相关论文: Solvent evaporation of spin cast films: crust effe…
We consider solutions where the surface tension of the solvent is smaller than the surface tension of the polymer. In an evaporating film, a plume of solvent rich fluid, then induces a local depression in surface tension, and the surface…
After impact onto a smooth dry surface, a drop of viscous liquid initially spreads in the form of a thick lamella. If the drop splashes, it first emits a thin fluid sheet that can ultimately break up into droplets causing the splash.…
Glassy polymers show strain hardening: at constant extensional load, their flow first accelerates, then arrests. Recent experiments have found this to be accompanied by a striking and unexplained dip in the segmental relaxation time. Here…
Thin polymer films have attracted attention because of both their broad range of applications and of the fundamental questions they raise regarding the dynamic response of confined polymers. These films are unstable if the temperature is…
Solvent evaporation in soft matter solutions (solutions of colloidal particles, polymers and their mixtures) is an important process in material making and in printing and coating industries. The solvent evaporation process determines the…
Glassy polymers show strain hardening: at constant extensional load, their flow first accelerates, then arrests. Recent experiments under such loading have found this to be accompanied by a striking dip in the segmental relaxation time.…
We report surface hardening or crust formation, unlike caking, during drying when a confined porous medium was heated from above using IR radiation. These crusts have higher strength than their closest counterparts such as sandcastles and…
We report on the rejuvenation of thin films of polystyrene (PS) as they are heated from stable glassy states - prepared either through vapour deposition or physical aging. For films with thickness $h \gtrsim 200$ nm, the rejuvenation of…
Despite their technological relevance, a full microscopic understanding of glasses is still lacking. This applies even more to their surfaces whose properties largely differ from that of the bulk material. Here, we experimentally…
Evaporating droplets of polymer or colloid solution may produce a glassy crust at the liquid-vapour interface, which subsequently deforms as an elastic shell. For sessile droplets, the known radial outward flow of solvent is expected to…
In both research and industrial settings spin coating is extensively used to prepare highly uniform thin polymer films. However, under certain conditions, spin coating results in films with non-uniform surface morphologies. Although the…
We demonstrate that surface morphogenesis in compressed thin films may result from spatially correlated plastic activity. A soft glassy film strongly adhering to a smooth and rigid substrate and subjected to uniaxial compression, indeed,…
Thin, viscous liquid films subjected to impact events can deform. Here we investigate free surface oil film deformations that arise due to the air pressure buildup under the impacting and rebouncing water drops. Using Digital Holographic…
Glass films created by vapor-depositing molecules onto a substrate can exhibit properties similar to those of ordinary glasses aged for thousands of years. It is believed that enhanced surface mobility is the mechanism that allows vapor…
The drying of a colloidal dispersion can result in a gel phase defined as a porous matrix saturated in solvent. During the drying process, high mechanical stresses are generated. When these stresses exceed the strength of the material, they…
Large scale molecular dynamics simulations are used to study the dispersion of nanoparticles (NPs) in a polymer film during solvent evaporation. As the solvent evaporates, a dense polymer-rich skin layer forms at the liquid/vapor interface,…
When a suspension dries, the suspending fluid evaporates, leaving behind a dry film composed of the suspended particles. During the final stages of drying, the height of the fluid film on the substrate drops below the particle size,…
Dewetting of thin polystyrene films deposited onto silicone wafers at temperatures close to the glass transition exhibits unusual dynamics and front morphologies. Here, we present a new theoretical approach of these phenomena taking into…
A liquid drop impacting a smooth solid substrate splashes by emitting a thin liquid sheet from near the contact line of the spreading liquid. This sheet is lifted from the substrate and ultimately breaks apart. Surprisingly, the splash is…
Saliva is primarily composed of water, but additionally includes a variety of organic and inorganic substances such as salt, proteins, peptides, mucins, virions, etc. The presence of such solutes affects the evaporation time of respiratory…