相关论文: Single-Molecule Magnets: Jahn-Teller Isomerism and…

It is shown that dipolar and weak superexchange interactions between the spin systems of single-molecule magnets (SMM) play an important role in the relaxation of magnetization. These interactions can reduce or increase resonant tunneling.…

Exponential and power law temperature dependences are widely used to fit experimental data of magnetic relaxation time in single molecular magnets. We derived a theory to show how these rules arise from the underling relaxation mechanisms…

High-field electron paramagnetic resonance (HFEPR) spectra were collected at several frequencies for single crystal [Zn3.91Ni0.09(hmp)4(dmb)4Cl4] (1), where dmb is 3,3-dimethyl-1-butanol and hmp is the monoanion of 2-hydroxymethylpyridine.…

The symmetry of magnetic quantum tunneling (MQT) in the single molecule magnet Mn12-acetate has been determined by sensitive low-temperature magnetic measurements in the pure quantum tunneling regime and high frequency EPR spectroscopy in…

The magnetic relaxation characteristics are investigated in the two-dimensional ($l^{}_x\times l^{}_y$) assembly of nanoparticles as a function of out-of-plane positional disorder strength $\Delta(\%)$ using numerical simulations. Such…

The nonlinear dynamical response of Mn$_{12}$ single-molecule magnets is experimentally found to be very large, quite insensitive to the spin-lattice coupling constant, and displaying peaks reversed with respect to classical…

We report on the synthesis and magnetic properties of Mn12-based single molecular magnets (SMMs) with benzene and pentafluorobenzene carboxylate ligands. The changes in ligand structure are shown to have a decisive effect on magnetic…

The electronic structure of a monolayer of single-molecule magnets Mn$_{12}$ on a Au(111) surface is studied using spin-polarized density-functional theory. The Mn$_{12}$ molecules are oriented such that the magnetic easy axis is normal to…

Precise magnetic hysteresis measurements of small single crystals of Mn$_{12}$ acetate of spin 10 have been conducted down to 0.4 K using a high sensitivity Hall magnetometer. At higher temperature (>1.6K) step-like changes in magnetization…

Beginning with a Heisenberg spin Hamiltonian for the manganese ions in the Mn_12 Ac molecule, we find a number of low-energy states of the system. We use these states to solve the time-dependent Schrodinger equation and find the…

We have developed a fully microscopic theory of magnetic properties of the prototype molecular magnet Mn12. First, the intra-molecular magnetic properties have been studied by means of first-principles density functional-based methods, with…

The magnetization processes in binary magnetic/nonmagnetic amorphous alloy Hf_{57}Fe_{43} are investigated by the detailed measurements of magnetic hysteresis loops, temperature dependence of magnetization, relaxation of magnetization and…

We describe and analyze a tight-binding model of single molecule magnets (SMMs) that captures both the spin and spatial aspects of the SMM electronic structure. The model generalizes extended Huckel theory to include the effects of spin…

The preparation and physical characterization are reported for several single-molecule magnet salts to investigate the effects of paramagnetic cations on the magnetization relaxation behavior of [Mn12]- anionic single-molecule magnets.

We propose an explanation for the experimentally observed temperature hysteresis of magnetization in single crystals of lanthanum manganite (La0.8Sr0.2MnO3). The phenomenon is interpreted within the framework of a double-exchange model with…

This is the first systematic ESR investigation of La_(1-x)Sr_(x)MnO_(3) single crystals for Sr concentrations x < 0.2. The rich phase diagram of this compound, which is dominated by the Jahn-Teller effect of Mn^(3+), is a matter of actual…

We present a first-principles investigation of spin-phonon relaxation in a molecular crystal of Co(II) single-ion magnets. Our study combines electronic structure calculations with machine-learning force fields and unravels the nature of…

We report transport measurements through a single-molecule magnet, the Mn12 derivative [Mn12O12(O2C-C6H4-SAc)16(H2O)4], in a single-molecule transistor geometry. Thiol groups connect the molecule to gold electrodes that are fabricated by…

Single-molecule magnets (SMMs) are promising elements for quantum informatics. In the presence of strong magnetic anisotropy, they exhibit magnetization blocking - a magnetic memory effect at the level of a single molecule. Recent studies…

Single-molecule magnets (SMMs) are molecules that can function as nanoscale magnets with potential use as magnetic memory bits. While SMMs can retain magnetization at low temperatures, characterizing them on surface and at room temperature…