相关论文: Theory of Chiral Imprinting
Imprinting of cholesteric textures in a polymer network is a method of preserving a macroscopically chiral phase in a system with no molecular chirality. By modifying the elastics properties of the network, the resulting stored helical…
We investigate the interaction between a chirally imprinted network and a solvent of chiral molecules. We find, a liquid crystalline polymer network is preferentially swollen by one component of a racemic solvent. This ability to separate…
Molecular chirality, and the chiral symmetry breaking of resulting macroscopic phases, can be topologically imprinted and manipulated by crosslinking and swelling of polymer networks. We present a new experimental approach to…
Chirality, either of light or matter, has proved to be very practical in biosensing and nanophotonics. However, the fundamental understanding of its temporal dynamics still needs to be discovered. A realistic setup for this are the…
A micrometer-scale elastic shell immersed in a nematic liquid crystal may be deformed by the host if the cost of deformation is comparable to the cost of elastic deformation of the nematic. Moreover, such inclusions interact and form chains…
Nematic twist--bend is the fifth nematic phase recognized in nature. This phase exhibits spiral orientational order, thus it is a chiral structure and it can be stabilized in systems composed of achiral molecules. The microscopic origin of…
In continuum mechanics, the non-centrosymmetric micropolar theory is usually used to capture the chirality inherent in materials. However when reduced to a two dimensional (2D) isotropic problem, the resulting model becomes non-chiral.…
Within the framework of continuum theory, we draw a parallel between ferromagnetic materials and nematic liquid crystals confined on curved surfaces, which are both characterized by local interaction and anchoring potentials. We show that…
We study the pattern formation of chiral charges in the presence of reactions. We show that, in contrast to the original Turing's mechanism of pattern formation in diffusion-reaction systems, the interplay between chiral effects and…
We consider the impact of the elastomer network on the structure and fluctuations in the isotropic-genesis nematic elastomer, via a phenomenological model that underscores the role of network compliance. The model contains a…
Starting from the linear sigma model with constituent quarks we derive the chiral fluid dynamics where hydrodynamic equations for the quark fluid are coupled to the equation of motion for the order-parameter field. In a static system at…
We present a theoretical study of director fields in toroidal geometries with degenerate planar boundary conditions. We find spontaneous chirality: despite the achiral nature of nematics the director configuration show a handedness if the…
The transport of slightly deformable chiral objects in a uniform shear flow is investigated. Depending on the equilibrium configuration one finds up to four different asymptotic states that can be distinguished by a lateral drift velocity…
Chirality transfer from the level of molecular structure up to mesoscopic lengthscales of supramolecular morphologies is a broad and persistent theme in self-assembled soft materials, from biological to synthetic matter. Here, we analyze…
Cholesteric elastomers possess a macroscopic ``phase chirality'' as the director n rotates in a helical fashion along an optical axis $z$ and can be described by a chiral order parameter. This parameter can be tuned by changing the helix…
Memory effects in amorphous materials have been widely studied because of their possible widespread future applications. We show here that ultrastable glasses can exhibit a transient reversible memory effect when subjected to both a local…
We use continuum theory to show that chirality is a key thermodynamic control parameter for the aggregation of biopolymers: chirality produces a stable disperse phase of hexagonal bundles under moderately poor solvent conditions, as has…
Using molecular simulations and classical density functional theory, we study the liquid-crystalline phase behaviour of a series of bent rod-like mesogens with a controlled degree of chirality introduced through a twist at the centre of the…
The textures associated with a point defect centered in a circular domain of a thin film with XY-like ordering have been analyzed. The family of equilibrium textures, both stable and metastable, can be classified by a new radial topological…
Chirality, or the breaking of mirror symmetry, appears across all scales in nature, from molecular conformations to the dynamics of bacterial collectives. Environments composed of such symmetry-breaking constituents can give rise to…