相关论文: Methyl group dynamics in a confined glass
We present results of molecular dynamics simulations on lithium metasilicate over a broad range of temperatures for which the silicate network is frozen in but the lithium ions can still be equilibrated. The lithium dynamics is studied via…
Performing molecular dynamics simulations, we investigate the enormous slowdowns of water dynamics when approaching a glass transition or a solid interface. We show that both effects can be described on common grounds within a theoretical…
Recent experiments showing scaling of the intrachromosomal contact probability, $P(s)\sim s^{-1}$ with the genomic distance $s$, are interpreted to mean a self-similar fractal-like chromosome organization. However, scaling of $P(s)$ varies…
In conventional glassformers at sufficiently short times and low enough temperatures, molecules are mutually caged by the intermolecular potential. The fluctuation and dissipation from motion of caged molecules when observed by elastic…
We study experimentally the origin of heterogeneous dynamics in strongly driven glass-forming systems. Thereto, we apply a well-defined force with a laser line trap on individual colloidal polystyrene probe particles seeded in an emulsion…
We study the dynamics of torque driven spherical spinners settled on a surface, and demonstrate that hydrodynamic interactions at finite Reynolds numbers can lead to a concentration dependent and non-uniform crystallisation. At semi-dilute…
The phase behavior of hydrocarbon fluids confined in porous media has been reported to deviate significantly from that in the bulk environment due to the existence of sub-10nm pores. Though experiments and simulations have measured the…
We have performed depth dependent muon spin rotation/relaxation studies of the dynamics of single layer films of {\it Au}Fe and {\it Cu}Mn spin glasses as a function of thickness and of its behavior as a function of distance from the vacuum…
This paper investigates the dynamical generation of entanglement in scattering systems, in particular two spin systems that interact via rotationally-invariant scattering. The spin degrees of freedom of the in-states are assumed to be in…
The dynamics of thin volatile droplets comprising of binary mixtures deposited on a heated substrate are investigated. Using lubrication theory, we develop a novel one-sided model to predict the spreading and retraction of an evaporating…
Systems in which a short-ranged attraction and long-ranged repulsion compete are intrinsically frustrated, leading their structure and dynamics to be dominated either by mesoscopic order or by metastable disorder. Here we report the latter…
Binary mixtures of water with lower alcohols display non-linear phase behaviour upon mixing which are attributed to potential cluster formation at molecular level. Unravelling such elusive structures requires the investigation of…
Molecular dynamics simulations are carried out to investigate mechanical properties and porous structure of binary glasses subjected to steady shear. The model vitreous systems were prepared via thermal quench at constant volume to a…
Electron spin resonance (ESR) experiments were performed with antiferromagnetic MnO confined within a porous vycor-type glass and within MCM-type channel matrices. A signal from confined MnO shows two components from crystallized and…
The complex behavior of confined fluids arising due to a competition between layering and local packing can be disentangled by considering quasi-confined liquids, where periodic boundary conditions along the confining direction restore…
We explore, by means of inelastic neutron scattering, the extent of changes in dynamic correlations induced by thermal poling of vitreous $SiO_2$. The measured vibrational density of states shows an excess of modes in certain frequency…
The diffusion of small molecular penetrants through polymeric materials represents an important fundamental problem, relevant to the design of materials for applications such as coatings and membranes. Polymer networks hold promise in these…
We show that a fluid under strong spatially periodic confinement displays a glass transition within mode-coupling theory (MCT) at a much lower density than the corresponding bulk system. We use fluctuating hydrodynamics, with confinement…
Soft-granular media, such as dense emulsions, foams or tissues, exhibit either fluid- or solid-like properties depending on the applied external stresses. Whereas bulk rheology of such materials has been thoroughly investigated, the…
We study glassy dynamics using a simulation of three soft Brownian particles confined to a two-dimensional circular region. If the circular region is large, the disks freely rearrange, but rearrangements are rarer for smaller system sizes.…