bonds is shown to be energetically…

材料科学 · 物理学 2015-05-13 N. Sanchez , S. Gallego , J. Cerdá , M. C. Muñoz

This study combines surface-sensitive photoemission experiments with density functional theory (DFT) to give a microscopic description of H adsorption-induced modifications of the ZnO(10${\overline{1}}$0) surface electronic structure. We…

材料科学 · 物理学 2015-06-23 J. -C. Deinert , O. T. Hofmann , M. Meyer , P. Rinke , J. Stähler

Tricobalt tetraoxide (Co3O4) is an important catalyst and Co3O4(110) is a frequently exposed surface in Co3O4 nanomaterials. We employed Density-functional theory with on-site Coulomb repulsion U term to study the atomic structures,…

材料科学 · 物理学 2015-06-04 Jia Chen , Annabella Selloni

We present a first-principles computational study of non-polar ZnO (10$\bar{1}$0) surfaces doped with indium. The calculations were performed using a model ZnO slab. The position of the In dopants was varied from deep bulk-like layers to…

We utilize classical molecular dynamics to study surface effects on the piezoelectric properties of ZnO nanowires as calculated under uniaxial loading. An important point to our work is that we have utilized two types of surface treatments,…

材料科学 · 物理学 2012-10-24 Shuangxing Dai , Harold S. Park

The structure-property relation of nanostructured Al-doped ZnO thin films has been investigated in detail through a systematic variation of structure and morphology, with particular emphasis on how they affect optical and electrical…

材料科学 · 物理学 2013-11-28 P. Gondoni , M. Ghidelli , F. Di Fonzo , M. Carminati , V. Russo , A. Li Bassi , C. S. Casari

In this work we have employed density-functional theory with hybrid functionals to investigate the atomic and electronic structure of bare and hydrogenated Mn doped ZnO nanowires with small diameter. We determine changes in magnetic and…

材料科学 · 物理学 2018-10-23 A. L. Rosa , L. L. Tacca , E. N. Lima , Th. Frauenheim

Using density-functional-theory we study the electronic and structural properties of a monolayer of Cu on the fcc (100) and (111) surfaces of the late 4d transition metals, as well as a monolayer of Pd on Mo bcc(110). We calculate the…

We have studied the structural, magnetic and electronic properties of Co-implanted ZnO (0001) films grown on Al2O3 (1120) substrates for different implantation doses and over a wide temperature range. Strong room temperature ferromagnetism…

Colloidal zinc oxide (ZnO) nanoparticles are frequently used in the field of organic photovoltaics for the realization of solution-producible, electron-selective interfacial layers. Despite of the widespread use, there is a lack of detailed…

应用物理 · 物理学 2019-04-25 Sebastian Wilken , Jürgen Parisi , Holger Borchert

In this work we investigate the electronic properties of mercaptocarboxylic acids with several carbon chain lengths adsorbed on ZnO-(10-10) surfaces via density functional theory calculations using semi-local and hybrid exchange-correlation…

材料科学 · 物理学 2018-10-05 Dennis Franke , Michael Lorke , Thomas Frauenheim , Andrea L. daRosa

Understanding the structure of ZnO surface reconstructions and their resultant properties is crucial to the rational design of ZnO-containing devices ranging from optoelectronics to catalysts. Here, we are motivated by recent experimental…

材料科学 · 物理学 2017-02-02 Ryan Jacobs , Bing Zheng , Brian Puchala , Paul M. Voyles , Andrew B. Yankovich , Dane Morgan

We perform molecular dynamics (MD) simulations to investigate the effect of polar surfaces on the thermal transport in zinc oxide (ZnO) nanowires. We find that the thermal conductivity in nanowires with free polar (0001) surfaces is much…

材料科学 · 物理学 2014-03-19 Jin-Wu Jiang , Harold S. Park , Timon Rabczuk

Our ab initio calculations of CO adsorption on several low and high miller index surfaces of Cu show that the adsorption energy increases as the coordination of the adsorption site decreases from 11 to 6, in qualitative agreement with…

材料科学 · 物理学 2013-05-29 Faisal Mehmood , Abdelkader Kara , Talat S. Rahman , Klaus Peter Bohnen

A comparative study of the physical properties of undoped Zinc Oxide (ZnO) and Al doped Zinc Oxide (AZO) thin films were performed as a function of annealing temperature. The structural properties were analyzed using X-ray diffraction and…

应用物理 · 物理学 2019-09-06 Joydip Sengupta , R. K. Sahoo , C. D. Mukherjee

The atomic surface and interface structure of bare and metal-coated ZnO(0001) Zn-polar wafers were investigated via surface x-ray diffraction. All bare samples showed the presence of a (1x1) overlayer of oxygen atoms located at the on-top…

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