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The description of threshold fragmentation under long range repulsive forces is presented. The dominant energy dependence near threshold is isolated by decomposing the cross section into a product of a back ground part and a barrier…

原子物理 · 物理学 2009-10-31 Jan M. Rost

In situations involving large potentials or surface charges, the Poisson Boltzman(PB) equation has shortcomings because it neglects ion-ion interactions and steric effects. This has been widely recognized by the electrochemistry community,…

化学物理 · 物理学 2007-05-23 Mustafa Sabri Kilic , Martin Z. Bazant , Armand Ajdari

In charge-stabilized colloidal suspensions, highly charged macroions, dressed by strongly correlated counterions, carry an effective charge that can be substantially reduced (renormalized) from the bare charge. Interactions between dressed…

软凝聚态物质 · 物理学 2011-06-28 Ben Lu , Alan R. Denton

The repulsive interaction between two atoms at short distances is studied in order to explore the range of validity of standard first-principles simulation techniques and improve the available short-range potentials for the description of…

材料科学 · 物理学 2007-05-23 J. M. Pruneda , E. Artacho

We study an interacting system of $N$ classical particles on a line at thermal equilibrium. The particles are confined by a harmonic trap and repelling each other via pairwise interaction potential that behaves as a power law $\propto…

The adsorption of large ions from solution to a charged surface is investigated theoretically. A generalized Poisson--Boltzmann equation, which takes into account the finite size of the ions is presented. We obtain analytical expressions…

软凝聚态物质 · 物理学 2009-10-31 I. Borukhov , D. Andelman , H. Orland

We perform computational investigations of electrolyte-mediated interactions of charged colloidal particles confined within nanochannels. We investigate the role of discrete ion effects, valence, and electrolyte strength on colloid-wall…

软凝聚态物质 · 物理学 2023-02-28 Inderbir S. Sidhu , Amalie L. Frischknecht , Paul J. Atzberger

We study the interaction between two charge regulating spherical macroions with dielectric interior and dissociable surface groups immersed in a monovalent electrolyte solution. The charge dissociation is modelled via the…

软凝聚态物质 · 物理学 2023-12-11 Hu Ruixuan , Arghya Majee , Jure Dobnikar , Rudolf Podgornik

Charged colloidal particles trapped at an air--water interface are well known to form an ordered crystal, stabilized by a long ranged repulsion, the details of this repulsion remain something of a mystery, but all experiments performed to…

软凝聚态物质 · 物理学 2016-12-22 Duck-Gyu Lee , Pietro Cicuta , Dominic Vella

Two overall neutral surfaces with positive and negative charged domains ("patches") have been shown in recent experiments to exhibit long-range attraction when immersed in an ionic solution. Motivated by the experiments, we calculate…

软凝聚态物质 · 物理学 2016-08-31 Ram M. Adar , David Andelman , Haim Diamant

In the framework of coupled 1D Gross-Pitaevskii equations, we explore the dynamics of a binary Bose-Einstein condensate where the intra-component interaction is repulsive, while the inter-component one is attractive. The existence regimes…

量子气体 · 物理学 2023-01-31 K. K. Ismailov , B. B. Baizakov , F. Kh. Abdullaev , M. Salerno

In this paper we develop a simple theory to study the effects of ionic size on ionic distributions around a charged spherical particle. We include a correction to the regular Poisson-Boltzmann equation in order to take into account the size…

软凝聚态物质 · 物理学 2017-08-30 Thiago Colla , Lucas Nunes Lopes , Alexandre P. dos Santos

We derive a general expression for the multipole expansion of the electro-magnetic interaction in relativistic heavy-ion collisions, which can be employed in higher-order dynamical calculations of Coulomb excitation. The interaction has…

核理论 · 物理学 2009-11-07 H. Esbensen , C. A. Bertulani

We study the effective interaction between differently charged polyelectrolyte-colloid complexes in electrolyte solutions via Monte Carlo simulations. These complexes are formed when short and flexible polyelectrolyte chains adsorb onto…

软凝聚态物质 · 物理学 2010-05-05 D. Truzzolillo , F. Bordi , F. Sciortino , S. Sennato

Within a general theoretical framework we study the effective, deformation-induced interaction between two colloidal particles trapped at a fluid interface in the regime of small deformations. In many studies, this interaction has been…

软凝聚态物质 · 物理学 2010-06-18 Alvaro Dominguez , Martin Oettel , Siegfried Dietrich

We propose a mean-field analytical model to account for the observed asymmetry in the ability to form long-range attraction by the negatively charged colloidal particles and not their equivalently charged positive counterpart. We conjecture…

软凝聚态物质 · 物理学 2009-11-13 William Kung , Monica Olvera de la Cruz

Charged soft-matter systems--such as colloidal dispersions and charged polymers--are dominated by attractive forces between constituent like-charged particles when neutralizing counterions of high charge valency are introduced. Such…

软凝聚态物质 · 物理学 2009-11-11 Ali Naji , Swetlana Jungblut , Andre G. Moreira , Roland R. Netz

Electrostatic interactions between macroions largely govern the equilibrium thermodynamic and dynamical properties of charge-stabilized colloidal suspensions and polyelectrolyte solutions. Predicting the properties of such complex,…

软凝聚态物质 · 物理学 2012-12-11 Alan R. Denton

Condensed ionic systems are described in the framework of a combined approach that takes into account both long-range and short-range interactions. Short-range interaction is expressed in terms of mean potentials and long-range interaction…

统计力学 · 物理学 2019-10-03 G. Bokun , I. Kravtsiv , M. Holovko , V. Vikhrenko , D. di Caprio

The interaction between charged bodies in an ionic solution is a general problem in colloid physics and becomes a central topic in the study of biological systems where the electrostatic interaction between proteins, nucleic acids,…

软凝聚态物质 · 物理学 2015-05-13 Fabien Paillusson , Maria Barbi , Jean-Marc Victor